GB603256A - Process of manufacture of glycol - Google Patents

Process of manufacture of glycol

Info

Publication number
GB603256A
GB603256A GB26043/45A GB2604345A GB603256A GB 603256 A GB603256 A GB 603256A GB 26043/45 A GB26043/45 A GB 26043/45A GB 2604345 A GB2604345 A GB 2604345A GB 603256 A GB603256 A GB 603256A
Authority
GB
United Kingdom
Prior art keywords
hydration
ethylene oxide
glycol
decomposed
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26043/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of GB603256A publication Critical patent/GB603256A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ethylene glycol is prepared by the hydration of ethylene oxide in the presence of a trihalogenoacetic acid which is subsequently removed from the reaction product by thermal decomposition. In an example, ethylene oxide is hydrated at about 60 DEG C. in the presence of trichloroacetic acid which is subsequently decomposed into chloroform and carbon dioxide by heating at 100 DEG C., and p ethylene glycol is separated from di- and triethylene glycol by fractional distillation. The Specification as open to inspection under Sect. 91 states that the hydration may be effected in the presence of any organic acid which can be decomposed at a temperature above the hydration temperature of ethylene oxide. This subject-matter does not appear in the Specification as accepted.
GB26043/45A 1942-12-24 1945-10-05 Process of manufacture of glycol Expired GB603256A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE603256X 1942-12-24

Publications (1)

Publication Number Publication Date
GB603256A true GB603256A (en) 1948-06-11

Family

ID=3874229

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26043/45A Expired GB603256A (en) 1942-12-24 1945-10-05 Process of manufacture of glycol

Country Status (1)

Country Link
GB (1) GB603256A (en)

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