DE659210C - Motor fuel - Google Patents

Motor fuel

Info

Publication number
DE659210C
DE659210C DEI52147D DEI0052147D DE659210C DE 659210 C DE659210 C DE 659210C DE I52147 D DEI52147 D DE I52147D DE I0052147 D DEI0052147 D DE I0052147D DE 659210 C DE659210 C DE 659210C
Authority
DE
Germany
Prior art keywords
motor fuel
amines
aliphatic
hydrocarbons
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI52147D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI52147D priority Critical patent/DE659210C/en
Application granted granted Critical
Publication of DE659210C publication Critical patent/DE659210C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Description

Motortreibstoff Die handelsüblichen Motortreibstoffe, wie z. B. Benzol, Benzin usw., enthalten größere oder geringere Mengen von organisch gebundenem Schwefel, der bei der praktischen Verwendung dieser Produkte in Verbrennungskraftmaschinen teilweise in Schwefelsäure verwandelt wird, die auf die metallischen Konstruktionsteile, wie Zylinderwände, Ventile, einen kortodierenden Einfluß ausübt.Motor fuel Commercially available motor fuels such as B. benzene, Gasoline, etc., contain larger or smaller amounts of organically bound sulfur, in the practical use of these products in internal combustion engines is partially converted into sulfuric acid, which affects the metallic construction parts, like cylinder walls, valves, exerts a cortoding influence.

Es wurde nun gefunden, daß man die erwähnten Übelstände vollkommen beseitigen kann, wenn man den Kohlenwasserstoffen bzw. Kohlenwasserstoffgemischen wasserunlösliche aliphatische oder aliphatisch-aromatische Amine mit einer offenen Kohlenstoffkette von mindestens 8 C-Atomen zusetzt. Geeignete Amine dieser Art sind beispielsweise n-Oktylamin, Dodecylamin, Oktodecylamin usw. An Stelle der reinen Amine können vorteilhaft die aus den natürlichen Fettsäuren, beispielsweise solche aus Palmkernfett, Kokosfett, Tran usw.; auf dem Wege über die Nitrile darstellbaren Amingemische verwendet werden. Besonders geeignet sind sekundäre und vor allem tertiäre Amine der erwähnten Art, wie Gemische von Aminen, die durch Umsetzung des durch katalytische Reduktion von Palmkernfett mit Wasserstoff erhältlichen Fettalkoholgemisches mit Dimethylamin erhalten werden, u. a., da diese Stoffe gegen Kohlensäure der Luft vollkommen beständig sind.It has now been found that the abovementioned evils are complete can eliminate if you use the hydrocarbons or hydrocarbon mixtures water-insoluble aliphatic or aliphatic-aromatic amines with an open Adds a carbon chain of at least 8 carbon atoms. Suitable amines of this type are for example n-octylamine, dodecylamine, octodecylamine, etc. Instead of the pure Amines can advantageously be derived from natural fatty acids, for example those from palm kernel oil, coconut oil, oil oil, etc .; can be represented on the way via the nitriles Amine mixtures can be used. Secondary and especially tertiary are particularly suitable Amines of the type mentioned, such as mixtures of amines obtained by reacting the catalytic reduction of palm kernel fat with hydrogen available fatty alcohol mixture can be obtained with dimethylamine, among other things, since these substances act against carbonic acid in the air are perfectly stable.

Für die praktische Anwendung werden die genannten Amine in geringen Mengen den Kohlenwasserstoffen bzw. Kohlenwasserstoffgemischen, wie Benzin, zugesetzt. Die Amine wirken hierbei gleichzeitig als ein Oberschmierungsmittel, auch zeigen sie klopfhindernde Eigenschaften.The amines mentioned are used in small amounts for practical use Amounts added to the hydrocarbons or hydrocarbon mixtures, such as gasoline. The amines act here at the same time as a top lubricant, also show they have anti-knock properties.

Beispiel ioo Teile eines technischen Benzins werden mit i Teil Dimethyldodecylamin versetzt. Das Gemisch wird in üblicher Weise als Motorbrennstoff verwendet.Example 100 parts of a technical gasoline are mixed with 1 part of dimethyldodecylamine offset. The mixture is used as engine fuel in a conventional manner.

An Stelle des Dimethyldodecylamins kann die gleiche Menge Dimethylpalmkernfettamin verwendet werden.The same amount of dimethyl palm kernel fatty amine can be used in place of dimethyldodecylamine be used.

Claims (1)

PATENTANSPRUCH: Verwendung von Kohlenwasserstoffen oder Kohlenwasserstoffgemischen mit einem Zusatz von wasserunlöslichen aliphatischen oder aliphatisch-aromatischen Aminen mit einer offenen Kohlenstoftkette von mindestens 8 Kohlenstoffatomen als Motortreibstoff.PATENT CLAIM: Use of hydrocarbons or hydrocarbon mixtures with an addition of water-insoluble aliphatic or aliphatic-aromatic Amines with an open carbon chain of at least 8 carbon atoms as Motor fuel.
DEI52147D 1935-04-18 1935-04-18 Motor fuel Expired DE659210C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI52147D DE659210C (en) 1935-04-18 1935-04-18 Motor fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI52147D DE659210C (en) 1935-04-18 1935-04-18 Motor fuel

Publications (1)

Publication Number Publication Date
DE659210C true DE659210C (en) 1938-04-28

Family

ID=7193268

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI52147D Expired DE659210C (en) 1935-04-18 1935-04-18 Motor fuel

Country Status (1)

Country Link
DE (1) DE659210C (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1144971B (en) * 1957-10-11 1963-03-07 Texaco Development Corp Hydrocarbon fuel from the gasoline boiling range
DE1148810B (en) * 1958-01-20 1963-05-16 Union Oil Co Leaded fuel for internal combustion engines
DE2112321A1 (en) * 1970-03-16 1971-09-30 Exxon Research Engineering Co Preparation to improve the air / fuel distribution ratio in internal combustion engines
EP0188042A1 (en) * 1981-04-01 1986-07-23 Ethyl Corporation Alkyldimethylamine fuel oil stabilizer
US5139534A (en) * 1990-04-03 1992-08-18 Shell Oil Company Diesel fuel additives
WO2013174619A1 (en) * 2012-05-25 2013-11-28 Basf Se Tertiary amines for reducing injector nozzle fouling in direct injection spark ignition engines
WO2014023853A3 (en) * 2012-11-06 2014-04-10 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines
US9388354B2 (en) 2012-11-06 2016-07-12 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1144971B (en) * 1957-10-11 1963-03-07 Texaco Development Corp Hydrocarbon fuel from the gasoline boiling range
DE1148810B (en) * 1958-01-20 1963-05-16 Union Oil Co Leaded fuel for internal combustion engines
DE2112321A1 (en) * 1970-03-16 1971-09-30 Exxon Research Engineering Co Preparation to improve the air / fuel distribution ratio in internal combustion engines
FR2084614A5 (en) * 1970-03-16 1971-12-17 Exxon Research Engineering Co
EP0188042A1 (en) * 1981-04-01 1986-07-23 Ethyl Corporation Alkyldimethylamine fuel oil stabilizer
US5139534A (en) * 1990-04-03 1992-08-18 Shell Oil Company Diesel fuel additives
WO2013174619A1 (en) * 2012-05-25 2013-11-28 Basf Se Tertiary amines for reducing injector nozzle fouling in direct injection spark ignition engines
WO2014023853A3 (en) * 2012-11-06 2014-04-10 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines
US9388354B2 (en) 2012-11-06 2016-07-12 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines

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