GB818426A - Improvements in and relating to the production of boron hydrides - Google Patents
Improvements in and relating to the production of boron hydridesInfo
- Publication number
- GB818426A GB818426A GB3934456A GB3934456A GB818426A GB 818426 A GB818426 A GB 818426A GB 3934456 A GB3934456 A GB 3934456A GB 3934456 A GB3934456 A GB 3934456A GB 818426 A GB818426 A GB 818426A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heating
- relating
- production
- yield
- closed system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/02—Boron; Borides
- C01B35/026—Higher boron hydrides, i.e. containing at least three boron atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
Abstract
Decaborane is prepared by heating diborane in the absence of O2 at at least 180 DEG C. in one part of a closed system, condensing the product in another part of the closed system at below 100 DEG C., and separating B10H14 from the condensate. The heating may be at 200-240 DEG C. and cooling may be at down to -40 DEG C., preferably 15-35 DEG C. Atmospheric, super-, or sub-atmospheric pressures may be used preferably superatmospheric up to 5 atmos. The heating may be effected in the presence of an ether, e.g. diethyl ether. In the examples, B2H6, with or without diethyl ether, is contained in a sealed, evacuated, tube which is placed in a furnace, so that half projected for cooling purposes. After heating, H2 was gassed-off, volatiles fractionated to yield B2H6 and B5H9, and the solid residue treated to yield (BH)x residue and B10H14 sublimate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3934456A GB818426A (en) | 1956-12-27 | 1956-12-27 | Improvements in and relating to the production of boron hydrides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3934456A GB818426A (en) | 1956-12-27 | 1956-12-27 | Improvements in and relating to the production of boron hydrides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB818426A true GB818426A (en) | 1959-08-19 |
Family
ID=10409049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3934456A Expired GB818426A (en) | 1956-12-27 | 1956-12-27 | Improvements in and relating to the production of boron hydrides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB818426A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1173881B (en) * | 1960-07-06 | 1964-07-16 | Montedison Spa | Process for the production of borohydrides |
-
1956
- 1956-12-27 GB GB3934456A patent/GB818426A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1173881B (en) * | 1960-07-06 | 1964-07-16 | Montedison Spa | Process for the production of borohydrides |
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