GB985769A - Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures - Google Patents

Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures

Info

Publication number
GB985769A
GB985769A GB2221061A GB2221061A GB985769A GB 985769 A GB985769 A GB 985769A GB 2221061 A GB2221061 A GB 2221061A GB 2221061 A GB2221061 A GB 2221061A GB 985769 A GB985769 A GB 985769A
Authority
GB
United Kingdom
Prior art keywords
hcl
hydrogen chloride
hydrogen
hydrogen fluoride
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2221061A
Inventor
Leopold Moller
John Lionel Pegler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Smelting Corp Ltd
Imperial Smelting Corp NSC Ltd
Original Assignee
Imperial Smelting Corp Ltd
Imperial Smelting Corp NSC Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Smelting Corp Ltd, Imperial Smelting Corp NSC Ltd filed Critical Imperial Smelting Corp Ltd
Priority to GB2221061A priority Critical patent/GB985769A/en
Publication of GB985769A publication Critical patent/GB985769A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00Halogens; Halogen acids
    • C01B7/01Chlorine; Hydrogen chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Gaseous hydrogen fluoride is removed from a gas mixture containing hydrogen chloride and hydrogen fluoride by contacting with aqueous boric acid solution containing hydrochloric acid in sufficient amount that the pressure of the hydrogen chloride is equal to the partial pressure of the hydrogen chloride in the mixture. The gas mixture, e.g. resulting from CCl4 + HF --> CCl2F2 + HCl, may be passed through a gas liquid contactor, e.g. a packed tower, which is irrigated with an aqueous solution of boric acid in HCl containing 5-10% HF with a F : B ratio of 2-4: 1 and saturated with HCl at a partial pressure of 0.5 atm. The HF reacts with H3BO3 to give HB.F4. In an example a gas containing HCl, HF and N2 was passed through a Drechsel bottle containing an aqueous solution at 30 DEG C. of HF, H3BO3 and HCl.
GB2221061A 1961-06-20 1961-06-20 Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures Expired GB985769A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2221061A GB985769A (en) 1961-06-20 1961-06-20 Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2221061A GB985769A (en) 1961-06-20 1961-06-20 Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures

Publications (1)

Publication Number Publication Date
GB985769A true GB985769A (en) 1965-03-10

Family

ID=10175708

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2221061A Expired GB985769A (en) 1961-06-20 1961-06-20 Improvements in or relating to the separation of hydrogen fluoride and hydrogen chloride mixtures

Country Status (1)

Country Link
GB (1) GB985769A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050690A1 (en) * 2011-10-06 2013-04-11 Arkema France Method of recycling hydrochloric and hydrofluoric acid effluent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050690A1 (en) * 2011-10-06 2013-04-11 Arkema France Method of recycling hydrochloric and hydrofluoric acid effluent
FR2981060A1 (en) * 2011-10-06 2013-04-12 Arkema France PROCESS FOR THE VALORISATION OF THE EFFLUENTS OF CHLOROFLUORHYDRIC ACID
US9783427B2 (en) 2011-10-06 2017-10-10 Arkema France Method of recycling hydrochloric and hydrofluoric acid effluent

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