GB980224A - Process for preparing isoalkoxydiphenylamines - Google Patents
Process for preparing isoalkoxydiphenylaminesInfo
- Publication number
- GB980224A GB980224A GB4029/62A GB402962A GB980224A GB 980224 A GB980224 A GB 980224A GB 4029/62 A GB4029/62 A GB 4029/62A GB 402962 A GB402962 A GB 402962A GB 980224 A GB980224 A GB 980224A
- Authority
- GB
- United Kingdom
- Prior art keywords
- preferred
- alkali hydroxide
- dihydroxydiphenylamine
- hydroxydiphenylamine
- given
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/84—Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
An isoalkoxydiphenylamine is made by heating a hydroxydiphenylamine with an alcoholic alkali hydroxide solution in the presence of a secondary alkyl halide. Suitable hydroxydiphenylamines are listed, the preferred amines being 4-hydroxydiphenylamine and 4,41-dihydroxydiphenylamine. The secondary alkyl halide is preferably a chloride but bromides, fluorides or iodides may also be used. Suitable examples are given. It is preferred to use sodium hydroxide but any alkali hydroxide may be used. Methyl alcohol is preferred but ethyl, n-propyl and n-butyl alcohols are also given. The process takes place generally at temperatures from 100 DEG to 140 DEG C., preferably 110-130 DEG C. Examples describe reaction of 4-hydrodiphenylamine and 4,41-dihydroxydiphenylamine with 2-chloropropane in methanolic or ethanolic NaOH. Comparative experiments illustrate the use of lower temperatures or aqueous instead of alcoholic alkali hydroxide solution. Specification 443,779 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8657161A | 1961-02-02 | 1961-02-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB980224A true GB980224A (en) | 1965-01-13 |
Family
ID=22199445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4029/62A Expired GB980224A (en) | 1961-02-02 | 1962-02-02 | Process for preparing isoalkoxydiphenylamines |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB980224A (en) |
-
1962
- 1962-02-02 GB GB4029/62A patent/GB980224A/en not_active Expired
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