GB1339450A - Acid-catalysed decomposition of aliphatic hydroperoxides - Google Patents

Acid-catalysed decomposition of aliphatic hydroperoxides

Info

Publication number
GB1339450A
GB1339450A GB3279171A GB3279171A GB1339450A GB 1339450 A GB1339450 A GB 1339450A GB 3279171 A GB3279171 A GB 3279171A GB 3279171 A GB3279171 A GB 3279171A GB 1339450 A GB1339450 A GB 1339450A
Authority
GB
United Kingdom
Prior art keywords
acids
alcohols
acid
aliphatic
july
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3279171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunoco Inc
Original Assignee
Sun Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sun Oil Co filed Critical Sun Oil Co
Publication of GB1339450A publication Critical patent/GB1339450A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/517—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of peroxy-compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides

Abstract

1339450 Reactions of peroxides with strong acids; alcohols with per-acids SUN OIL CO 13 July 1971 [13 July 1970 14 Dec 1970] 32791/71 Heading C2C Ketones, aldehydes and alcohols, in admixture are obtained either by contacting a sec. or tert. aliphatic-peroxide or hydroperoxide with aqueous HCl, H 2 SO 4 , oleum, H 2 S 2 O 8 , a mixture of H 2 SO 4 and H 2 S 2 O 8 , HClO 4 , HFSO 3 or an acid treated molecular sieve having a concentration of at least 75 weight per cent or by contacting a sec. or tert. aliphatic alcohol with a peracid having a concentration of at least 75 weight per cent. In the latter process, carboxylic acids are formed in the presence of excess per-acids. The alcohols may be formed as their acid esters.
GB3279171A 1970-07-13 1971-07-13 Acid-catalysed decomposition of aliphatic hydroperoxides Expired GB1339450A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5457870A 1970-07-13 1970-07-13
US9803570A 1970-12-14 1970-12-14

Publications (1)

Publication Number Publication Date
GB1339450A true GB1339450A (en) 1973-12-05

Family

ID=26733220

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3279171A Expired GB1339450A (en) 1970-07-13 1971-07-13 Acid-catalysed decomposition of aliphatic hydroperoxides

Country Status (5)

Country Link
BE (1) BE769917A (en)
DE (1) DE2134292C3 (en)
FR (1) FR2101651A5 (en)
GB (1) GB1339450A (en)
NL (1) NL7109673A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3899538A (en) * 1970-12-14 1975-08-12 Sun Ventures Inc Acid-catalyzed decomposition of aliphatic hydroperoxides

Also Published As

Publication number Publication date
DE2134292B2 (en) 1978-07-06
NL7109673A (en) 1972-01-17
DE2134292C3 (en) 1979-03-08
DE2134292A1 (en) 1972-01-20
BE769917A (en) 1972-01-13
FR2101651A5 (en) 1972-03-31

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee