GB886182A - Improvements in or relating to catalysts and to a process of polymerisation - Google Patents

Improvements in or relating to catalysts and to a process of polymerisation

Info

Publication number
GB886182A
GB886182A GB3600358A GB3600358A GB886182A GB 886182 A GB886182 A GB 886182A GB 3600358 A GB3600358 A GB 3600358A GB 3600358 A GB3600358 A GB 3600358A GB 886182 A GB886182 A GB 886182A
Authority
GB
United Kingdom
Prior art keywords
ethylene
alloy
catalyst
prepared
pentenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3600358A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE584527D priority Critical patent/BE584527A/xx
Priority to NL245171D priority patent/NL245171A/xx
Priority to IT618686D priority patent/IT618686A/it
Application filed by BP PLC filed Critical BP PLC
Priority to GB3600358A priority patent/GB886182A/en
Priority to FR809656A priority patent/FR1245064A/en
Priority to DE19591418070 priority patent/DE1418070A1/en
Publication of GB886182A publication Critical patent/GB886182A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/064—Aluminium compounds with C-aluminium linkage compounds with an Al-Halogen linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Unsaturated compounds are polymerized by use of a catalyst prepared by reacting (1) an alloy of Al and Ni, Co, Fe, Pt, Pd or Ir with (2) an alkyl chloride, bromide or iodide and optionally (3) free Cl2, Br2 or I2. Monomers mentioned are ethylene, propylene, n- and i-butene and pentenes. In the example, ethylene (containing as trace impurities methane, acetylene and ethane) gave a liquid polymer of which 55,98% was fractionated between 24 and 350 DEG C., the catalyst being prepared from Al/Ni alloy, I2 and EtBr.ALSO:Unsaturated compounds are polymerised by use of a catalyst prepared by reacting (1) an alloy of Al and Ni, Co, Fe, Pt, Pd or Ir with (2) an alkyl chloride, bromide or iodide and optionally, (3) free Cl2, Br2 or I2. Monomers mentioned are ethylene, propylene, n- and ibutene and pentenes. In the example, ethylene (containing as trace impurities methane, acetylene and ethane) gave a liquid polymer of which 55.98% was fractionated between 24 DEG C. and 350 DEG C., the catalyst being prepared from Al/Ni alloy, I2 and EtBr.
GB3600358A 1958-11-10 1958-11-10 Improvements in or relating to catalysts and to a process of polymerisation Expired GB886182A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BE584527D BE584527A (en) 1958-11-10
NL245171D NL245171A (en) 1958-11-10
IT618686D IT618686A (en) 1958-11-10
GB3600358A GB886182A (en) 1958-11-10 1958-11-10 Improvements in or relating to catalysts and to a process of polymerisation
FR809656A FR1245064A (en) 1958-11-10 1959-11-09 Process for the manufacture of a catalyst for the polymerization of a compound having unsaturated bonds between carbons, and catalyst and polymers obtained by this process
DE19591418070 DE1418070A1 (en) 1958-11-10 1959-11-10 Process for the polymerization of compounds with unsaturated C-C bonds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3600358A GB886182A (en) 1958-11-10 1958-11-10 Improvements in or relating to catalysts and to a process of polymerisation

Publications (1)

Publication Number Publication Date
GB886182A true GB886182A (en) 1962-01-03

Family

ID=10383892

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3600358A Expired GB886182A (en) 1958-11-10 1958-11-10 Improvements in or relating to catalysts and to a process of polymerisation

Country Status (6)

Country Link
BE (1) BE584527A (en)
DE (1) DE1418070A1 (en)
FR (1) FR1245064A (en)
GB (1) GB886182A (en)
IT (1) IT618686A (en)
NL (1) NL245171A (en)

Also Published As

Publication number Publication date
BE584527A (en)
IT618686A (en)
NL245171A (en)
FR1245064A (en) 1960-11-04
DE1418070A1 (en) 1968-10-10

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