GB970072A - New catalytic compositions - Google Patents
New catalytic compositionsInfo
- Publication number
- GB970072A GB970072A GB63362A GB63362A GB970072A GB 970072 A GB970072 A GB 970072A GB 63362 A GB63362 A GB 63362A GB 63362 A GB63362 A GB 63362A GB 970072 A GB970072 A GB 970072A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxide
- catalyst
- ethylene oxide
- butanol
- olefine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Esters of formic acid are made by contacting an alcohol, an enol or a phenol with CO in the presence of a catalyst comprising, in a substantially anhydrous condition, an olefine oxide and at least one compound of general formula <FORM:0970072/C1/1> in which R1, R2 and R3 are the same or different hydrocarbon radicals and X is a group Vb element preferably N, P, or As. The same catalyst is used to prepare N-substituted formamides from primary or secondary aliphatic or aromatic amines and CO. Compounds which may be converted to formic esters are methanol, ethanol, n-butanol, sec-butanol, tert-butanol and 2-methoxy ethanol, and by similar treatment diphenylamine may be converted to N-formyldiphenylamine. Example 14 describes the preparation of the formate corresponding to 2-tert.-butylphenol.ALSO:A catalyst comprises an olefine oxide and at least one compound of general formula <FORM:0970072/B1-B2/1> where R1, R2 and R3 are identical or different hydrocarbon radicals and X is a Group Vb element, in substantially anhydrous conditions. X is preferably N, P or As and the olefine oxide preferably forms the major portion of the catalyst. Examples describe the use of ethylene oxide and tributyl phosphine, ethylene oxide and triethylamine, tributyl phosphine and propylene oxide, tributylamine and propylene oxide or ethylene oxide, tributyl phosphine and styrene oxide, and triphenyl arsine and ethylene oxide. The Provisional Specification mentions the use of triphenyl phosphine, tripropylamine and tertiary stibines.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB63362A GB970072A (en) | 1962-01-08 | 1962-01-08 | New catalytic compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB63362A GB970072A (en) | 1962-01-08 | 1962-01-08 | New catalytic compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB970072A true GB970072A (en) | 1964-09-16 |
Family
ID=9707774
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB63362A Expired GB970072A (en) | 1962-01-08 | 1962-01-08 | New catalytic compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB970072A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024286A1 (en) * | 1979-08-16 | 1981-03-04 | Bayer Ag | Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates |
-
1962
- 1962-01-08 GB GB63362A patent/GB970072A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024286A1 (en) * | 1979-08-16 | 1981-03-04 | Bayer Ag | Process for the preparation of aromatic dicarboxylic acid dichlorides and their use in the preparation of polycondensates |
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