GB866610A - Octane appreciators for hydrocarbon fuels - Google Patents

Octane appreciators for hydrocarbon fuels

Info

Publication number
GB866610A
GB866610A GB31794/58A GB3179458A GB866610A GB 866610 A GB866610 A GB 866610A GB 31794/58 A GB31794/58 A GB 31794/58A GB 3179458 A GB3179458 A GB 3179458A GB 866610 A GB866610 A GB 866610A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
hydrocarbyl radical
volume
radical containing
octane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31794/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of GB866610A publication Critical patent/GB866610A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/189—Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C10L1/306—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond) organo Pb compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

866,610. Liquid fuels. TEXACO DEVELOPMENT CORPORATION. Oct. 6, 1958 [Oct. 11, 1957; Dec. 2, 1957 (3); Dec. 23, 1957; March 7, 1958; March 10, 1958; April 14, 1958; June 19, 1958; June 27, 1958], No. 31794/58. Class 91. A hydrocarbon fuel in the gasoline boiling range contains an organo-lead anti-knock agent, at least 10% volume of high octane components selected from olefinic hydrocarbons, aromatic hydrocarbons and mixtures thereof, and from 0.1 to 5% volume of one or more octane appreciators having the general formla: R<SP>1</SP>(X) n (R<SP>2</SP>) m COOR, [R<SP>1</SP>(X) n (R<SP>2</SP>) m CO] 2 O, or R<SP>1</SP>CHO wherein R<SP>1</SP> is hydrogen or a monovalent hydrocarbyl radical containing 1-29 carbon atoms, R<SP>2</SP> is a divalent hydrocarbyl radical containing 1-18 carbon atoms, R is hydrogen or a tertiary aliphatic hydrocarbyl radical containing 4 to 18 carbon atoms, X is R<SP>1</SP> being a monovalent hydrocarbyl radical when X is -O-, n and m are 0 or 1, where m is O and n is 1, X is only C=O, and the total number of carbon atoms in R<SP>1</SP>, R<SP>2</SP> and X is not more than 29. Effective appreciators are thus monocarboxylic acids of 1-30 carbon atoms, their anhydrides and t-alkyl esters and the ether- and keto-substituted derivatives of such acids, and also aldehydes. Many examples of all these classes of compounds are given. The fuel may contain additionally at least 0.1% volume of one or more arylamines having the formula R<SP>3</SP>NHR<SP>4</SP> wherein R<SP>3</SP> is a monocyclic aryl, a bicyclic aryl or alkaryl hydrocarbyl radical containing 6-16 carbon atoms and R<SP>4</SP> is hydrogen or a hydrocarbyl radical containing 1-12 carbon atoms. These amines, of which examples are given, are said to react synergistically with the octane appreciators to improve the octane rating of the leaded fuel. The aromatic and/or olefin content of the fuel can constitute up to 100% volume thereof but is usually between 20 and 80% volume. Organo-lead anti-knock agents specified are tetra-ethyl, -methyl, -butyl, -amyl, and -propyl lead. An ethylene chloride-ethylene bromide mixture is employed as scavenger.
GB31794/58A 1957-10-11 1958-10-06 Octane appreciators for hydrocarbon fuels Expired GB866610A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US689466A US3541723A (en) 1957-10-11 1957-10-11 Motor fuels containing monocarboxylic acids

Publications (1)

Publication Number Publication Date
GB866610A true GB866610A (en) 1961-04-26

Family

ID=24768600

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31794/58A Expired GB866610A (en) 1957-10-11 1958-10-06 Octane appreciators for hydrocarbon fuels

Country Status (7)

Country Link
US (1) US3541723A (en)
BE (1) BE571921A (en)
DE (1) DE1144971B (en)
FR (1) FR1230463A (en)
GB (1) GB866610A (en)
IT (1) IT597932A (en)
NL (2) NL111819C (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3083086A (en) * 1959-04-09 1963-03-26 Sinclair Research Inc N-propyl n-butyrate in leaded gasoline
US3083088A (en) * 1960-06-15 1963-03-26 Sinclair Research Inc Leaded gasoline containing aromaticsubstituted esters
US3212867A (en) * 1961-03-02 1965-10-19 Sun Oil Co Motor fuel compositions
US3282662A (en) * 1961-03-22 1966-11-01 Shell Oil Co Organic co-antiknock agents
US3160485A (en) * 1962-03-05 1964-12-08 Standard Oil Co Hydrocarbon fuels having improved anti-knock properties
US3198611A (en) * 1962-03-15 1965-08-03 Du Pont Tetraalkyl lead antiknock blends
US3254972A (en) * 1962-04-03 1966-06-07 Du Pont Alkyl lead antiknock appreciators
US3198612A (en) * 1962-09-20 1965-08-03 Standard Oil Co Esters of primary acetylenic alcohols as tetraalkyl lead appreciators
US5114436A (en) * 1987-04-20 1992-05-19 Betz Laboratories, Inc. Process and composition for stabilized distillate fuel oils
TW449617B (en) * 1996-07-05 2001-08-11 Shell Int Research Fuel oil compositions
DE19843380A1 (en) * 1998-09-22 2000-03-23 Kief Horst Process for reducing the pollutant emissions from I.C. engines comprises adding glyoxal in an aqueous solution to the fuel
US6102975A (en) * 1999-10-01 2000-08-15 Marr; Wesley D. Fuel conditioner and improver compositions
EP1834951A1 (en) * 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use
WO2008002643A2 (en) * 2006-06-28 2008-01-03 Cibus Llc Fatty acid blends and uses therefor

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE339989C (en) * 1921-07-11 Siemens Schuckertwerke G M B H Folding anchor for anchoring traction means on which tractors move forward through driven rollers
GB599222A (en) * 1945-09-21 1948-03-08 Anglo Iranian Oil Co Ltd Improvements relating to motor fuels
DE341162C (en) *
US1692784A (en) * 1925-01-23 1928-11-20 Boyce Ite Products Inc Fuel and fuel ingredients
FR640311A (en) * 1926-09-07 1928-07-10 Avenarius Soc Geb Method and means for preventing knocking caused by motor fuels
US2002645A (en) * 1926-11-26 1935-05-28 Socony Vacuum Oil Co Inc Distillate petroleum product and method of treating same
GB277326A (en) * 1927-09-06 1929-01-07 Avenarius Geb A method for preventing the knocking of motor fuel
US2086589A (en) * 1933-04-20 1937-07-13 Standard Oil Dev Co Motor fuel
DE659210C (en) * 1935-04-18 1938-04-28 I G Farbenindustrie Akt Ges Motor fuel
US2125448A (en) * 1935-12-21 1938-08-02 Joseph W Johnson Fuel
CH206436A (en) * 1937-11-08 1939-08-15 Melle Usines Sa Indetonating fuel.
US2207163A (en) * 1938-12-07 1940-07-09 Tide Water Associated Oil Comp Gum ihibitor
US2228662A (en) * 1939-05-31 1941-01-14 Standard Oil Co Motor fuel
DE941946C (en) * 1940-11-19 1956-04-19 Versuchsanstalt Fuer Luftfahrt Process for increasing the shelf life of fuels
US2360585A (en) * 1941-10-27 1944-10-17 Pure Oil Co Motor fuel
US2426709A (en) * 1943-05-06 1947-09-02 Texas Co Stabilization of motor fuels
DE833732C (en) * 1943-10-30 1952-03-10 Standard Oil Dev Co Motor fuels
US2667408A (en) * 1949-10-05 1954-01-26 Sinclair Refining Co Prevention of rust
US2635042A (en) * 1950-04-07 1953-04-14 Ethyl Corp Stabilized motor fuel
US2672450A (en) * 1950-06-28 1954-03-16 Gen Motors Corp Composition for removing adherent deposits from internal-combustion engines
DE885500C (en) * 1951-08-31 1953-08-06 Josef Schaefer Additive to diesel fuel
DE1011222B (en) * 1952-07-31 1957-06-27 Autol Werke G M B H Additive to the fuel for gasoline engines
FR1064316A (en) * 1952-10-11 1954-05-12 Renault Products for the break-in of combustion engines
US2721846A (en) * 1953-04-30 1955-10-25 Texas Co Flushing oil composition
US2800400A (en) * 1953-12-24 1957-07-23 Standard Oil Co Motor fuel additive and fuel containing same
DE1008958B (en) * 1955-07-14 1957-05-23 Autol Werke G M B H Fuels for internal combustion engines
DE964279C (en) * 1955-07-15 1957-05-23 Autol Werke G M B H Additive for motor fuels

Also Published As

Publication number Publication date
DE1144971B (en) 1963-03-07
IT597932A (en)
FR1230463A (en) 1960-09-15
NL111819C (en)
NL112127C (en)
US3541723A (en) 1970-11-24
BE571921A (en)

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