GB1301029A - Process and composition for the anti-static treatment of acrylic fibers - Google Patents
Process and composition for the anti-static treatment of acrylic fibersInfo
- Publication number
- GB1301029A GB1301029A GB427570A GB427570A GB1301029A GB 1301029 A GB1301029 A GB 1301029A GB 427570 A GB427570 A GB 427570A GB 427570 A GB427570 A GB 427570A GB 1301029 A GB1301029 A GB 1301029A
- Authority
- GB
- United Kingdom
- Prior art keywords
- agent
- fibres
- integer
- formula
- agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
1301029 Acrylonitrile polymer fibres MITSUBISHI RAYON CO Ltd 29 Jan 1970 [28 Feb 1969] 4275/70 Heading B5B [Also in Divisions C3 and D1] Acrylonitrile polymer fibres in the aqua-gel state are rendered antistatic by treating with compositions comprising (1) a polymeric cationic antistatic agent containing at least 50% by weight of units of a monomer of the formula wherein R 1 to R 5 are the same or different and represent H or C 1 -C 12 alkyl and n is an integer not exceeding 20, (2) an anionic surface-active agent of the formula where R is a saturated or unsaturated monovalent aliphatic hydrocarbon group having 1-22 carbon atoms, X is H (in which case the surface-active compound is in the form of a salt with a tertiary amine) or a monovalent metal ion, k is 0 or an integer of 1-100, and l and m are 1 or 2 and l+m = 3, and (3) an agent for improving the hand feeling of the fibres to be treated, which agent is a softening agent or a smoothing agent or a mixture of these agents. The fibres may be wet spun "neverdried" fibres, or may be made by dry-spinning followed by treatment in a boiling water bath to give the aqua-gel structure. The compositions are preferably used in the form of aqueous dispersions and may include a dispersing agent, e.g. a nonionic or ampholytic surface-active agent such as poly(ethylene oxide/propylene oxide), and, if desired, an anti-foaming agent, e.g. a silicone compound. If desired, components (1) and (2) can be applied separately to the fibres. The antistatic agent (1) may include as a comonomer component a monomer of the formula where R 6 is H or C 1 -C 5 alkyl, R 7 is H or C 1 - C 22 alkyl optionally substituted by a phenyl group, and n is an integer from 1-200. Suitable as smoothing agents are carboxylic acid (C 10 -C 20 ) esters of alcohols such as sorbitol, glucose and glycols or polyglycols, and ethers such as anisole. Preferred softening agents are certain compounds containing amide and ammonium salt groups, an example of which is the 1 : 1 molar condensation product of acetic acid and α,#-dihydroxyethyl-α<SP>1</SP>,#<SP>1</SP>-di(#-stearylamidoethyl) urea. In certain cases it is advantageous to use dimethylpolysiloxane or methyl hydrogen polysiloxane to prevent the fibres from sticking together.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1517169A JPS4838039B1 (en) | 1969-02-28 | 1969-02-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1301029A true GB1301029A (en) | 1972-12-29 |
Family
ID=11881345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB427570A Expired GB1301029A (en) | 1969-02-28 | 1970-01-29 | Process and composition for the anti-static treatment of acrylic fibers |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS4838039B1 (en) |
DE (1) | DE2009478A1 (en) |
GB (1) | GB1301029A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115029927A (en) * | 2022-07-29 | 2022-09-09 | 湖南佑华医疗用品有限公司 | Medical disposable protective clothing with good antibacterial performance |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001329253A (en) * | 2000-03-14 | 2001-11-27 | Kao Corp | Antistatic agent composition |
JP2005298560A (en) * | 2004-04-07 | 2005-10-27 | Daiwa Kagaku Kogyo Kk | Antistatic agent and method for antistatic treatment |
-
1969
- 1969-02-28 JP JP1517169A patent/JPS4838039B1/ja active Pending
-
1970
- 1970-01-29 GB GB427570A patent/GB1301029A/en not_active Expired
- 1970-02-28 DE DE19702009478 patent/DE2009478A1/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115029927A (en) * | 2022-07-29 | 2022-09-09 | 湖南佑华医疗用品有限公司 | Medical disposable protective clothing with good antibacterial performance |
Also Published As
Publication number | Publication date |
---|---|
JPS4838039B1 (en) | 1973-11-15 |
DE2009478A1 (en) | 1970-10-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |