GB886168A - Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst - Google Patents

Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst

Info

Publication number
GB886168A
GB886168A GB4096159A GB4096159A GB886168A GB 886168 A GB886168 A GB 886168A GB 4096159 A GB4096159 A GB 4096159A GB 4096159 A GB4096159 A GB 4096159A GB 886168 A GB886168 A GB 886168A
Authority
GB
United Kingdom
Prior art keywords
catalyst
olefins
ethylene
albr3
gave
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4096159A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE597740D priority Critical patent/BE597740A/xx
Application filed by BP PLC filed Critical BP PLC
Priority to GB4096159A priority patent/GB886168A/en
Priority to FR845358A priority patent/FR1282010A/en
Priority to DE19601418643 priority patent/DE1418643A1/en
Publication of GB886168A publication Critical patent/GB886168A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Olefins, such as C2-4 (or higher) mono-olefins or polyenes, are polymerized at elevated temperature and pressure in presence of a catalyst introduced as a mixture comprising Al, Mg, Hg and AlX3 or AlRX2 wherein X is halogen and R is alkyl. In place of Hg there may be used a Hg compound which liberates the metal in presence of the other catalyst components, e.g. mercuric acetate, chloride, bromide, iodide, nitrate, sulphate, cyanide or chromate. In examples, ethylene with an Al/Mg/Hg/AlBr3 catalyst gave fractions boiling from below 60 DEG C. up to 300 DEG C. and a residue; using an Al/Mg/HgCl2/AlBr3 catalyst, ethylene gave liquid reaction products containing specifically hexene-1.ALSO:Olefins, such as C2-4 (or higher) mono-olefins or polyenes, are polymerised at elevated temperature and pressure in presence of a catalyst introduced as a mixture comprising Al, Mg, Hg and AlX3 or AlRX2 wherein X is halogen and R is alkyl. In place of Hg there may be used a Hg compound which liberates the metal in presence of the other catalyst components, e.g. mercuric acetate, chloride, bromide, iodide, nitrate, sulphate, cyanide or chromate. In examples, ethylene with an Al/Mg/Hg/AlBr3 catalyst gave fractions boiling from below 60 DEG C. up to 300 DEG C. and a residue; using an Al/Mg/HgCl2/AlBr3 catalyst, ethylene gave liquid reaction products containing specifically hexene-1.
GB4096159A 1959-12-02 1959-12-02 Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst Expired GB886168A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE597740D BE597740A (en) 1959-12-02
GB4096159A GB886168A (en) 1959-12-02 1959-12-02 Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst
FR845358A FR1282010A (en) 1959-12-02 1960-11-29 Catalyst mixture and polymerization process using this catalyst
DE19601418643 DE1418643A1 (en) 1959-12-02 1960-12-01 Process and catalyst for the polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4096159A GB886168A (en) 1959-12-02 1959-12-02 Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst

Publications (1)

Publication Number Publication Date
GB886168A true GB886168A (en) 1962-01-03

Family

ID=10417460

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4096159A Expired GB886168A (en) 1959-12-02 1959-12-02 Improvements in or relating to catalysts and to a process of polymerisation using animproved catalyst

Country Status (3)

Country Link
BE (1) BE597740A (en)
DE (1) DE1418643A1 (en)
GB (1) GB886168A (en)

Also Published As

Publication number Publication date
BE597740A (en)
DE1418643A1 (en) 1969-04-24

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