GR1001183B - Εντομοαπωθητικα ν-αρυλο και ν-κυκλοαλκυλο νεοαλκαναμιδιου. - Google Patents

Εντομοαπωθητικα ν-αρυλο και ν-κυκλοαλκυλο νεοαλκαναμιδιου.

Info

Publication number
GR1001183B
GR1001183B GR920100065A GR920100065A GR1001183B GR 1001183 B GR1001183 B GR 1001183B GR 920100065 A GR920100065 A GR 920100065A GR 920100065 A GR920100065 A GR 920100065A GR 1001183 B GR1001183 B GR 1001183B
Authority
GR
Greece
Prior art keywords
areas
carbon atoms
aryl
neoalkanamides
substituted
Prior art date
Application number
GR920100065A
Other languages
English (en)
Inventor
J Robert Steltenkamp
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of GR1001183B publication Critical patent/GR1001183B/el

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/05—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/06—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/07—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Textile Engineering (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Dermatology (AREA)
  • Microbiology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Peptides Or Proteins (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Catching Or Destruction (AREA)

Abstract

N-μονοϋποκατεστημένα νεοαλκαναμίδια 11 έως 14 ατόμων άνθρακα, όπου ο υποκαταστάτης επί του αμιδο αζώτου είναι κυκλικός (αρωματικός ή κυκλοαλειφατικός όπως αρυλ ή κυκλοαλκυλ) και τουλάχιστον με πέντε άτομα άνθρακα, έχουν ανακαλυφθεί να είναι εντομοαπωθητικά υπό τον όρο ότι οποιοσδήποτε αρωματικός υποκαταστάτης είναι Ν-υποκατεστημένος στην ορθο-θέση και ότι όταν η νεοαλκανοϋλο ομάδα είναι πιβαλοϋλ ο ολικός αριθμός ατόμων άνθρακα στο Ν-κυκλικό νεοαλκαναμίδιο είναι τουλάχιστον 12. Τέτοια νεοαλκαναμίδια είναι χρήσιμα σαν απωθητικά εναντι κατσαρίδων συμπεριλαμβανομένων Αμερικανικών, Γερμανικών κατσαρίδων και κατσαρίδων oriental, και είναι επίσης αποτελεσματικά έναντι κουνουπιών (τόσο Anopheles όσο και Aedes), μαύρων μυγών και σαρακιών του ξύλου και σε κάποια έκταση έναντι ελαφοτσιμπουριών. Μπορεί αυτά να εφαρμόζονται σε περιοχές, τοποθεσίες και αντικείμενα που επιθυμείται να διατηρούνται χωρίς τέτοια έντομα, με εφαρμογές άμεσες ή διαλυμάτων ή γαλακτωμάτων αυτών, κατά προτίμηση με ψεκασμό ή σε συνθέσεις απορρυπαντικού ή άλλα προϊόντα που θα εφαρμόζονται σε τέτοιες περιοχές, κ.λ.π. Επειδή τα περιγραφέντα νεαλκαναμίδια είναι επιθυμητά ουσιώδη προς τις επιφάνειες και συνήθως είναι σε υγρή κατάσταση δίνουν μακροχρόνια απωθητικότητα σε τέτοιες περιοχές, κ.λ.π. και δοκιμές έχουν δείξει ότι αυτά διαρκούν επαρκώς για μακρύ χρονικό διάστημα. ω
GR920100065A 1991-02-19 1992-02-19 Εντομοαπωθητικα ν-αρυλο και ν-κυκλοαλκυλο νεοαλκαναμιδιου. GR1001183B (el)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/657,707 US5182305A (en) 1986-08-08 1991-02-19 N-aryl and n-cycloakyl neoalkanamide insect repellents

Publications (1)

Publication Number Publication Date
GR1001183B true GR1001183B (el) 1993-06-07

Family

ID=24638337

Family Applications (1)

Application Number Title Priority Date Filing Date
GR920100065A GR1001183B (el) 1991-02-19 1992-02-19 Εντομοαπωθητικα ν-αρυλο και ν-κυκλοαλκυλο νεοαλκαναμιδιου.

Country Status (37)

Country Link
US (1) US5182305A (el)
EP (1) EP0499992B1 (el)
JP (1) JPH04327562A (el)
KR (1) KR100210223B1 (el)
CN (2) CN1030074C (el)
AT (1) ATE116966T1 (el)
AU (1) AU661836B2 (el)
BG (1) BG60910B1 (el)
BR (1) BR9200527A (el)
CA (1) CA2061449A1 (el)
CZ (1) CZ286002B6 (el)
DE (1) DE69201138D1 (el)
EC (1) ECSP920812A (el)
ES (1) ES2070538T3 (el)
FI (1) FI920700A (el)
GR (1) GR1001183B (el)
HK (1) HK71497A (el)
HU (1) HU217361B (el)
IE (1) IE74858B1 (el)
IL (1) IL100891A (el)
MA (1) MA22487A1 (el)
MX (1) MX9200654A (el)
MY (1) MY110509A (el)
NO (1) NO302358B1 (el)
NZ (1) NZ241622A (el)
OA (1) OA09759A (el)
PL (1) PL168890B1 (el)
PT (1) PT100135B (el)
RO (1) RO109844B1 (el)
RU (1) RU2091367C1 (el)
SK (1) SK280878B6 (el)
TR (1) TR25694A (el)
TW (1) TW222229B (el)
UY (2) UY23376A1 (el)
YU (1) YU48637B (el)
ZA (1) ZA921209B (el)
ZW (1) ZW1792A1 (el)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5434190A (en) * 1986-08-08 1995-07-18 Colgate-Palmolive Co. N-aryl and N-cycloalkyl neoalkanamide insect repellents
NZ260145A (en) * 1993-04-08 1995-12-21 Colgate Palmolive Co Liquid cleaning composition containing detergent and insect repellent material
US5610130A (en) * 1993-08-04 1997-03-11 Colgate-Palmolive Company Microemulsion all-purpose liquid cleaning compositions with insect repellent
US5542207A (en) * 1994-11-23 1996-08-06 Home Saving Termite Control, Inc. Process for controlling insect infestations in a structure
US6054182A (en) * 1998-04-08 2000-04-25 Collins; Daniel R. Method for treating garments with insect repellent
AR035884A1 (es) 2001-05-18 2004-07-21 Nihon Nohyaku Co Ltd Derivado de amida aromatico sustituido, derivado de amina aromatico sustituido con un grupo fluoroalquilo util como intermediario para obtener el mismo, insecticida para agrohorticultura que lo contiene y metodo para usar este ultimo
GB0214342D0 (en) * 2002-06-21 2002-07-31 Givaudan Sa Insect repellents
FR2871996B1 (fr) * 2004-06-25 2006-10-27 Cie Franco Continentale Des Lu Nouvelle composition pour la protection des arbres contre les xylophages et d'autres insectes grimpant par le tronc des arbres
KR101106134B1 (ko) 2005-07-11 2012-01-20 서울옵토디바이스주식회사 나노와이어 형광체를 채택한 발광소자
US7566759B2 (en) * 2005-10-27 2009-07-28 Georgia-Pacific Chemicals Llc Non-aqueous coating formulation of low volatility

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2221771A1 (de) * 1972-05-04 1973-11-15 Bayer Ag Verfahren zur herstellung von alphaimino-nitrilen
FR2602506A1 (fr) * 1986-08-08 1988-02-12 Colgate Palmolive Co N-alkyl-neoalcanamides insectifuges, composition detergente, produit detergent, composition insectifuge, produit a usage domestique et parfum en contenant et procede les utilisant
EP0367257A1 (en) * 1988-11-04 1990-05-09 Colgate-Palmolive Company N-alkyl neoalkanamide insect repellents

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891912A (en) * 1956-06-21 1959-06-23 Gillette Co Opalescent detergent composition
US3852058A (en) * 1957-05-27 1974-12-03 Monsanto Co Herbicidal compositions and methods
US4804683A (en) * 1986-08-08 1989-02-14 Colgate-Palmolive Company N-alkyl neotridecanamide insect repellents

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2221771A1 (de) * 1972-05-04 1973-11-15 Bayer Ag Verfahren zur herstellung von alphaimino-nitrilen
FR2602506A1 (fr) * 1986-08-08 1988-02-12 Colgate Palmolive Co N-alkyl-neoalcanamides insectifuges, composition detergente, produit detergent, composition insectifuge, produit a usage domestique et parfum en contenant et procede les utilisant
EP0367257A1 (en) * 1988-11-04 1990-05-09 Colgate-Palmolive Company N-alkyl neoalkanamide insect repellents

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMISTRY LETTERS. no. 4, April 1983, TOKYO JP pages 449 - 452 H. SUZUKI 'DIPHOSPHORUS TETRAIODIDE AS A NEW MILD CONDENSING AGENT FOR THE SYNTHESIS OF AMIDES' *
LIEBIGS ANNALEN DER CHEMIE. 1977, WEINHEIM DE pages 8 - 19 W. LWOWSKI ET AL. 'CYCLISIERUNG VON ALKANOYLNITRENEN' *
PHARMAZIE. vol. 34, 1979, BERLIN DD pages 12 - 13 F. EL-ZAHRAA ET AL. 'SYNTHESIS AND PHARMACOLOGICAL SCREENING OF CERTAIN N-SUBSTITUTED AMIDES STRUCTURALLY RELATED TO SOME LOCAL ANESTHETICS' *

Also Published As

Publication number Publication date
IL100891A (en) 1995-03-31
HUT61269A (en) 1992-12-28
IE74858B1 (en) 1997-08-13
AU661836B2 (en) 1995-08-10
ECSP920812A (es) 1993-01-12
HU217361B (hu) 2000-01-28
HU9200519D0 (en) 1992-05-28
IL100891A0 (en) 1992-11-15
TW222229B (el) 1994-04-11
MA22487A1 (fr) 1992-12-31
FI920700A (fi) 1992-08-20
MY110509A (en) 1998-07-31
CN1064266A (zh) 1992-09-09
KR920016006A (ko) 1992-09-24
PL293516A1 (en) 1992-11-02
NZ241622A (en) 1994-12-22
NO920644D0 (no) 1992-02-18
CN1030074C (zh) 1995-10-18
EP0499992A1 (en) 1992-08-26
IE920509A1 (en) 1992-08-26
TR25694A (tr) 1993-09-01
YU48637B (sh) 1999-03-04
PT100135B (pt) 1999-06-30
HK71497A (en) 1997-06-06
DE69201138D1 (de) 1995-02-23
AU1106992A (en) 1992-08-27
CN1036781C (zh) 1997-12-24
CN1109869A (zh) 1995-10-11
RU2091367C1 (ru) 1997-09-27
CS48792A3 (en) 1992-09-16
BG60910B1 (bg) 1996-06-28
YU15992A (sh) 1994-06-10
OA09759A (fr) 1993-11-30
MX9200654A (es) 1992-08-01
PT100135A (pt) 1993-05-31
BR9200527A (pt) 1992-10-20
NO302358B1 (no) 1998-02-23
UY25086A1 (es) 2000-12-29
ES2070538T3 (es) 1995-06-01
PL168890B1 (pl) 1996-04-30
US5182305A (en) 1993-01-26
CZ286002B6 (cs) 1999-12-15
ZA921209B (en) 1993-08-19
UY23376A1 (es) 1992-07-15
ATE116966T1 (de) 1995-01-15
EP0499992B1 (en) 1995-01-11
BG95939A (bg) 1993-12-24
ZW1792A1 (en) 1992-05-20
CA2061449A1 (en) 1992-08-20
NO920644L (no) 1992-08-20
KR100210223B1 (ko) 1999-07-15
SK280878B6 (sk) 2000-08-14
JPH04327562A (ja) 1992-11-17
FI920700A0 (fi) 1992-02-18
RO109844B1 (ro) 1995-06-30

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