GB723715A - Process for the manufacture of fluorochlorethylenes - Google Patents
Process for the manufacture of fluorochlorethylenesInfo
- Publication number
- GB723715A GB723715A GB27226/52A GB2722652A GB723715A GB 723715 A GB723715 A GB 723715A GB 27226/52 A GB27226/52 A GB 27226/52A GB 2722652 A GB2722652 A GB 2722652A GB 723715 A GB723715 A GB 723715A
- Authority
- GB
- United Kingdom
- Prior art keywords
- active carbon
- fluoro
- yield
- copper
- trichlorethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
Abstract
Fluorochloroethylenes are made by passing vaporized fluorochlorethanes over heated surfaces. Substances having large surfaces are preferred, e.g. active carbon and silica gel, and activators, e.g. metal salts such as chlorides and particularly alkaline earth metal or copper chlorides may be present. Specified temperatures are 200-300 DEG C. or higher. In examples 1-fluoro-1,1,2,2-tetrachlorethane is passed through (1) a copper p tube containing copper turnings at 470 DEG C. to yield fluoro-trichlorethylene; (2) active carbon containing barium chloride at 300 DEG C. to yield fluoro-trichlorethylene; and (3) active carbon containing strontium chloride at 240 DEG C. to yield 1,1-difluoro-2,2-dichlorethylene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE307970X | 1951-11-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB723715A true GB723715A (en) | 1955-02-09 |
Family
ID=6121588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27226/52A Expired GB723715A (en) | 1951-11-20 | 1952-10-29 | Process for the manufacture of fluorochlorethylenes |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE513162A (en) |
CH (1) | CH307970A (en) |
FR (1) | FR1074575A (en) |
GB (1) | GB723715A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116337A (en) * | 1960-09-06 | 1963-12-31 | Pennsalt Chemicals Corp | Process for the preparation of fluorinated olefins |
US3118005A (en) * | 1960-12-27 | 1964-01-14 | Attila E Pavlath | Titania catalyzed dehydrofluorination of 1, 1, 1-difluorochloro alkanes |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2774799A (en) * | 1954-04-01 | 1956-12-18 | Kellogg M W Co | Selective dehydrohalogenation of fluorohaloalkanes using a copper catalyst |
-
0
- BE BE513162D patent/BE513162A/xx unknown
-
1952
- 1952-07-18 CH CH307970D patent/CH307970A/en unknown
- 1952-08-29 FR FR1074575D patent/FR1074575A/en not_active Expired
- 1952-10-29 GB GB27226/52A patent/GB723715A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116337A (en) * | 1960-09-06 | 1963-12-31 | Pennsalt Chemicals Corp | Process for the preparation of fluorinated olefins |
US3118005A (en) * | 1960-12-27 | 1964-01-14 | Attila E Pavlath | Titania catalyzed dehydrofluorination of 1, 1, 1-difluorochloro alkanes |
Also Published As
Publication number | Publication date |
---|---|
FR1074575A (en) | 1954-10-06 |
CH307970A (en) | 1955-06-30 |
BE513162A (en) |
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