GB1041870A - Improvements in or relating to organopolysiloxanes and their use as release agents - Google Patents

Improvements in or relating to organopolysiloxanes and their use as release agents

Info

Publication number
GB1041870A
GB1041870A GB24388/65D GB2438865D GB1041870A GB 1041870 A GB1041870 A GB 1041870A GB 24388/65 D GB24388/65 D GB 24388/65D GB 2438865 D GB2438865 D GB 2438865D GB 1041870 A GB1041870 A GB 1041870A
Authority
GB
United Kingdom
Prior art keywords
units
alkyl radical
release agents
polymers
branched chain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24388/65D
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones Corp
Original Assignee
Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corp filed Critical Dow Corning Corp
Publication of GB1041870A publication Critical patent/GB1041870A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/38Polysiloxanes modified by chemical after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers
    • B29C33/64Silicone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/50Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • C10M2229/0415Siloxanes with specific structure containing aliphatic substituents used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/36Release agents or mold release agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Paints Or Removers (AREA)
  • Silicon Polymers (AREA)
  • Adhesive Tapes (AREA)

Abstract

A polymer is claimed per se which consists essentially of: (a) units <FORM:1041870/C3/1> where R is a C8-C20 n-alkyl radical or a radica -CH2CH2Q, where Q is a branched chain C6-C18 alkyl radical and (b) units <FORM:1041870/C3/2> where R1 is a C1-C7 n-alkyl radical or a radical -CH2CH2Q1, where Q1 is a branched chain C3-C5 alkyl radical. The mol. per cent of (b) based on the number of moles of (a) present may be from 0 to 100%. A preferred polymer contains substantially no (b) units and R contains 10-18 carbon atoms. It also contains an average of 20 to 40 (a) units per molecule. The polymers may be used as release agents to prevent adhesion or as lubricating agents for surfaces (e.g. of rubber or synthetic resin). The surfaces may be painted. Examples relate to the preparation of the polymers from methyl hydrogen polysiloxanes and a -olefins using chloroplatinic acid as catalyst.
GB24388/65D 1964-08-10 1965-06-09 Improvements in or relating to organopolysiloxanes and their use as release agents Expired GB1041870A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US38870664A 1964-08-10 1964-08-10

Publications (1)

Publication Number Publication Date
GB1041870A true GB1041870A (en) 1966-09-07

Family

ID=23535185

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24388/65D Expired GB1041870A (en) 1964-08-10 1965-06-09 Improvements in or relating to organopolysiloxanes and their use as release agents

Country Status (4)

Country Link
AT (1) AT252428B (en)
DE (1) DE1276269B (en)
GB (1) GB1041870A (en)
NL (2) NL6510413A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2928813A1 (en) * 1978-10-16 1980-04-24 Goldschmidt Ag Th LUBRICANT AND RELEASE AGENT FOR RUBBER SHAPED BODIES
FR2575168A1 (en) * 1984-12-20 1986-06-27 Rhone Poulenc Spec Chim ORGANOPOLYSILOXANIC COMPOSITIONS FOR THE ANTI-ADHERENT TREATMENT OF MOLD WALLS
EP0243131A2 (en) * 1986-04-22 1987-10-28 Union Carbide Chemicals And Plastics Company, Inc. Silicone surfactants and their use in the manufacture of polyurethane foam
EP0527286A1 (en) * 1991-08-13 1993-02-17 Goyo Paper Working Co. Ltd. Lubricant
EP0527594A1 (en) * 1991-08-08 1993-02-17 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
DE19807022A1 (en) * 1998-02-19 1999-08-26 Wacker Chemie Gmbh Hydrocarbyl-substituted organosilicon compounds especially for treating textiles or ceramic hobs
US8754155B2 (en) 2005-09-06 2014-06-17 Dow Corning Corporation Delivery system for releasing silicone ingredients

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3883628A (en) * 1973-05-14 1975-05-13 Stauffer Chemical Co Silicone release agent
US3872038A (en) * 1973-12-03 1975-03-18 Stauffer Chemical Co Aqueous based release composition
DE3436164A1 (en) * 1984-10-03 1986-04-10 Bayer Ag, 5090 Leverkusen LUBRICANT PREPARATIONS
US4640792A (en) * 1985-11-25 1987-02-03 Dow Corning Corporation Silicone brake fluid having reduced air solubility

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2928813A1 (en) * 1978-10-16 1980-04-24 Goldschmidt Ag Th LUBRICANT AND RELEASE AGENT FOR RUBBER SHAPED BODIES
FR2575168A1 (en) * 1984-12-20 1986-06-27 Rhone Poulenc Spec Chim ORGANOPOLYSILOXANIC COMPOSITIONS FOR THE ANTI-ADHERENT TREATMENT OF MOLD WALLS
EP0191261A1 (en) * 1984-12-20 1986-08-20 Rhone-Poulenc Chimie Silicone compositions for the antiadherent coating of moulds
EP0243131A2 (en) * 1986-04-22 1987-10-28 Union Carbide Chemicals And Plastics Company, Inc. Silicone surfactants and their use in the manufacture of polyurethane foam
EP0243131A3 (en) * 1986-04-22 1988-09-28 Bp Chemicals Limited Silicone surfactants
EP0527594A1 (en) * 1991-08-08 1993-02-17 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
US5338536A (en) * 1991-08-08 1994-08-16 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
US5397566A (en) * 1991-08-08 1995-03-14 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
US5541276A (en) * 1991-08-08 1996-07-30 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
US5626857A (en) * 1991-08-08 1997-05-06 General Electric Company Personal care compositions containing polyalkylsiloxane copolymers
EP0527286A1 (en) * 1991-08-13 1993-02-17 Goyo Paper Working Co. Ltd. Lubricant
DE19807022A1 (en) * 1998-02-19 1999-08-26 Wacker Chemie Gmbh Hydrocarbyl-substituted organosilicon compounds especially for treating textiles or ceramic hobs
US8754155B2 (en) 2005-09-06 2014-06-17 Dow Corning Corporation Delivery system for releasing silicone ingredients

Also Published As

Publication number Publication date
DE1276269B (en) 1968-08-29
AT252428B (en) 1967-02-27
NL131855C (en)
NL6510413A (en) 1966-02-11

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