GB2318360A - Fluorescent whitening agent formulation - Google Patents
Fluorescent whitening agent formulation Download PDFInfo
- Publication number
- GB2318360A GB2318360A GB9621421A GB9621421A GB2318360A GB 2318360 A GB2318360 A GB 2318360A GB 9621421 A GB9621421 A GB 9621421A GB 9621421 A GB9621421 A GB 9621421A GB 2318360 A GB2318360 A GB 2318360A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formulation
- formulation according
- formula
- s03na
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 238000009472 formulation Methods 0.000 title claims abstract description 68
- 239000006081 fluorescent whitening agent Substances 0.000 title claims abstract description 42
- 239000003599 detergent Substances 0.000 claims abstract description 17
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 11
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000000129 anionic group Chemical group 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- 239000002798 polar solvent Substances 0.000 claims abstract description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 44
- 150000001875 compounds Chemical class 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 17
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- -1 methoxy, phenoxy Chemical group 0.000 claims description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000006184 cosolvent Substances 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 3
- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 125000000066 S-methyl group Chemical group [H]C([H])([H])S* 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000002979 fabric softener Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 1
- 239000012669 liquid formulation Substances 0.000 description 14
- 239000013543 active substance Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 239000004435 Oxo alcohol Substances 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229940113165 trimethylolpropane Drugs 0.000 description 8
- 239000002002 slurry Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004440 Isodecyl alcohol Substances 0.000 description 1
- 239000004439 Isononyl alcohol Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9621421A GB2318360A (en) | 1996-10-15 | 1996-10-15 | Fluorescent whitening agent formulation |
| TW086112472A TW400379B (en) | 1996-10-15 | 1997-08-30 | Fluorescent whitening agent formulation |
| EP97810741A EP0837124B1 (en) | 1996-10-15 | 1997-10-06 | Fluorescent whitening agent formulation |
| ES97810741T ES2210486T3 (es) | 1996-10-15 | 1997-10-06 | Formulacion de agente blanqueante fluorescente. |
| DE69726544T DE69726544T2 (de) | 1996-10-15 | 1997-10-06 | Fluoreszierende Weisstöner-Formulierung |
| MX9707800A MX9707800A (es) | 1996-10-15 | 1997-10-10 | Composicion de agente blanqueador fluorescente. |
| CNB971204411A CN1165606C (zh) | 1996-10-15 | 1997-10-14 | 荧光增白剂制剂 |
| IDP973434A ID18528A (id) | 1996-10-15 | 1997-10-14 | Formulasi bahan pemutih fluoresen |
| KR1019970052433A KR100503774B1 (ko) | 1996-10-15 | 1997-10-14 | 형광증백제조성물및이의제조방법 |
| BR9705030A BR9705030A (pt) | 1996-10-15 | 1997-10-14 | Formulação de agente fluorescente de branqueamento |
| ZA9709178A ZA979178B (en) | 1996-10-15 | 1997-10-14 | Fluorescent whitening agent formulation. |
| AU41000/97A AU732991B2 (en) | 1996-10-15 | 1997-10-14 | Fluorescent whitening agent formulation |
| JP9280987A JPH10152695A (ja) | 1996-10-15 | 1997-10-15 | 蛍光増白剤調合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9621421A GB2318360A (en) | 1996-10-15 | 1996-10-15 | Fluorescent whitening agent formulation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB9621421D0 GB9621421D0 (en) | 1996-12-04 |
| GB2318360A true GB2318360A (en) | 1998-04-22 |
Family
ID=10801404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9621421A Withdrawn GB2318360A (en) | 1996-10-15 | 1996-10-15 | Fluorescent whitening agent formulation |
Country Status (13)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001012771A1 (en) * | 1999-08-16 | 2001-02-22 | Ciba Specialty Chemicals Holding Inc. | Liquid fluorescent whitening agent formulation |
| ES2271534T3 (es) * | 2002-02-25 | 2007-04-16 | Ciba Specialty Chemicals Holding Inc. | Procedimiento para el tratamiento de materiales de fibras textiles. |
| CA2534896A1 (en) * | 2003-09-19 | 2005-03-31 | Ciba Specialty Chemicals Holding Inc. | Aqueous solutions of fluorescent whitening agents |
| KR100689260B1 (ko) * | 2005-05-24 | 2007-03-02 | 삼원산업주식회사 | 항산화성 스틸벤계 형광증백제 및 이의 합성방법 |
| KR101421622B1 (ko) * | 2012-06-29 | 2014-07-23 | 삼원산업주식회사 | 항산화성 스틸벤계 형광증백의 합성방법 |
| WO2015106449A1 (en) | 2014-01-20 | 2015-07-23 | The Procter & Gamble Company | Fluorescent brightener premix |
| CN104862120A (zh) * | 2015-04-09 | 2015-08-26 | 广州立白企业集团有限公司 | 一种洗涤剂用荧光增白剂水溶液的制备方法 |
| CN105238099B (zh) * | 2015-10-12 | 2017-07-07 | 山西青山化工有限公司 | 一种增白皂用液体荧光增白剂及其制备方法 |
| CN106087384A (zh) * | 2016-06-21 | 2016-11-09 | 太仓市东明化工有限公司 | 一种织物用耐水型荧光增白剂 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298490A (en) * | 1978-12-22 | 1981-11-03 | Ciba-Geigy Corporation | Process for the production of washing powders of stabilized or enhanced appearance which contain fluorescent whitening agents |
| GB2172608A (en) * | 1985-03-19 | 1986-09-24 | Colgate Palmolive Co | Stable soil release promoting enzymatic liquid detergent composition |
| US4764302A (en) * | 1986-10-21 | 1988-08-16 | The Clorox Company | Thickening system for incorporating fluorescent whitening agents |
| US5149463A (en) * | 1989-04-21 | 1992-09-22 | The Clorox Company | Thickened acidic liquid composition with sulfonate fwa useful as a bleaching agent vehicle |
| EP0577557A1 (de) * | 1992-06-30 | 1994-01-05 | Ciba-Geigy Ag | Hydrate des 4,4'-Bis-(2-sulfostyryl)-biphenyl-dinatrium oder -dikalium Salzes |
| WO1995009216A1 (en) * | 1993-09-27 | 1995-04-06 | The Clorox Company | Improved thickening system for incorporating fluorescent whitening agents |
| WO1995013358A1 (en) * | 1993-11-11 | 1995-05-18 | Unilever Plc | Process for the production of a detergent composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953380A (en) * | 1970-10-28 | 1976-04-27 | Colgate-Palmolive Company | Liquid detergent |
| ES2053807T3 (es) * | 1987-11-27 | 1994-08-01 | Ciba Geigy Ag | Dispersion blanqueadora acuosa y procedimiento para su preparacion. |
| EP0427670A1 (de) * | 1989-11-07 | 1991-05-15 | Ciba-Geigy Ag | Flüssigwaschmittel |
| IT1237754B (it) * | 1989-11-08 | 1993-06-17 | Sigma Prodotti Chimici Srl | Composizione liquida di candeggiante ottico. |
| CH682748A5 (de) * | 1991-11-07 | 1993-11-15 | Ciba Geigy Ag | Lagerstabile Formulierung von optischen Aufhellermischungen. |
| KR0161894B1 (ko) * | 1991-11-08 | 1999-01-15 | 구자홍 | 스크롤 압축기 |
| CH686959A5 (de) * | 1992-12-22 | 1996-08-15 | Ciba Geigy Ag | Lagerstabile Formulierung von optischen Aufhellern. |
| JPH07286198A (ja) * | 1994-04-15 | 1995-10-31 | Lion Corp | 粒状ノニオン洗剤組成物の製造方法 |
| IT1270004B (it) * | 1994-09-23 | 1997-04-16 | 3V Sigma Spa | "formulazioni di candeggianti ottici" |
| GB9509291D0 (en) * | 1995-05-06 | 1995-06-28 | Ciba Geigy Ag | Formulations |
-
1996
- 1996-10-15 GB GB9621421A patent/GB2318360A/en not_active Withdrawn
-
1997
- 1997-08-30 TW TW086112472A patent/TW400379B/zh not_active IP Right Cessation
- 1997-10-06 DE DE69726544T patent/DE69726544T2/de not_active Expired - Fee Related
- 1997-10-06 ES ES97810741T patent/ES2210486T3/es not_active Expired - Lifetime
- 1997-10-06 EP EP97810741A patent/EP0837124B1/en not_active Expired - Lifetime
- 1997-10-10 MX MX9707800A patent/MX9707800A/es active IP Right Grant
- 1997-10-14 BR BR9705030A patent/BR9705030A/pt not_active IP Right Cessation
- 1997-10-14 KR KR1019970052433A patent/KR100503774B1/ko not_active Expired - Fee Related
- 1997-10-14 CN CNB971204411A patent/CN1165606C/zh not_active Expired - Fee Related
- 1997-10-14 ID IDP973434A patent/ID18528A/id unknown
- 1997-10-14 AU AU41000/97A patent/AU732991B2/en not_active Ceased
- 1997-10-14 ZA ZA9709178A patent/ZA979178B/xx unknown
- 1997-10-15 JP JP9280987A patent/JPH10152695A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298490A (en) * | 1978-12-22 | 1981-11-03 | Ciba-Geigy Corporation | Process for the production of washing powders of stabilized or enhanced appearance which contain fluorescent whitening agents |
| GB2172608A (en) * | 1985-03-19 | 1986-09-24 | Colgate Palmolive Co | Stable soil release promoting enzymatic liquid detergent composition |
| US4764302A (en) * | 1986-10-21 | 1988-08-16 | The Clorox Company | Thickening system for incorporating fluorescent whitening agents |
| US5149463A (en) * | 1989-04-21 | 1992-09-22 | The Clorox Company | Thickened acidic liquid composition with sulfonate fwa useful as a bleaching agent vehicle |
| EP0577557A1 (de) * | 1992-06-30 | 1994-01-05 | Ciba-Geigy Ag | Hydrate des 4,4'-Bis-(2-sulfostyryl)-biphenyl-dinatrium oder -dikalium Salzes |
| WO1995009216A1 (en) * | 1993-09-27 | 1995-04-06 | The Clorox Company | Improved thickening system for incorporating fluorescent whitening agents |
| WO1995013358A1 (en) * | 1993-11-11 | 1995-05-18 | Unilever Plc | Process for the production of a detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0837124A2 (en) | 1998-04-22 |
| KR100503774B1 (ko) | 2005-10-13 |
| ZA979178B (en) | 1998-04-15 |
| BR9705030A (pt) | 1999-06-15 |
| ID18528A (id) | 1998-04-16 |
| TW400379B (en) | 2000-08-01 |
| JPH10152695A (ja) | 1998-06-09 |
| DE69726544T2 (de) | 2004-09-30 |
| CN1165606C (zh) | 2004-09-08 |
| EP0837124B1 (en) | 2003-12-03 |
| ES2210486T3 (es) | 2004-07-01 |
| AU4100097A (en) | 1998-04-23 |
| CN1179466A (zh) | 1998-04-22 |
| EP0837124A3 (en) | 1999-01-20 |
| DE69726544D1 (de) | 2004-01-15 |
| GB9621421D0 (en) | 1996-12-04 |
| AU732991B2 (en) | 2001-05-03 |
| MX9707800A (es) | 1998-04-30 |
| KR19980032785A (ko) | 1998-07-25 |
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| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |