HK1003598A1 - Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation - Google Patents

Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation Download PDF

Info

Publication number
HK1003598A1
HK1003598A1 HK98102704A HK98102704A HK1003598A1 HK 1003598 A1 HK1003598 A1 HK 1003598A1 HK 98102704 A HK98102704 A HK 98102704A HK 98102704 A HK98102704 A HK 98102704A HK 1003598 A1 HK1003598 A1 HK 1003598A1
Authority
HK
Hong Kong
Prior art keywords
group
cyclopentadienyl
borane
tris
hydrocarbyl
Prior art date
Application number
HK98102704A
Other languages
German (de)
English (en)
French (fr)
Chinese (zh)
Other versions
HK1003598B (en
Inventor
N. Nickias Peter
J. Timmers Francis
D. Devore David
K. Rosen Robert
D. Mussell Robert
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of HK1003598B publication Critical patent/HK1003598B/en
Publication of HK1003598A1 publication Critical patent/HK1003598A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
HK98102704A 1993-03-19 1994-02-10 Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation HK1003598A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/034,434 US5347024A (en) 1993-03-19 1993-03-19 Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
PCT/US1994/001647 WO1994021693A1 (en) 1993-03-19 1994-02-10 Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation
US34434 1998-03-04

Publications (2)

Publication Number Publication Date
HK1003598B HK1003598B (en) 1998-10-30
HK1003598A1 true HK1003598A1 (en) 1998-10-30

Family

ID=21876391

Family Applications (1)

Application Number Title Priority Date Filing Date
HK98102704A HK1003598A1 (en) 1993-03-19 1994-02-10 Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation

Country Status (12)

Country Link
US (1) US5347024A (enExample)
EP (1) EP0641360B1 (enExample)
JP (1) JP3547440B2 (enExample)
KR (1) KR950701651A (enExample)
CA (1) CA2134890A1 (enExample)
DE (1) DE69405952T2 (enExample)
ES (1) ES2107201T3 (enExample)
FI (1) FI945435A7 (enExample)
HK (1) HK1003598A1 (enExample)
NO (1) NO944420D0 (enExample)
TW (1) TW273557B (enExample)
WO (1) WO1994021693A1 (enExample)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1273753B (it) * 1994-02-11 1997-07-10 Eniriceche Spa Sistema catalitico e processo per la produzione di polidiolefine
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
DE69704614T2 (de) 1996-06-17 2001-11-08 Exxonmobil Chemical Patents Inc., Baytown Olefinpolymerisationkatalysatorsysteme von gemischten übergangsmetalen
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
DE59712644D1 (de) 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
ATE202365T1 (de) * 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
JP2001516371A (ja) 1996-09-04 2001-09-25 ザ ダウ ケミカル カンパニー 床、壁または天井のカバリング
TW412560B (en) 1996-09-04 2000-11-21 Dow Chemical Co Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
CA2304674A1 (en) * 1997-10-17 1999-04-29 The Dow Chemical Company Compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers
CN1298425A (zh) 1998-03-11 2001-06-06 陶氏化学公司 混有工程热塑性塑料的α－烯烃单体与一种或多种乙烯基或亚乙烯基芳族单体和/或一种或多种位阻脂族或环脂族乙烯基或亚乙烯基单体的共聚体的热塑性组合物
US6403773B1 (en) * 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US6231795B1 (en) 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6048909A (en) * 1998-12-04 2000-04-11 The Dow Chemical Company Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6187232B1 (en) * 1998-12-04 2001-02-13 The Dow Chemical Company Acoustical insulation foams
AU2476600A (en) 1998-12-08 2000-06-26 Dow Chemical Company, The Mel-bondable polypropylene/ethylene polymer fiber and composition for making thesame
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
US6524702B1 (en) 1999-08-12 2003-02-25 Dow Global Technologies Inc. Electrical devices having polymeric members
ES2646296T3 (es) 1999-08-17 2017-12-13 Dow Global Technologies Llc Composición polimérica fluida
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6417276B2 (en) 2000-01-07 2002-07-09 The Dow Chemical Company Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
JP2004504467A (ja) 2000-07-20 2004-02-12 ダウ　グローバル　テクノロジーズ　インコーポレイティド アルケニル芳香族ポリマーとアルファオレフィン／ビニルまたはビニリデン芳香族インターポリマーとをブレンドして得られる発泡組成物
US6946520B2 (en) * 2001-02-27 2005-09-20 Dow Global Technologies, Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
US6953501B2 (en) 2001-08-10 2005-10-11 Inventions & Discoveries, Llc Wood treatment composition and method of use
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
ES2932265T3 (es) 2018-03-30 2023-01-17 Dow Global Technologies Llc Activadores de polimerización de olefinas binucleares
EP3774937A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
US12037440B2 (en) 2018-03-30 2024-07-16 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerization
KR20200138272A (ko) 2018-03-30 2020-12-09 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합 활성화제
KR102729476B1 (ko) 2018-03-30 2024-11-14 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합 활성화제

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation

Also Published As

Publication number Publication date
FI945435A0 (fi) 1994-11-18
TW273557B (enExample) 1996-04-01
EP0641360B1 (en) 1997-10-01
JPH07507099A (ja) 1995-08-03
CA2134890A1 (en) 1994-09-29
NO944420L (no) 1994-11-18
FI945435L (fi) 1994-11-18
DE69405952D1 (de) 1997-11-06
KR950701651A (ko) 1995-04-28
US5347024A (en) 1994-09-13
JP3547440B2 (ja) 2004-07-28
FI945435A7 (fi) 1994-11-18
WO1994021693A1 (en) 1994-09-29
NO944420D0 (no) 1994-11-18
DE69405952T2 (de) 1998-04-16
EP0641360A1 (en) 1995-03-08
ES2107201T3 (es) 1997-11-16

Similar Documents

Publication Publication Date Title
EP0641360B1 (en) Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation
HK1003598B (en) Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation
US5350723A (en) Process for preparation of monocyclopentadienyl metal complex compounds and method of use
KR100203235B1 (ko) 산화 활성을 갖는 부가 중합 촉매의 제조방법, 당해방법으로 제조된 촉매 및 이의 용도
EP1015462B1 (en) Bimetallic complexes and polymerization catalysts therefrom
US5994255A (en) Allyl containing metal complexes and olefin polymerization process
EP0495375B1 (en) Process for preparing addition polymerization catalysts via metal center oxidation
EP0662979B1 (en) Supported homogeneous catalyst complexes for olefin polymerization
US5470927A (en) Ionic metallocene catalyst compositions
US5198401A (en) Ionic metallocene catalyst compositions
KR100449117B1 (ko) 지지될수있는비스시클로펜타디에닐금속착체
US6294625B1 (en) Catalyst system of enhanced productivity and its use in polymerization process
KR19990067026A (ko) 용이하게 지지될 수 있는 금속 착체
EP0668880B1 (en) Polymerisation process using a catalyst system of enhanced productivity
US5721183A (en) Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
JP2004513193A (ja) オレフィン重合のためのフッ素化両性助触媒活性剤
WO1997043294A1 (en) Yttrium containing metal complexes and olefin polymerization process
EP0917543B1 (en) Saturated tricyclic ligand containing metal complexes and olefin polymerization process

Legal Events

Date Code Title Description
PC Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee)