GB970072A - New catalytic compositions - Google Patents

New catalytic compositions

Info

Publication number
GB970072A
GB970072A GB63362A GB63362A GB970072A GB 970072 A GB970072 A GB 970072A GB 63362 A GB63362 A GB 63362A GB 63362 A GB63362 A GB 63362A GB 970072 A GB970072 A GB 970072A
Authority
GB
United Kingdom
Prior art keywords
oxide
catalyst
ethylene oxide
butanol
olefine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB63362A
Inventor
Robert David Smith
Robert Arthur Lawrence Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB63362A priority Critical patent/GB970072A/en
Publication of GB970072A publication Critical patent/GB970072A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esters of formic acid are made by contacting an alcohol, an enol or a phenol with CO in the presence of a catalyst comprising, in a substantially anhydrous condition, an olefine oxide and at least one compound of general formula <FORM:0970072/C1/1> in which R1, R2 and R3 are the same or different hydrocarbon radicals and X is a group Vb element preferably N, P, or As. The same catalyst is used to prepare N-substituted formamides from primary or secondary aliphatic or aromatic amines and CO. Compounds which may be converted to formic esters are methanol, ethanol, n-butanol, sec-butanol, tert-butanol and 2-methoxy ethanol, and by similar treatment diphenylamine may be converted to N-formyldiphenylamine. Example 14 describes the preparation of the formate corresponding to 2-tert.-butylphenol.ALSO:A catalyst comprises an olefine oxide and at least one compound of general formula <FORM:0970072/B1-B2/1> where R1, R2 and R3 are identical or different hydrocarbon radicals and X is a Group Vb element, in substantially anhydrous conditions. X is preferably N, P or As and the olefine oxide preferably forms the major portion of the catalyst. Examples describe the use of ethylene oxide and tributyl phosphine, ethylene oxide and triethylamine, tributyl phosphine and propylene oxide, tributylamine and propylene oxide or ethylene oxide, tributyl phosphine and styrene oxide, and triphenyl arsine and ethylene oxide. The Provisional Specification mentions the use of triphenyl phosphine, tripropylamine and tertiary stibines.
GB63362A 1962-01-08 1962-01-08 New catalytic compositions Expired GB970072A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB63362A GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB63362A GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Publications (1)

Publication Number Publication Date
GB970072A true GB970072A (en) 1964-09-16

Family

ID=9707774

Family Applications (1)

Application Number Title Priority Date Filing Date
GB63362A Expired GB970072A (en) 1962-01-08 1962-01-08 New catalytic compositions

Country Status (1)

Country Link
GB (1) GB970072A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024286A1 (en) * 1979-08-16 1981-03-04 Bayer Ag Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024286A1 (en) * 1979-08-16 1981-03-04 Bayer Ag Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates

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