GB957000A - Production of tert.-butyl-alkyl ethers - Google Patents

Production of tert.-butyl-alkyl ethers

Info

Publication number
GB957000A
GB957000A GB53562A GB53562A GB957000A GB 957000 A GB957000 A GB 957000A GB 53562 A GB53562 A GB 53562A GB 53562 A GB53562 A GB 53562A GB 957000 A GB957000 A GB 957000A
Authority
GB
United Kingdom
Prior art keywords
alcohol
resin
ethylene glycol
isobutene
saturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB53562A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB957000A publication Critical patent/GB957000A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation

Abstract

Ethers are prepared by reacting isobutene with a primary or secondary saturated or unsaturated aliphatic, cycloaliphatic or araliphatic alcohol, which may be substituted, in the presence of a sulphonic acid group-containing cation exchange resin based on one or more vinyl aromatic polymers. The isobutene may be used in admixture with saturated and unsaturated hydrocarbons, e.g. the C4 fraction from the fractionation of cracked gasoline. The resin may be based on a copolymer of a monovinyl compound with an aromatic divinyl compound, the divinyl compound being in a proportion of from 1 to 20% by weight. The resin may be in the so-called H form. The reaction is preferably at 0 to 100 DEG C. and between 0 and 300 atmospheres pressure. Substituents which may be present in the alcohol are halogen, alkoxy, and carbonyl. Alcohols specified in examples are methanol, allyl alcohol, ethylene chlorohydrin, ethylene glycol monomethyl ether, benzyl alcohol, ethylene glycol, isopropanol, aldol.
GB53562A 1961-01-09 1962-01-05 Production of tert.-butyl-alkyl ethers Expired GB957000A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF32926A DE1224294B (en) 1961-01-09 1961-01-09 Process for the production of tertiary butyl alkyl ethers

Publications (1)

Publication Number Publication Date
GB957000A true GB957000A (en) 1964-04-29

Family

ID=7094863

Family Applications (1)

Application Number Title Priority Date Filing Date
GB53562A Expired GB957000A (en) 1961-01-09 1962-01-05 Production of tert.-butyl-alkyl ethers

Country Status (3)

Country Link
BE (1) BE612388A (en)
DE (1) DE1224294B (en)
GB (1) GB957000A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4961109A (en) * 1972-10-12 1974-06-13
US3940450A (en) * 1974-12-16 1976-02-24 Texaco Inc. Preparation and recovery of ethers
US3969416A (en) * 1971-05-04 1976-07-13 Peter Sylvester Shaw Preparation of ketals
US3979461A (en) * 1974-05-21 1976-09-07 Sham Progetti S.P.A. Process for the preparation of methyl tert-butyl ether
US4020114A (en) * 1974-05-21 1977-04-26 Snam Progetti S.P.A. Process for separating butadiene from C4 hydrocarbons streams obtained by stream-cracking
US4039590A (en) * 1974-05-21 1977-08-02 Snam Progetti S.P.A. Process for the synthesis of methyl-tert-butyl ether from methanol and isobutylene in the presence of butadiene
US4071567A (en) * 1974-05-21 1978-01-31 Snamprogetti S.P.A. Process for the production of methyl tert-butyl ether
FR2367721A1 (en) * 1976-10-14 1978-05-12 Basf Ag PROCESS FOR PREPARING TERTIARY ALKYL ETHERS
US4139566A (en) * 1977-10-03 1979-02-13 Shell Oil Company Secondary alcohol ethoxylate process
US4182913A (en) * 1976-11-22 1980-01-08 Nippon Oil Company Ltd. Method for producing methyl tert-butyl ether and fuel composition containing the same
US4182914A (en) * 1974-01-22 1980-01-08 Nippon Oil Company Limited Process for continuously producing diisopropyl ether
US4198530A (en) * 1978-06-29 1980-04-15 Atlantic Richfield Company Production of tertiary butyl methyl ether
US4219678A (en) * 1976-07-02 1980-08-26 Chemische Werke Huls Ag Process for preparing pure methyl tert.-butyl ether
US4299997A (en) * 1978-08-30 1981-11-10 Maruzen Oil Co., Ltd. Process for producing ethylene glycol mono-tert-butyl ether

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1934422C3 (en) * 1968-07-09 1984-04-26 Shell Internationale Research Maatschappij B.V., Den Haag Process for the separation of one or more tertiary monoolefins with four to seven carbon atoms in the molecule from hydrocarbon mixtures
IT1012690B (en) * 1974-05-21 1977-03-10 Snam Progetti PROCEDURE FOR THE PRODUCTION OF TER-ALKYL ETHERS
JPS5168512A (en) * 1974-12-02 1976-06-14 Texaco Development Corp
JPS56142218A (en) * 1980-04-08 1981-11-06 Sumitomo Chem Co Ltd Removal of isobutylene
DE3148109A1 (en) 1981-12-04 1983-06-09 EC Erdölchemie GmbH, 5000 Köln METHOD FOR THE PRODUCTION OF METHYL-TERT.-BUTYL ETHER (MTBE) AND MOSTLY OF I-BUTEN AND METHANOL-FREE HYDROCARBON REFINATES
IT1150678B (en) * 1982-03-12 1986-12-17 Anic Spa PROCEDURE FOR THE PRODUCTION OF TERBUTYL ALCHYL ETHERS IN THE PRESENCE OF BUTADIENE
IT1151183B (en) * 1982-05-20 1986-12-17 Snam Progetti PROCEDURE FOR THE PRODUCTION OF TER-BUTYL ALCHYL ETHERS
EP1639061B1 (en) 2003-06-24 2010-01-20 Biovalue Holding BV Use of an oxygenate as an additive for the reduction of particulate emissions in fuels, particularly in diesel fuels, gasoline and rapeseed methyl ester
RU2609264C1 (en) 2015-12-09 2017-01-31 Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") Method for producing high-octane components from olefins of catalytic cracking
WO2018055065A1 (en) 2016-09-21 2018-03-29 Cepsa S.A.U. Solketal-ethers, production method and uses thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE866191C (en) * 1944-08-12 1953-02-09 Basf Ag Process for the production of alcohols
US2477380A (en) * 1946-08-30 1949-07-26 Atlantic Refining Co Production of tertiary aliphatic alcohols

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3969416A (en) * 1971-05-04 1976-07-13 Peter Sylvester Shaw Preparation of ketals
JPS4961109A (en) * 1972-10-12 1974-06-13
US4182914A (en) * 1974-01-22 1980-01-08 Nippon Oil Company Limited Process for continuously producing diisopropyl ether
US3979461A (en) * 1974-05-21 1976-09-07 Sham Progetti S.P.A. Process for the preparation of methyl tert-butyl ether
US4020114A (en) * 1974-05-21 1977-04-26 Snam Progetti S.P.A. Process for separating butadiene from C4 hydrocarbons streams obtained by stream-cracking
US4039590A (en) * 1974-05-21 1977-08-02 Snam Progetti S.P.A. Process for the synthesis of methyl-tert-butyl ether from methanol and isobutylene in the presence of butadiene
US4071567A (en) * 1974-05-21 1978-01-31 Snamprogetti S.P.A. Process for the production of methyl tert-butyl ether
US3940450A (en) * 1974-12-16 1976-02-24 Texaco Inc. Preparation and recovery of ethers
US4219678A (en) * 1976-07-02 1980-08-26 Chemische Werke Huls Ag Process for preparing pure methyl tert.-butyl ether
FR2367721A1 (en) * 1976-10-14 1978-05-12 Basf Ag PROCESS FOR PREPARING TERTIARY ALKYL ETHERS
US4182913A (en) * 1976-11-22 1980-01-08 Nippon Oil Company Ltd. Method for producing methyl tert-butyl ether and fuel composition containing the same
US4256465A (en) * 1976-11-22 1981-03-17 Nippon Oil Co., Ltd. Method for producing methyl tert-butyl ether and fuel composition containing the same
US4139566A (en) * 1977-10-03 1979-02-13 Shell Oil Company Secondary alcohol ethoxylate process
US4198530A (en) * 1978-06-29 1980-04-15 Atlantic Richfield Company Production of tertiary butyl methyl ether
US4299997A (en) * 1978-08-30 1981-11-10 Maruzen Oil Co., Ltd. Process for producing ethylene glycol mono-tert-butyl ether
US4345102A (en) * 1978-08-30 1982-08-17 Maruzen Oil Co., Ltd. Process for producing ethylene glycol mono-t-butyl ether

Also Published As

Publication number Publication date
DE1224294B (en) 1966-09-08
BE612388A (en) 1962-07-09

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