GB914451A - Chelate complexes of ª--hydroxy acids with magnesium and other metals - Google Patents
Chelate complexes of ª--hydroxy acids with magnesium and other metalsInfo
- Publication number
- GB914451A GB914451A GB27330/59A GB2733059A GB914451A GB 914451 A GB914451 A GB 914451A GB 27330/59 A GB27330/59 A GB 27330/59A GB 2733059 A GB2733059 A GB 2733059A GB 914451 A GB914451 A GB 914451A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- precipitate
- hydroxy acid
- magnesium
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 8
- 239000002184 metal Substances 0.000 title abstract 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011777 magnesium Substances 0.000 title abstract 4
- 229910052749 magnesium Inorganic materials 0.000 title abstract 4
- 150000002739 metals Chemical class 0.000 title abstract 3
- 239000013522 chelant Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000002244 precipitate Substances 0.000 abstract 6
- 150000003839 salts Chemical class 0.000 abstract 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 3
- 229910052742 iron Inorganic materials 0.000 abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000004411 aluminium Chemical group 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000000797 iron chelating agent Substances 0.000 abstract 1
- MHKWSJBPFXBFMX-UHFFFAOYSA-N iron magnesium Chemical compound [Mg].[Fe] MHKWSJBPFXBFMX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 1
- 150000004692 metal hydroxides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Chemical group 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003870 salicylic acids Chemical class 0.000 abstract 1
- 239000011734 sodium Chemical group 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- -1 sodium hydroxide Chemical class 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/01—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
- C07C65/03—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
- C07C65/05—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring o-Hydroxy carboxylic acids
- C07C65/10—Salicylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/418—Preparation of metal complexes containing carboxylic acid moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
- C07C59/06—Glycolic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
- C07C59/08—Lactic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
- C07C59/10—Polyhydroxy carboxylic acids
- C07C59/105—Polyhydroxy carboxylic acids having five or more carbon atoms, e.g. aldonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C07C59/255—Tartaric acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention comprises complexes of the general formula: Mx[M12(OH)yAz] where M is magnesium, aluminium, iron, sodium, potassium or the ammonium radical, M1 is magnesium, aluminium or iron, A is an a -hydroxy acid ion in chelated form, x is an integer from 1 to 5, y is zero or an integer from 1 to 8 and z is an integer from 1 to 4 and the preparation thereof either by dissolving the stoichiometric amounts of chlorides or sulphates of the metal or metals represented by M and M1 and the a -hydroxy acid or a salt thereof in water and slowly adding thereto the stoichiometric amount of an alkali metal hydroxide, e.g. sodium hydroxide, or by precipitating the hydroxides or carbonates of the metal or metals represented by M and M1, washing the precipitate free from the soluble salts and dissolving the precipitate in the stoichiometric amount of the a -hydroxy acid. Alternatively, in the latter process, one or more of the metal hydroxides or carbonates may be replaced by the corresponding oxide or a co-precipitate of the metal salts is formed with sodium hydroxide or sodium carbonate with the optional inclusion of ammonium hydroxide or ammonium chloride, and the co-precipitate dissolved in the a -hydroxy acid. The metal carbonates may be dissolved in the a -hydroxy acid under pressure of the carbon dioxide generated in the reaction as in the case of the formation of magnesium or magnesium-iron chelates or in the case of ironII precipitates the reaction is carried out in an inert atmosphere to avoid oxidation. Compounds of the invention wherein M is iron are also prepared by forming the alkali metal hydroxoferrate, adding thereto a solution of the salt of the cation metal to precipitate the required ferrate and thereafter dissolving the precipitate in the a -hydroxy acid. a -Hydroxy acids which may be used include citric, tartaric, lactic, glycolic, gluconic and salicylic acids. Specification 905,427 is referred to.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL254744D NL254744A (en) | 1959-08-10 | ||
GB27330/59A GB914451A (en) | 1959-08-10 | 1959-08-10 | Chelate complexes of ª--hydroxy acids with magnesium and other metals |
DEP1270A DE1270540B (en) | 1959-08-10 | 1960-08-08 | Process for the preparation of water-soluble complex compounds of aliphatic oxycarboxylic acids |
FR835371A FR159M (en) | 1959-08-10 | 1960-08-09 | Pharmaceutical composition consisting of a chelated complex of alpha-hydroxy acids with magnesium. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB27330/59A GB914451A (en) | 1959-08-10 | 1959-08-10 | Chelate complexes of ª--hydroxy acids with magnesium and other metals |
Publications (1)
Publication Number | Publication Date |
---|---|
GB914451A true GB914451A (en) | 1963-01-02 |
Family
ID=10257819
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27330/59A Expired GB914451A (en) | 1959-08-10 | 1959-08-10 | Chelate complexes of ª--hydroxy acids with magnesium and other metals |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1270540B (en) |
FR (1) | FR159M (en) |
GB (1) | GB914451A (en) |
NL (1) | NL254744A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0380829A1 (en) * | 1988-01-05 | 1990-08-08 | Mission Pharmacal Company, Inc. | Magnesium potassium citrate |
JP2006036699A (en) * | 2004-07-28 | 2006-02-09 | Komatsuya Kagaku Kk | alpha-HYDROXYCARBOXYLIC ACID ALUMINUM SALT, ITS COMPLEX SALT AND METHOD FOR PRODUCING THE SAME |
JP2006036698A (en) * | 2004-07-28 | 2006-02-09 | Komatsuya Kagaku Kk | Citric acid aluminum salt and complex salt, and method for producing the same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE335475C (en) * | 1919-11-28 | 1921-04-02 | K A Hofmann Dr | Process for the preparation of iron-alkali lactates |
DE825402C (en) * | 1948-12-18 | 1951-12-17 | Rhein Chemie G M B H | Process for the production of highly basic carboxylic or sulphonic acid salts |
DE857363C (en) * | 1949-09-13 | 1952-11-27 | Johann G W Opfermann & Sohn | Process for the production of ferrocalcium citrate |
DE869486C (en) * | 1950-11-22 | 1953-03-05 | Johann G W Opfermann & Sohn | Process for the production of ferrocalcium citrate |
DE874305C (en) * | 1950-11-22 | 1953-04-23 | Johann G W Opfermann & Sohn | Process for the production of ferrocalcium citrate |
GB827523A (en) * | 1957-03-27 | 1960-02-03 | Director Of Technical Services | New organic copper compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds |
GB827521A (en) * | 1957-03-27 | 1960-02-03 | Director Of Technical Services | New organic copper compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds |
-
0
- NL NL254744D patent/NL254744A/xx unknown
-
1959
- 1959-08-10 GB GB27330/59A patent/GB914451A/en not_active Expired
-
1960
- 1960-08-08 DE DEP1270A patent/DE1270540B/en active Pending
- 1960-08-09 FR FR835371A patent/FR159M/en active Active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0380829A1 (en) * | 1988-01-05 | 1990-08-08 | Mission Pharmacal Company, Inc. | Magnesium potassium citrate |
JP2006036699A (en) * | 2004-07-28 | 2006-02-09 | Komatsuya Kagaku Kk | alpha-HYDROXYCARBOXYLIC ACID ALUMINUM SALT, ITS COMPLEX SALT AND METHOD FOR PRODUCING THE SAME |
JP2006036698A (en) * | 2004-07-28 | 2006-02-09 | Komatsuya Kagaku Kk | Citric acid aluminum salt and complex salt, and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
NL254744A (en) | |
DE1270540B (en) | 1968-06-20 |
FR159M (en) | 1961-02-13 |
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