GB959533A - Process of boronizing metal or alloy surfaces - Google Patents

Process of boronizing metal or alloy surfaces

Info

Publication number
GB959533A
GB959533A GB4043862A GB4043862A GB959533A GB 959533 A GB959533 A GB 959533A GB 4043862 A GB4043862 A GB 4043862A GB 4043862 A GB4043862 A GB 4043862A GB 959533 A GB959533 A GB 959533A
Authority
GB
United Kingdom
Prior art keywords
boronizing
base alloy
max
balance
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4043862A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motors Liquidation Co
Original Assignee
Motors Liquidation Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Motors Liquidation Co filed Critical Motors Liquidation Co
Publication of GB959533A publication Critical patent/GB959533A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/40Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions
    • C23C8/42Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions only one element being applied

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

A metal or alloy surface, e.g. of Fe, Ni, Co, Mo, W, or Ta base alloy, is boronized by immersing it in a fused salt bath containing boron carbide within a silicon carbide lined vessel. Suitable solvents for the B4C in the bath may be molten NaOH or KOH, boric acid, or one or more alkali or alakline earth metal meta-, penta- and/or fluoro-borates. Preferably the bath is of fused sodium tetraborate at 1500-2150 DEG F. containing 5-20% by weight of dissociated B4C. A small amount of carburizing may take place. After boronizing, the surface may be heat-treated to diffuse boron further into the surface, e.g. at 1900 DEG F. for 1 hour, followed by water quenching for a Ni base alloy. Prior to boronizing, the surface may be cleaned and/or heated. A resist of electro-deposited copper may be applied to the surface for boronizing selected parts only. The following alloys are specified:-(a) low alloy steel: .38-.43% Cu, .5-.7% Mn, .2-.4% Si, .04% max. P, .04% max. S, 1.4-1.8% Cr, .3-.4% Mo, .95-1.3% Al, balance Fe; (b) nickel base alloy: .08% max. C, 1% Mn, 9% Fe, .55% Si, .2% Cu, 14-16% Cr, 2.2-2.7% Ti, .4-1% Al, .7-1.2% Nb, balance Ni; (c) cobalt base alloy: .3-.45% C, 18-22% Ni, 18-22% Cr, 3.5-5% Mo, 3.5-8% W, 2.5-4% Nb, 4% Fe, balance Co at least 38%.
GB4043862A 1961-10-26 1962-10-25 Process of boronizing metal or alloy surfaces Expired GB959533A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14790161A 1961-10-26 1961-10-26

Publications (1)

Publication Number Publication Date
GB959533A true GB959533A (en) 1964-06-03

Family

ID=22523388

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4043862A Expired GB959533A (en) 1961-10-26 1962-10-25 Process of boronizing metal or alloy surfaces

Country Status (1)

Country Link
GB (1) GB959533A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2128779A1 (en) * 1971-03-09 1972-10-20 Toyoda Chuo Kenkyusho Kk
US4019926A (en) * 1974-07-01 1977-04-26 The Secretary Of State For Industry In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Prevention of corrosion of metals
US4536224A (en) * 1983-07-26 1985-08-20 Degussa Aktiengesellschaft Salt bath for the currentless production of wear resistant boride layers
CN104630860A (en) * 2015-02-02 2015-05-20 西安建筑科技大学 Rare-earth-catalyzed titanizing melting salt pulse electrolysis boronizing method near phase transition temperature

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2128779A1 (en) * 1971-03-09 1972-10-20 Toyoda Chuo Kenkyusho Kk
US4019926A (en) * 1974-07-01 1977-04-26 The Secretary Of State For Industry In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Prevention of corrosion of metals
US4536224A (en) * 1983-07-26 1985-08-20 Degussa Aktiengesellschaft Salt bath for the currentless production of wear resistant boride layers
CN104630860A (en) * 2015-02-02 2015-05-20 西安建筑科技大学 Rare-earth-catalyzed titanizing melting salt pulse electrolysis boronizing method near phase transition temperature

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