GB980224A - Process for preparing isoalkoxydiphenylamines - Google Patents

Process for preparing isoalkoxydiphenylamines

Info

Publication number
GB980224A
GB980224A GB4029/62A GB402962A GB980224A GB 980224 A GB980224 A GB 980224A GB 4029/62 A GB4029/62 A GB 4029/62A GB 402962 A GB402962 A GB 402962A GB 980224 A GB980224 A GB 980224A
Authority
GB
United Kingdom
Prior art keywords
preferred
alkali hydroxide
dihydroxydiphenylamine
hydroxydiphenylamine
given
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4029/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB980224A publication Critical patent/GB980224A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82Purification; Separation; Stabilisation; Use of additives
    • C07C209/84Purification
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

An isoalkoxydiphenylamine is made by heating a hydroxydiphenylamine with an alcoholic alkali hydroxide solution in the presence of a secondary alkyl halide. Suitable hydroxydiphenylamines are listed, the preferred amines being 4-hydroxydiphenylamine and 4,41-dihydroxydiphenylamine. The secondary alkyl halide is preferably a chloride but bromides, fluorides or iodides may also be used. Suitable examples are given. It is preferred to use sodium hydroxide but any alkali hydroxide may be used. Methyl alcohol is preferred but ethyl, n-propyl and n-butyl alcohols are also given. The process takes place generally at temperatures from 100 DEG to 140 DEG C., preferably 110-130 DEG C. Examples describe reaction of 4-hydrodiphenylamine and 4,41-dihydroxydiphenylamine with 2-chloropropane in methanolic or ethanolic NaOH. Comparative experiments illustrate the use of lower temperatures or aqueous instead of alcoholic alkali hydroxide solution. Specification 443,779 is referred to.
GB4029/62A 1961-02-02 1962-02-02 Process for preparing isoalkoxydiphenylamines Expired GB980224A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US8657161A 1961-02-02 1961-02-02

Publications (1)

Publication Number Publication Date
GB980224A true GB980224A (en) 1965-01-13

Family

ID=22199445

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4029/62A Expired GB980224A (en) 1961-02-02 1962-02-02 Process for preparing isoalkoxydiphenylamines

Country Status (1)

Country Link
GB (1) GB980224A (en)

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