GB970072A - New catalytic compositions - Google Patents

New catalytic compositions

Info

Publication number
GB970072A
GB970072A GB63362A GB63362A GB970072A GB 970072 A GB970072 A GB 970072A GB 63362 A GB63362 A GB 63362A GB 63362 A GB63362 A GB 63362A GB 970072 A GB970072 A GB 970072A
Authority
GB
United Kingdom
Prior art keywords
oxide
catalyst
ethylene oxide
butanol
olefine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB63362A
Inventor
Robert David Smith
Robert Arthur Lawrence Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB63362A priority Critical patent/GB970072A/en
Publication of GB970072A publication Critical patent/GB970072A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0237Amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0202Alcohols or phenols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0209Esters of carboxylic or carbonic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00Preparation of carboxylic acid amides
    • C07C231/10Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esters of formic acid are made by contacting an alcohol, an enol or a phenol with CO in the presence of a catalyst comprising, in a substantially anhydrous condition, an olefine oxide and at least one compound of general formula <FORM:0970072/C1/1> in which R1, R2 and R3 are the same or different hydrocarbon radicals and X is a group Vb element preferably N, P, or As. The same catalyst is used to prepare N-substituted formamides from primary or secondary aliphatic or aromatic amines and CO. Compounds which may be converted to formic esters are methanol, ethanol, n-butanol, sec-butanol, tert-butanol and 2-methoxy ethanol, and by similar treatment diphenylamine may be converted to N-formyldiphenylamine. Example 14 describes the preparation of the formate corresponding to 2-tert.-butylphenol.ALSO:A catalyst comprises an olefine oxide and at least one compound of general formula <FORM:0970072/B1-B2/1> where R1, R2 and R3 are identical or different hydrocarbon radicals and X is a Group Vb element, in substantially anhydrous conditions. X is preferably N, P or As and the olefine oxide preferably forms the major portion of the catalyst. Examples describe the use of ethylene oxide and tributyl phosphine, ethylene oxide and triethylamine, tributyl phosphine and propylene oxide, tributylamine and propylene oxide or ethylene oxide, tributyl phosphine and styrene oxide, and triphenyl arsine and ethylene oxide. The Provisional Specification mentions the use of triphenyl phosphine, tripropylamine and tertiary stibines.
GB63362A 1962-01-08 1962-01-08 New catalytic compositions Expired GB970072A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB63362A GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB63362A GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Publications (1)

Publication Number Publication Date
GB970072A true GB970072A (en) 1964-09-16

Family

ID=9707774

Family Applications (1)

Application Number Title Priority Date Filing Date
GB63362A Expired GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Country Status (1)

Country Link
GB (1) GB970072A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024286A1 (en) * 1979-08-16 1981-03-04 Bayer Ag Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024286A1 (en) * 1979-08-16 1981-03-04 Bayer Ag Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates

Similar Documents

Publication Publication Date Title
GB1144947A (en) Catalysts
GB957000A (en) Production of tert.-butyl-alkyl ethers
GB1197353A (en) Production of Molybdenum Catalysts
GB970072A (en) New catalytic compositions
GB1125935A (en) Production of surface active agents
GB939713A (en) A process for preparing unsaturated monocarboxylic acids from olefins
GB790824A (en) Improvements in the compound di-(2,2,2-trifluoroethyl) acetal of acetaldehyde, process for producing the compound, and process for producing 2,2,2-trifluoroethyl vinyl ether
GB496264A (en) Improvements in or relating to the hydrogenation of alkylene oxides
ES316131A1 (en) A procedure for the purification of a phenol. (Machine-translation by Google Translate, not legally binding)
GB1027481A (en) Crystalline mixtures of capillary active salts and processes for preparing same
CH422812A (en) Process for the preparation of 2-nitro-p-phenylenediamine compounds by catalytic hydrogenation of 2,4-dinitroaniline compounds
GB1097491A (en) Improvements in and relating to surface active compounds
US2052095A (en) Hydration of olefines
ES8200320A1 (en) Manufacturing olefines from crude methanol.
GB804132A (en) Process for the dehydrogenation of alcohols
GB453422A (en) Process for the manufacture of condensation products of olefines
GB687745A (en) Improvements in or relating to the production of aldehydes and ketones
GB1077914A (en) Process for the preparation of phthalic acid esters
GB1094925A (en) Anthraquinone dyestuffs containing aralkylamino groups
GB368935A (en) Improvements in the manufacture and production of aliphatic alcohols
GB558618A (en) Improvements in recovery of olefin oxides
GB1060122A (en) Production of epoxy compounds
GB400189A (en) Improvements in or relating to the production of organic acids or esters thereof
GB500745A (en) Improvements in the purification of synthetic methanol
GB768199A (en) Process for the production of alcohols