GB889312A - Improvements in or relating to the polymerisation of olefins - Google Patents

Improvements in or relating to the polymerisation of olefins

Info

Publication number
GB889312A
GB889312A GB4218559A GB4218559A GB889312A GB 889312 A GB889312 A GB 889312A GB 4218559 A GB4218559 A GB 4218559A GB 4218559 A GB4218559 A GB 4218559A GB 889312 A GB889312 A GB 889312A
Authority
GB
United Kingdom
Prior art keywords
aluminium
metals
mercury
mixture
trihalide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4218559A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE597898D priority Critical patent/BE597898A/xx
Application filed by BP PLC filed Critical BP PLC
Priority to GB4218559A priority patent/GB889312A/en
Priority to FR846211A priority patent/FR1275746A/en
Priority to DE19601418649 priority patent/DE1418649A1/en
Publication of GB889312A publication Critical patent/GB889312A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Liquid polymers are prepared by polymerizing olefins containing at least 3 carbon atoms in the presence of a catalyst formed by reacting with ethylene a mixture comprising aluminium and an aluminium trihalide or an aluminium alkyl dihalide. The said mixture may also contain magnesium, mercury or a compound which liberates mercury in the presence of the other components, and metals, or compounds thereof, which metals have activity as hydrogenation catalysts, e.g. cobalt, iron, nickel, platinum, palladium and iridium. The metals may be present as alloys or amalgams. The preferred aluminium trihalide is aluminium bromide. The olefin may be propylene or a butene.ALSO:Liquid polymers are prepared by polymerising olefins containing at least 3 carbon atoms in the presence of a catalyst formed by reacting, with ethylene, a mixture comprising aluminium and an aluminium trihalide or an aluminium alkyl dihalide. The said mixture may also comprise magnesium, mercury or a compound which liberates mercury in the presence of the other components, and metals, or compounds thereof, which metals have activity as hydrogenation catalysts, e.g. cobalt, iron, nickel, platinum, palladium and iridium. The metals may be present as alloys or amalgams. The preferred aluminium trihalide is aluminium bromide. The olefin may be propylene or a butene. In examples propylene is polymerized in the presence of catalysts prepared from (1) aluminium chloride and aluminium to give a product comprising 2-methylpentene-1, 2-methyl pentene-2, 3- and 4-methyl pentene-1 and 4-methyl pentene-2; and (2) aluminium bromide, aluminium, magnesium, mercury and nickel chloride to give a product comprising 2-methyl-pentene-1.
GB4218559A 1959-12-11 1959-12-11 Improvements in or relating to the polymerisation of olefins Expired GB889312A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE597898D BE597898A (en) 1959-12-11
GB4218559A GB889312A (en) 1959-12-11 1959-12-11 Improvements in or relating to the polymerisation of olefins
FR846211A FR1275746A (en) 1959-12-11 1960-12-07 Process for the production of normally liquid polymers, and polymers obtained by this process
DE19601418649 DE1418649A1 (en) 1959-12-11 1960-12-12 Process for the preparation of normally liquid polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4218559A GB889312A (en) 1959-12-11 1959-12-11 Improvements in or relating to the polymerisation of olefins
GB828460 1960-03-09

Publications (1)

Publication Number Publication Date
GB889312A true GB889312A (en) 1962-02-14

Family

ID=26242073

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4218559A Expired GB889312A (en) 1959-12-11 1959-12-11 Improvements in or relating to the polymerisation of olefins

Country Status (3)

Country Link
BE (1) BE597898A (en)
DE (1) DE1418649A1 (en)
GB (1) GB889312A (en)

Also Published As

Publication number Publication date
BE597898A (en)
DE1418649A1 (en) 1969-07-10

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