GB407944A - Improvements in or relating to the production of ethylene from ethyl alcohol and ethyl alcohol from ethylene - Google Patents
Improvements in or relating to the production of ethylene from ethyl alcohol and ethyl alcohol from ethyleneInfo
- Publication number
- GB407944A GB407944A GB2666032A GB2666032A GB407944A GB 407944 A GB407944 A GB 407944A GB 2666032 A GB2666032 A GB 2666032A GB 2666032 A GB2666032 A GB 2666032A GB 407944 A GB407944 A GB 407944A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- ethyl alcohol
- catalyst
- alcohol
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The catalytic hydration of ethylene to produce alcohol and the catalytic dehydration of alcohol to produce ethylene are effected in the presence of strontium metaphosphate which may be employed alone, viz. in association with known catalysts and/or with supports such as pumice or asbestos. The reactions are preferably effected in the vapour phase, and pressure may be employed especially for the hydration of ethylene, 100 atmospheres being mentioned. The catalyst may be prepared by heating one molecular proportion of strontium carbonate with two molecular proportions of aqueous phosphoric acid the mixture being evaporated to dryness and dried at a temperature not above 300 DEG C. In examples: (1) ethyl alcohol is passed over the catalyst at 250 DEG C. and atmospheric pressure; (2) a mixture of 70 volumes of ethylene and 30 volumes of steam is passed over the catalyst at 290 DEG C. and 100 atmospheres pressure.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2666032A GB407944A (en) | 1932-09-26 | 1932-09-26 | Improvements in or relating to the production of ethylene from ethyl alcohol and ethyl alcohol from ethylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2666032A GB407944A (en) | 1932-09-26 | 1932-09-26 | Improvements in or relating to the production of ethylene from ethyl alcohol and ethyl alcohol from ethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
GB407944A true GB407944A (en) | 1934-03-26 |
Family
ID=10247155
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2666032A Expired GB407944A (en) | 1932-09-26 | 1932-09-26 | Improvements in or relating to the production of ethylene from ethyl alcohol and ethyl alcohol from ethylene |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB407944A (en) |
-
1932
- 1932-09-26 GB GB2666032A patent/GB407944A/en not_active Expired
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