GB945166A - Improvements in or relating to the decomposition of cyclohexyl peroxide - Google Patents

Improvements in or relating to the decomposition of cyclohexyl peroxide

Info

Publication number
GB945166A
GB945166A GB1960360A GB1960360A GB945166A GB 945166 A GB945166 A GB 945166A GB 1960360 A GB1960360 A GB 1960360A GB 1960360 A GB1960360 A GB 1960360A GB 945166 A GB945166 A GB 945166A
Authority
GB
United Kingdom
Prior art keywords
salts
decomposition
relating
molecular oxygen
cyclohexyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1960360A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific Design Co Inc
Original Assignee
Scientific Design Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scientific Design Co Inc filed Critical Scientific Design Co Inc
Publication of GB945166A publication Critical patent/GB945166A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The products of the partial oxidation of cyclohexane by molecular oxygen are freed from cyclohexyl peroxides by adding a catalytic amount of dispersible copper and manganese salts and stripping the unreacted cyclohexane therefrom. The residue containing the salts may then be admixed with a monocarboxylic acid, contacted with molecular oxygen and the resulting adipic acid separated. The salts may be acetates or naphthenates and are either soluble in, or capable of being suspended or dispersed in the partially oxidised mixture.
GB1960360A 1959-06-03 1960-06-02 Improvements in or relating to the decomposition of cyclohexyl peroxide Expired GB945166A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81772659A 1959-06-03 1959-06-03

Publications (1)

Publication Number Publication Date
GB945166A true GB945166A (en) 1963-12-23

Family

ID=25223754

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1960360A Expired GB945166A (en) 1959-06-03 1960-06-02 Improvements in or relating to the decomposition of cyclohexyl peroxide

Country Status (5)

Country Link
BE (1) BE591336A (en)
CH (1) CH393312A (en)
DE (1) DE1193501B (en)
ES (1) ES258575A1 (en)
GB (1) GB945166A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4704476A (en) * 1986-01-17 1987-11-03 Basf Aktiengesellschaft Working up reaction mixtures containing cyclohexyl hydro-peroxide, cyclohexanol and cyclohexanone

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3222144A1 (en) * 1982-06-11 1983-12-15 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING CYCLOHEXANOL AND CYCLOHEXANONE

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE859465C (en) * 1941-04-13 1952-12-15 Basf Ag Process for the production of cycloaliphatic ketones and alcohols in addition to dicarboxylic acids
DE1002754B (en) * 1954-05-12 1957-02-21 Du Pont Process for the production of mixtures of cyclohexanone and cyclohexanol suitable for the production of adipic acid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4704476A (en) * 1986-01-17 1987-11-03 Basf Aktiengesellschaft Working up reaction mixtures containing cyclohexyl hydro-peroxide, cyclohexanol and cyclohexanone

Also Published As

Publication number Publication date
CH393312A (en) 1965-06-15
ES258575A1 (en) 1960-10-16
DE1193501B (en) 1965-05-26
BE591336A (en) 1960-09-16

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