GB780553A - A method of coating glass - Google Patents
A method of coating glassInfo
- Publication number
- GB780553A GB780553A GB28827/55A GB2882755A GB780553A GB 780553 A GB780553 A GB 780553A GB 28827/55 A GB28827/55 A GB 28827/55A GB 2882755 A GB2882755 A GB 2882755A GB 780553 A GB780553 A GB 780553A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glass
- carbon atoms
- group
- hydrocarbon radical
- monovalent hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Laminated Bodies (AREA)
Abstract
Glass fabric is treated with an aqueous solution of a siloxane of the average general formula <FORM:0780553/IV (b)/1> in which R is a divalent or trivalent saturated aliphatic or cycloaliphatic hydrocarbon radical containing at least 3 carbon atoms, wherein each carboxyl group is attached to at least the third carbon atom from the silicon atom, R1 is a monovalent hydrocarbon or halogenated monovalent hydrocarbon radical free from aliphatic unsaturation, a is 1 or 2 and b has a value of from 0 to 1 inclusive, said solution having a pH of at least 8, and the fabric is then dried. The preferred siloxane is <FORM:0780553/IV (b)/2> though the R group may be propylene, tetramethylene, octadecamethylene, <FORM:0780553/IV (b)/3> cyclohexylene, cyclopentylene, methylcyclohexylene, 2:7-decahydro-naphthylene, <FORM:0780553/IV (b)/4> The R1 group may be alkyl, cycloalkyl, aryl, chlorophenyl, tribromoxenyl, a ,a ,a -trifluorotolyl, tetrafluoroethyl and chlorocyclohexyl. The acidic siloxanes may be neutralized by methylamine, ethanolamine, triethanolamine, ethylene diamine, ammonia, tetramethylammonium hydroxide or 2-hydroxyethyl-trimethylammonium hydroxide, and these may be subsequently removed by heating the treated glass fabric or by treating it with alkali metal hydroxides, carbonates or bicarbonates, the metallic ions being subsequently washed from the fabric. Acidic groups containing 8 or more carbon atoms ensure good lubrication, whereas those with less than 8 carbon atoms increase the strand integrity of the fabrics. The coatings cause increased adherence of resins such as polyesters, polyamides, phenol-formaldehydes, melamine-formaldehydes and urea-aldehydes to glass fabrics.ALSO:A glass surface is coated with an aqueous solution of a siloxane of the average general formula <FORM:0780553/III/1> in which R is a divalent or trivalent saturated aliphatic or cycloaliphatic hydrocarbon radical, containing at least 3 carbon atoms, wherein each carboxyl group is attached to at least the third carbon atom from the silicon atom, R1 is a monovalent hydrocarbon or halogenated monovalent hydrocarbon radical free from aliphatic unsaturation, a is 1 or 2 and b has a value of from 0 to 1 inclusive, said solution having a pH of at least 8, and the surface is then dried. The preferred siloxane is <FORM:0780553/III/2> though the R group may be propylene, tetramethylene, octadecamethylene, <FORM:0780553/III/3> cyclohexylene, cyclopentylene, methylcyclohexylene, 2 : 7 - decahydro-naphthylene, <FORM:0780553/III/4> and <FORM:0780553/III/5> The R1 group may be alkyl, cycloalkyl, aryl, chlorophenyl, tribromoxenyl, a ,a ,a -trifluorotolyl, tetrafluoroethyl and chlorocyclohexyl. The acidic siloxanes may be neutralized by methylamine, ethanolamine, triethanolamine, ethylene diamine, ammonia, tetramethylammonium hydroxide or 2-hydroxyethyl-trimethylammonium hydroxide and these subsequently removed by heating the treated glass, or by alkali metal hydroxides, carbonates or bicarbonates and the metallic ions subsequently washed from the glass. Acidic groups containing 8 or more carbon atoms ensure good lubrication. These coatings cause increased adherence of resins such as polyesters, polyamides, phenol - formaldehydes, melamine - formaldehyde and urea-aldehydes to glass.ALSO:A coating composition for glass surfaces comprises an aqueous solution of a siloxane of the average general formula <FORM:0780553/IV (a)/1> in which R is a divalent or trivalent saturated aliphatic or cycloaliphatic hydrocarbon radical, containing at least 3 carbon atoms, wherein each carboxyl group is attached to at least the third carbon atom from the silicon atom, R1 is a monovalent hydrocarbon or halogenated monovalent hydrocarbon radical free from aliphatic unsaturation, a is 1 or 2 and b has a value of from 0 to 1 inclusive, said solution having a pH of at least 8, and the surface is then dried. The preferred siloxane is <FORM:0780553/IV (a)/2> though the R group may be propylene, tetramethylene, octadecamethylene, <FORM:0780553/IV (a)/3> cyclohexylene, cyclopentylene, methylcyclohexylene, 2:7 - decahydro - naphthylene, <FORM:0780553/IV (a)/4> The R1 group may be alkyl, cycloalkyl, aryl, chlorophenyl, tribromoxenyl, a ,a ,a -trifluorotolyl, tetrafluoroethyl and chlorocyclohexyl. The acidic siloxanes may be neutralized by methylamine, ethanolamine, triethanolamine, ethylene diamine, ammonia, tetramethylammonium hydroxide or 2-hydroxyethyl-trimethylammonium hydroxide and these subsequently removed by heating the treated glass, or by alkali metal hydroxides, carbonates or bicarbonates and the metallic ions subsequently washed from the glass. Acidic groups containing 8 or more carbon atoms ensure good lubrication. These coatings cause increased adherence of resins such as polyesters, polyamides phenol-formaldehydes, melamine-formaldehyde and urea-aldehydes to glass.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US780553XA | 1954-10-18 | 1954-10-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB780553A true GB780553A (en) | 1957-08-07 |
Family
ID=22141645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28827/55A Expired GB780553A (en) | 1954-10-18 | 1955-10-10 | A method of coating glass |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1132818A (en) |
GB (1) | GB780553A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3249464A (en) * | 1961-08-28 | 1966-05-03 | Dow Corning | Molded and laminated siliceous articles and methods of preparing same |
-
1955
- 1955-10-10 GB GB28827/55A patent/GB780553A/en not_active Expired
- 1955-10-17 FR FR1132818D patent/FR1132818A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3249464A (en) * | 1961-08-28 | 1966-05-03 | Dow Corning | Molded and laminated siliceous articles and methods of preparing same |
Also Published As
Publication number | Publication date |
---|---|
FR1132818A (en) | 1957-03-18 |
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