GB744890A - A novel unsaturated dialdehyde and the manufacture thereof - Google Patents

A novel unsaturated dialdehyde and the manufacture thereof

Info

Publication number
GB744890A
GB744890A GB24214/55A GB2421455A GB744890A GB 744890 A GB744890 A GB 744890A GB 24214/55 A GB24214/55 A GB 24214/55A GB 2421455 A GB2421455 A GB 2421455A GB 744890 A GB744890 A GB 744890A
Authority
GB
United Kingdom
Prior art keywords
ine
diol
manufacture
octadiene
dimethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24214/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roche Products Ltd
Original Assignee
Roche Products Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roche Products Ltd filed Critical Roche Products Ltd
Publication of GB744890A publication Critical patent/GB744890A/en
Expired legal-status Critical Current

Links

Abstract

The invention comprises 2,7-dimethyl-octadiene-(2,6)-ine-(4)-dial-(1,8), O=CH.C(CH3)= CH-C­C-CH=C(CH3).CH=O. This may be produced by oxidizing 2,7-dimethyl-octadiene - (2,6) - ine - (4) - diol - (1,8) with manganese dioxide in the presence of acetone. The reaction temperature is preferably 20 DEG C. but may vary between 0 DEG C. and the boiling point of the solvent. The diol is prepared by anionotropic rearrangement in aqueous acetone by means of sulphuric acid of 2,7-dimethyloctadiene - (1,7) - ine - (4) - diol - (3,6), which is obtained by reacting a -methyl acrolein with acetylene di-(magnesium bromide). The novel dialdehyde is an intermediate in the preparation of b -carotene, bixin and crocetin. A detailed example of its preparation is given.
GB24214/55A 1952-12-31 1953-12-31 A novel unsaturated dialdehyde and the manufacture thereof Expired GB744890A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH744890X 1952-12-31

Publications (1)

Publication Number Publication Date
GB744890A true GB744890A (en) 1956-02-15

Family

ID=4533415

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24214/55A Expired GB744890A (en) 1952-12-31 1953-12-31 A novel unsaturated dialdehyde and the manufacture thereof

Country Status (1)

Country Link
GB (1) GB744890A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3103352A1 (en) 2015-06-12 2016-12-14 DSM IP Assets B.V. Acid stable beverages comprising bixin
WO2016198569A1 (en) 2015-06-12 2016-12-15 Dsm Ip Assets B.V. New orange color for edible coatings
WO2016198570A1 (en) 2015-06-12 2016-12-15 Dsm Ip Assets B.V. New natural color for edible coatings

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3103352A1 (en) 2015-06-12 2016-12-14 DSM IP Assets B.V. Acid stable beverages comprising bixin
WO2016198569A1 (en) 2015-06-12 2016-12-15 Dsm Ip Assets B.V. New orange color for edible coatings
WO2016198567A1 (en) 2015-06-12 2016-12-15 Dsm Ip Assets B.V. Acid stable beverages comprising bixin
WO2016198570A1 (en) 2015-06-12 2016-12-15 Dsm Ip Assets B.V. New natural color for edible coatings

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