GB552061A - Improvements in or relating to the preparation of organic phosphinous acids - Google Patents
Improvements in or relating to the preparation of organic phosphinous acidsInfo
- Publication number
- GB552061A GB552061A GB1200041A GB1200041A GB552061A GB 552061 A GB552061 A GB 552061A GB 1200041 A GB1200041 A GB 1200041A GB 1200041 A GB1200041 A GB 1200041A GB 552061 A GB552061 A GB 552061A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- phosphinous
- organic
- preparation
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RYIOLWQRQXDECZ-UHFFFAOYSA-N phosphinous acid Chemical class PO RYIOLWQRQXDECZ-UHFFFAOYSA-N 0.000 title abstract 3
- YGHRJJRRZDOVPD-UHFFFAOYSA-N 3-methylbutanal Chemical compound CC(C)CC=O YGHRJJRRZDOVPD-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- YXOFLQYROLMFCC-UHFFFAOYSA-N 3-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one phosphinous acid Chemical compound PO.OC1C(C2(CCC1C2(C)C)C)=O YXOFLQYROLMFCC-UHFFFAOYSA-N 0.000 abstract 1
- CRDRZQIIEIADSD-UHFFFAOYSA-N [hydroxy(phenyl)methyl]phosphinous acid Chemical compound OPC(O)C1=CC=CC=C1 CRDRZQIIEIADSD-UHFFFAOYSA-N 0.000 abstract 1
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- -1 oxymethylene camphor Chemical class 0.000 abstract 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/4816—Acyclic saturated acids or derivatices which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
552,061. Organic phosphinous acids. ABBEY, A. (Siegfried, Ltd., B.). Sept. 18, 1941, No. 12000. [A Specification was laid open to inspection under Sect. 91 of the Acts, April 29, 1942.] [Class 2 (iii)] Organic phosphinous acids and their salts of the formula R-CH(OH)-P(OH) 2 where R is an organic radical are prepared by reaction of hypophosphorous acid with aldehydes at 50- 60‹C. in concentrated solution. Examples are given of the preparation of α-hydroxybenzylphosphinous acid, which is a strongly acting toxic, from benzaldehyde, sodium salt of metaxyl - dialpha - hydroxyphosphinous acid from isophthalic aldehyde, sodium salt of hydroxy-camphor phosphinous acid from oxymethylene camphor, hydroxy - oenanthylic - phosphinous acid from oenanthic aldehyde, the plumbate being first formed, and hydroxyisoamylic-phosphinous acid from isovalericaldehyde Snd 80-82 per cent. hypophosphorous acid in each case.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1200041A GB552061A (en) | 1941-09-18 | 1941-09-18 | Improvements in or relating to the preparation of organic phosphinous acids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1200041A GB552061A (en) | 1941-09-18 | 1941-09-18 | Improvements in or relating to the preparation of organic phosphinous acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB552061A true GB552061A (en) | 1943-03-22 |
Family
ID=9996585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1200041A Expired GB552061A (en) | 1941-09-18 | 1941-09-18 | Improvements in or relating to the preparation of organic phosphinous acids |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB552061A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2579810A (en) * | 1949-08-18 | 1951-12-25 | Research Corp | Process of preparing substituted hydroxymethylphosphonic esters |
| US2758971A (en) * | 1952-05-20 | 1956-08-14 | Exxon Research Engineering Co | Blending agents for mineral oils |
| EP0544345A1 (en) * | 1991-11-23 | 1993-06-02 | Fmc Corporation (Uk) Limited | Corrosion and/or scale inhibition |
-
1941
- 1941-09-18 GB GB1200041A patent/GB552061A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2579810A (en) * | 1949-08-18 | 1951-12-25 | Research Corp | Process of preparing substituted hydroxymethylphosphonic esters |
| US2758971A (en) * | 1952-05-20 | 1956-08-14 | Exxon Research Engineering Co | Blending agents for mineral oils |
| EP0544345A1 (en) * | 1991-11-23 | 1993-06-02 | Fmc Corporation (Uk) Limited | Corrosion and/or scale inhibition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES397611A1 (en) | Zirconium rinse for phosphate coated metal surfaces | |
| GB496252A (en) | Improvements relating to photographic treating solutions | |
| GB552061A (en) | Improvements in or relating to the preparation of organic phosphinous acids | |
| GB952411A (en) | Improvements in offset printing | |
| GB1383939A (en) | Battery electrolyte composition | |
| GB1198829A (en) | Process for Preparing Pyrryl-(2)-Acetic Acid Esters | |
| GB563019A (en) | Improvements in the manufacture of plaster of paris | |
| DE722339C (en) | Process for producing an azo compound containing the arseno group | |
| FR2027873A1 (en) | Electrodeposition of ruthenium | |
| GB932523A (en) | Process for the production of lead hydroxide oxide of the formula 5 pbo.2ho | |
| IE34307B1 (en) | New 1-alkyl-6-azauracil compounds and preparations which contain a 1-alkyl-6-azauracil compound as an active ingredient | |
| GB535739A (en) | Improvements in and relating to acid-resistant cements and concretes | |
| GB1315564A (en) | Nickel salts of phosphonic acid monoesters | |
| GB562269A (en) | Improvements relating to the production of copolymers of divinyl sulphide and butadiene | |
| GB560859A (en) | Improvements in insulin preparations | |
| GB543897A (en) | Manufacture of pharmaceutical and veterinary preparations | |
| GB564154A (en) | Detoxicants | |
| GB298101A (en) | Manufacture of derivatives of the triarylmethane series | |
| GB529382A (en) | Manufacture of derivatives of aliphatic amino-sulphonic acids | |
| USD135483S (en) | Design for a vane pump | |
| Baird et al. | Inotropic effects of thyroxine and related compounds on guinea‐pig left atria in vitro | |
| GB727007A (en) | New semicarbazones | |
| JPS5422303A (en) | Preparation of alcohols | |
| GB474518A (en) | Improvements in or relating to cleansing agents | |
| GB556901A (en) | Sulphone derivatives |