JPS5168512A - - Google Patents
Info
- Publication number
- JPS5168512A JPS5168512A JP50121411A JP12141175A JPS5168512A JP S5168512 A JPS5168512 A JP S5168512A JP 50121411 A JP50121411 A JP 50121411A JP 12141175 A JP12141175 A JP 12141175A JP S5168512 A JPS5168512 A JP S5168512A
- Authority
- JP
- Japan
- Prior art keywords
- reactant
- alcohol
- inert hydrocarbon
- ether
- raffinate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1473263 Production of ethers TEXACO DEVELOPMENT CORP 4 Nov 1975 [2 Dec 1974] 45718/75 Heading C2C An ether is prepared by (a) reacting a watersoluble alcohol as first reactant with an olefin or a water-insoluble alcohol as second reactant in an inert hydrocarbon solvent having 3 or 4 carbon atoms and in the presence of a solid etherification catalyst, thereby forming a reaction mixture including unreacted first reactant and product ether containing moieties from the first reactant and the second reactant, (b) contacting the reaction mixture with an aqueous extractant in the presence of the inert hydrocarbon, thereby forming an aqueous extract containing the first reactant and a raffinate containing rhe inert hydrocarbon and product ether, and (c) recovering the raffinate. The ether may be recovered from the raffinate, e.g. by fractionation. The first reactant may be a monohydric alcohol (e.g. a C 1 -C 6 aliphatic alcohol or benzyl alcohol) or a polyhydroxy alcohol, a number of which are listed; in the examples, methanol is used. The second reactant is for example a monoolefin i.butene, i.pentene, i.hexene, styrene or phenylpropene) or a di- or tri-olefin; alternatively it may be for example a C 5 -C 10 alcohol; the use of isobutene, is exemplified. The inert hydrocarbon is for example n.butane or isobutane. When the first reactant is isobutene, it may be admitted to the reaction as part of a refinery stream containing butanes; n.butenes present may also be classed as inert hydrocarbons in this case. The catalyst is for example a sulphonated coal or a sulphonated synthetic resin, e.g. a divinylbenzene-crosslinked polystyrene. A flow diagram of a suitable apparatus is given.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US52897074A | 1974-12-02 | 1974-12-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5168512A true JPS5168512A (en) | 1976-06-14 |
Family
ID=24107977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50121411A Pending JPS5168512A (en) | 1974-12-02 | 1975-10-09 |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS5168512A (en) |
AR (1) | AR218609A1 (en) |
AT (1) | AT348497B (en) |
BE (1) | BE836051A (en) |
BR (1) | BR7507887A (en) |
DE (1) | DE2547380A1 (en) |
ES (1) | ES443080A1 (en) |
FR (1) | FR2293411A1 (en) |
GB (1) | GB1473263A (en) |
IN (1) | IN143386B (en) |
IT (1) | IT1051014B (en) |
MX (1) | MX3189E (en) |
NL (1) | NL7513964A (en) |
PH (1) | PH11937A (en) |
SE (1) | SE7513302L (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714547A (en) * | 1980-06-11 | 1982-01-25 | Inst Francais Du Petrole | Manufacture of methyl-tert-butyl ether from methanol and isobutene |
JPS58110529A (en) * | 1981-12-22 | 1983-07-01 | ドイツチエ・テキサコ・アクチエンゲゼルシヤフト | Separation of methanol from reactants obtained in reactor on etherifying c4-c7-isoolefin with methanol |
JPS6114288A (en) * | 1984-06-18 | 1986-01-22 | アンステイテユ・フランセ・デユ・ペトロール | Value increase for olefinic gasoline by etherification |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PH12545A (en) * | 1975-06-06 | 1979-06-07 | Texaco Development Corp | Method for preparation of ethers |
DE3024147C2 (en) | 1980-06-27 | 1983-05-05 | Edeleanu Gmbh, 6000 Frankfurt | Process for the separation of the reaction products obtained in the etherification of lower i-olefins with methanol |
DE3435936A1 (en) * | 1984-09-29 | 1986-04-10 | Linde Ag, 6200 Wiesbaden | METHOD AND DEVICE FOR PRODUCING AETHER |
US5329051A (en) * | 1992-12-30 | 1994-07-12 | Phillips Petroleum Company | Ether recovery |
DE4445635A1 (en) * | 1994-12-21 | 1996-06-27 | Veba Oel Ag | Process for the preparation of polyol alkyl ethers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB954197A (en) * | 1959-05-04 | 1964-04-02 | Sinclair Refining Co | Recovery of tertiary olefins |
DE1224294B (en) * | 1961-01-09 | 1966-09-08 | Bayer Ag | Process for the production of tertiary butyl alkyl ethers |
SE349559B (en) * | 1968-07-09 | 1972-10-02 | Shell Nv | |
BE791661A (en) * | 1971-11-22 | 1973-05-21 | Sun Oil Co Pennsylvania | MANUFACTURE OF GASOLINE COMPOUNDS CONTAINING METHYL-2-METHOXY-2-PROPANE |
BE793163A (en) * | 1971-12-22 | 1973-06-21 | Sun Oil Co Pennsylvania | ETHERS DRYING PROCESS |
-
1975
- 1975-10-09 JP JP50121411A patent/JPS5168512A/ja active Pending
- 1975-10-23 DE DE19752547380 patent/DE2547380A1/en active Granted
- 1975-11-03 AT AT833875A patent/AT348497B/en not_active IP Right Cessation
- 1975-11-04 GB GB4571875A patent/GB1473263A/en not_active Expired
- 1975-11-10 IN IN2144/CAL/75A patent/IN143386B/en unknown
- 1975-11-12 PH PH17764A patent/PH11937A/en unknown
- 1975-11-26 SE SE7513302A patent/SE7513302L/en unknown
- 1975-11-27 BE BE162266A patent/BE836051A/en not_active IP Right Cessation
- 1975-11-27 BR BR7507887*A patent/BR7507887A/en unknown
- 1975-11-28 ES ES443080A patent/ES443080A1/en not_active Expired
- 1975-11-28 MX MX002843U patent/MX3189E/en unknown
- 1975-11-28 FR FR7536514A patent/FR2293411A1/en active Granted
- 1975-12-01 NL NL7513964A patent/NL7513964A/en not_active Application Discontinuation
- 1975-12-01 IT IT29873/75A patent/IT1051014B/en active
-
1980
- 1980-01-01 AR AR21860980D patent/AR218609A1/en active
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714547A (en) * | 1980-06-11 | 1982-01-25 | Inst Francais Du Petrole | Manufacture of methyl-tert-butyl ether from methanol and isobutene |
JPS6342609B2 (en) * | 1980-06-11 | 1988-08-24 | Ansuchi* Furanse Deyu Petorooru | |
JPS58110529A (en) * | 1981-12-22 | 1983-07-01 | ドイツチエ・テキサコ・アクチエンゲゼルシヤフト | Separation of methanol from reactants obtained in reactor on etherifying c4-c7-isoolefin with methanol |
JPH0345053B2 (en) * | 1981-12-22 | 1991-07-09 | Eru Uee Ee Dee Ee Aa Ag Fuyua Minerarueeru Unto Hiemii | |
JPS6114288A (en) * | 1984-06-18 | 1986-01-22 | アンステイテユ・フランセ・デユ・ペトロール | Value increase for olefinic gasoline by etherification |
JPH0519595B2 (en) * | 1984-06-18 | 1993-03-17 | Ansuchi* Furanse Deyu Petorooru |
Also Published As
Publication number | Publication date |
---|---|
AT348497B (en) | 1979-02-26 |
SE7513302L (en) | 1976-06-03 |
DE2547380A1 (en) | 1976-08-12 |
GB1473263A (en) | 1977-05-11 |
FR2293411B1 (en) | 1980-05-16 |
BR7507887A (en) | 1976-09-08 |
ATA833875A (en) | 1978-07-15 |
DE2547380C2 (en) | 1989-10-05 |
FR2293411A1 (en) | 1976-07-02 |
MX3189E (en) | 1980-06-23 |
NL7513964A (en) | 1976-06-04 |
ES443080A1 (en) | 1977-04-01 |
IT1051014B (en) | 1981-04-21 |
IN143386B (en) | 1977-11-12 |
AR218609A1 (en) | 1980-06-30 |
BE836051A (en) | 1976-05-28 |
PH11937A (en) | 1978-09-15 |
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