GB1569514A - Pesticidal composition and process for its preparation - Google Patents
Pesticidal composition and process for its preparation Download PDFInfo
- Publication number
- GB1569514A GB1569514A GB4291/78A GB429178A GB1569514A GB 1569514 A GB1569514 A GB 1569514A GB 4291/78 A GB4291/78 A GB 4291/78A GB 429178 A GB429178 A GB 429178A GB 1569514 A GB1569514 A GB 1569514A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphide
- silicon
- composition according
- hydrophobic
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 92
- 238000000034 method Methods 0.000 title claims description 28
- 230000000361 pesticidal effect Effects 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 11
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 66
- 229910052751 metal Inorganic materials 0.000 claims abstract description 49
- 239000002184 metal Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 10
- 125000005843 halogen group Chemical group 0.000 claims abstract description 9
- 238000009877 rendering Methods 0.000 claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 24
- -1 methyl hydrogen Chemical compound 0.000 claims description 21
- 239000003054 catalyst Substances 0.000 claims description 19
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 18
- PPNXXZIBFHTHDM-UHFFFAOYSA-N aluminium phosphide Chemical compound P#[Al] PPNXXZIBFHTHDM-UHFFFAOYSA-N 0.000 claims description 18
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 claims description 18
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 18
- 239000005952 Aluminium phosphide Substances 0.000 claims description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 13
- 239000004202 carbamide Substances 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- PGYDGBCATBINCB-UHFFFAOYSA-N 4-diethoxyphosphoryl-n,n-dimethylaniline Chemical compound CCOP(=O)(OCC)C1=CC=C(N(C)C)C=C1 PGYDGBCATBINCB-UHFFFAOYSA-N 0.000 claims description 7
- 239000006009 Calcium phosphide Substances 0.000 claims description 7
- 239000005953 Magnesium phosphide Substances 0.000 claims description 7
- 238000002474 experimental method Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 150000002902 organometallic compounds Chemical class 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 150000003868 ammonium compounds Chemical class 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical group [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 3
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 3
- 239000001099 ammonium carbonate Substances 0.000 claims description 3
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims description 3
- 230000002452 interceptive effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000011369 resultant mixture Substances 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- PZGVVCOOWYSSGB-KWZUVTIDSA-L (z)-but-2-enedioate;dioctyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC PZGVVCOOWYSSGB-KWZUVTIDSA-L 0.000 claims 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims 1
- 239000012975 dibutyltin dilaurate Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 238000007792 addition Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 239000013043 chemical agent Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2705228A DE2705228C2 (de) | 1977-02-08 | 1977-02-08 | Hydrophobiertes, Phosphorwasserstoff entwickelndes Schädlingsbekämpfungsmittel und Verfahren zu seiner Herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1569514A true GB1569514A (en) | 1980-06-18 |
Family
ID=6000627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4291/78A Expired GB1569514A (en) | 1977-02-08 | 1978-02-02 | Pesticidal composition and process for its preparation |
Country Status (12)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4503032A (en) * | 1979-12-18 | 1985-03-05 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf | Hydrogen-phosphide releasing compositions and their use |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4146619A (en) * | 1977-05-31 | 1979-03-27 | Block Drug Company Inc. | Siloxane toxicants |
| JPS611A (ja) * | 1984-06-11 | 1986-01-06 | Kumiai Chem Ind Co Ltd | 農薬粉剤組成物 |
| JPS6445903U (enrdf_load_stackoverflow) * | 1987-09-17 | 1989-03-22 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1542877C3 (de) * | 1966-05-27 | 1982-07-15 | Veb Delicia, Ddr 7270 Delitzsch | Formkörper mit hydrolisierbaren Phosphiden |
| DE2002655A1 (de) * | 1970-01-22 | 1971-07-29 | Deutsche Ges Schaedlingsbek | Schaedlingsbekaempfungsmittel und Verfahren zu seiner Herstellung |
| DE2443333B2 (de) * | 1974-09-11 | 1977-09-01 | Deutsche Gesellschaft für Schädlingsbekämpfung mbH, 6000 Frankfurt | Phosphinentwickelndes schaedlingsbekaempfungsmittel und verfahren zu seiner herstellung |
-
1977
- 1977-02-08 DE DE2705228A patent/DE2705228C2/de not_active Expired
- 1977-12-05 ZA ZA00777233A patent/ZA777233B/xx unknown
-
1978
- 1978-02-02 GB GB4291/78A patent/GB1569514A/en not_active Expired
- 1978-02-02 CA CA296,180A patent/CA1103151A/en not_active Expired
- 1978-02-07 RO RO7893127A patent/RO76148A/ro unknown
- 1978-02-07 CH CH135578A patent/CH645245A5/de not_active IP Right Cessation
- 1978-02-07 JP JP1205578A patent/JPS53124616A/ja active Granted
- 1978-02-07 MX MX786826U patent/MX5333E/es unknown
- 1978-02-07 DD DD78203593A patent/DD136569A5/xx not_active IP Right Cessation
- 1978-02-07 AR AR271020A patent/AR219101A1/es active
- 1978-02-07 IL IL53986A patent/IL53986A/xx unknown
- 1978-02-08 ES ES466775A patent/ES466775A1/es not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4503032A (en) * | 1979-12-18 | 1985-03-05 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf | Hydrogen-phosphide releasing compositions and their use |
| US4720380A (en) * | 1979-12-18 | 1988-01-19 | Dr. Werner Freyberg Chemische Febrik Delitia Naschf. | Hydrogen-phosphide releasing compositions and processes for their production and use |
Also Published As
| Publication number | Publication date |
|---|---|
| MX5333E (es) | 1983-06-24 |
| DE2705228C2 (de) | 1986-04-03 |
| IL53986A (en) | 1985-02-28 |
| ZA777233B (en) | 1979-08-29 |
| JPS53124616A (en) | 1978-10-31 |
| CH645245A5 (en) | 1984-09-28 |
| IL53986A0 (en) | 1978-04-30 |
| AR219101A1 (es) | 1980-07-31 |
| RO76148A (ro) | 1981-08-17 |
| CA1103151A (en) | 1981-06-16 |
| ES466775A1 (es) | 1978-10-01 |
| DD136569A5 (de) | 1979-07-18 |
| JPS6233203B2 (enrdf_load_stackoverflow) | 1987-07-20 |
| DE2705228A1 (de) | 1978-08-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |