GB945166A - Improvements in or relating to the decomposition of cyclohexyl peroxide - Google Patents
Improvements in or relating to the decomposition of cyclohexyl peroxideInfo
- Publication number
- GB945166A GB945166A GB1960360A GB1960360A GB945166A GB 945166 A GB945166 A GB 945166A GB 1960360 A GB1960360 A GB 1960360A GB 1960360 A GB1960360 A GB 1960360A GB 945166 A GB945166 A GB 945166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salts
- decomposition
- relating
- molecular oxygen
- cyclohexyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The products of the partial oxidation of cyclohexane by molecular oxygen are freed from cyclohexyl peroxides by adding a catalytic amount of dispersible copper and manganese salts and stripping the unreacted cyclohexane therefrom. The residue containing the salts may then be admixed with a monocarboxylic acid, contacted with molecular oxygen and the resulting adipic acid separated. The salts may be acetates or naphthenates and are either soluble in, or capable of being suspended or dispersed in the partially oxidised mixture.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81772659A | 1959-06-03 | 1959-06-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB945166A true GB945166A (en) | 1963-12-23 |
Family
ID=25223754
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1960360A Expired GB945166A (en) | 1959-06-03 | 1960-06-02 | Improvements in or relating to the decomposition of cyclohexyl peroxide |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE591336A (en) |
CH (1) | CH393312A (en) |
DE (1) | DE1193501B (en) |
ES (1) | ES258575A1 (en) |
GB (1) | GB945166A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4704476A (en) * | 1986-01-17 | 1987-11-03 | Basf Aktiengesellschaft | Working up reaction mixtures containing cyclohexyl hydro-peroxide, cyclohexanol and cyclohexanone |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3222144A1 (en) * | 1982-06-11 | 1983-12-15 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING CYCLOHEXANOL AND CYCLOHEXANONE |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE859465C (en) * | 1941-04-13 | 1952-12-15 | Basf Ag | Process for the production of cycloaliphatic ketones and alcohols in addition to dicarboxylic acids |
DE1002754B (en) * | 1954-05-12 | 1957-02-21 | Du Pont | Process for the production of mixtures of cyclohexanone and cyclohexanol suitable for the production of adipic acid |
-
1960
- 1960-05-30 BE BE591336A patent/BE591336A/en unknown
- 1960-06-02 CH CH628360A patent/CH393312A/en unknown
- 1960-06-02 ES ES0258575A patent/ES258575A1/en not_active Expired
- 1960-06-02 GB GB1960360A patent/GB945166A/en not_active Expired
- 1960-06-03 DE DES68818A patent/DE1193501B/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4704476A (en) * | 1986-01-17 | 1987-11-03 | Basf Aktiengesellschaft | Working up reaction mixtures containing cyclohexyl hydro-peroxide, cyclohexanol and cyclohexanone |
Also Published As
Publication number | Publication date |
---|---|
ES258575A1 (en) | 1960-10-16 |
CH393312A (en) | 1965-06-15 |
DE1193501B (en) | 1965-05-26 |
BE591336A (en) | 1960-09-16 |
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