GB744890A - A novel unsaturated dialdehyde and the manufacture thereof - Google Patents
A novel unsaturated dialdehyde and the manufacture thereofInfo
- Publication number
- GB744890A GB744890A GB24214/55A GB2421455A GB744890A GB 744890 A GB744890 A GB 744890A GB 24214/55 A GB24214/55 A GB 24214/55A GB 2421455 A GB2421455 A GB 2421455A GB 744890 A GB744890 A GB 744890A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ine
- diol
- manufacture
- octadiene
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Abstract
The invention comprises 2,7-dimethyl-octadiene-(2,6)-ine-(4)-dial-(1,8), O=CH.C(CH3)= CH-CC-CH=C(CH3).CH=O. This may be produced by oxidizing 2,7-dimethyl-octadiene - (2,6) - ine - (4) - diol - (1,8) with manganese dioxide in the presence of acetone. The reaction temperature is preferably 20 DEG C. but may vary between 0 DEG C. and the boiling point of the solvent. The diol is prepared by anionotropic rearrangement in aqueous acetone by means of sulphuric acid of 2,7-dimethyloctadiene - (1,7) - ine - (4) - diol - (3,6), which is obtained by reacting a -methyl acrolein with acetylene di-(magnesium bromide). The novel dialdehyde is an intermediate in the preparation of b -carotene, bixin and crocetin. A detailed example of its preparation is given.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH744890X | 1952-12-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB744890A true GB744890A (en) | 1956-02-15 |
Family
ID=4533415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24214/55A Expired GB744890A (en) | 1952-12-31 | 1953-12-31 | A novel unsaturated dialdehyde and the manufacture thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB744890A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3103352A1 (en) | 2015-06-12 | 2016-12-14 | DSM IP Assets B.V. | Acid stable beverages comprising bixin |
WO2016198569A1 (en) | 2015-06-12 | 2016-12-15 | Dsm Ip Assets B.V. | New orange color for edible coatings |
WO2016198570A1 (en) | 2015-06-12 | 2016-12-15 | Dsm Ip Assets B.V. | New natural color for edible coatings |
-
1953
- 1953-12-31 GB GB24214/55A patent/GB744890A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3103352A1 (en) | 2015-06-12 | 2016-12-14 | DSM IP Assets B.V. | Acid stable beverages comprising bixin |
WO2016198569A1 (en) | 2015-06-12 | 2016-12-15 | Dsm Ip Assets B.V. | New orange color for edible coatings |
WO2016198567A1 (en) | 2015-06-12 | 2016-12-15 | Dsm Ip Assets B.V. | Acid stable beverages comprising bixin |
WO2016198570A1 (en) | 2015-06-12 | 2016-12-15 | Dsm Ip Assets B.V. | New natural color for edible coatings |
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