GB1427966A - Heat-processable photographic silver salt material - Google Patents
Heat-processable photographic silver salt materialInfo
- Publication number
- GB1427966A GB1427966A GB2836473A GB2836473A GB1427966A GB 1427966 A GB1427966 A GB 1427966A GB 2836473 A GB2836473 A GB 2836473A GB 2836473 A GB2836473 A GB 2836473A GB 1427966 A GB1427966 A GB 1427966A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thione
- silver
- heat
- methylthiazoline
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 3
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 title abstract 3
- NLHAIPFBNQZTMY-UHFFFAOYSA-N 4-methyl-3h-1,3-thiazole-2-thione Chemical compound CC1=CSC(S)=N1 NLHAIPFBNQZTMY-UHFFFAOYSA-N 0.000 abstract 3
- 241001061127 Thione Species 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- -1 silver halide Chemical class 0.000 abstract 3
- 238000011065 in-situ storage Methods 0.000 abstract 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 1
- FDDDTDSPQXLQFY-UHFFFAOYSA-N 1-methylimidazolidine-2-thione Chemical compound CN1CCNC1=S FDDDTDSPQXLQFY-UHFFFAOYSA-N 0.000 abstract 1
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical compound C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 abstract 1
- YVHAVWLNPPSAOG-UHFFFAOYSA-N 3-(2-sulfanylidene-3h-benzimidazol-1-yl)propanoic acid Chemical compound C1=CC=C2NC(=S)N(CCC(=O)O)C2=C1 YVHAVWLNPPSAOG-UHFFFAOYSA-N 0.000 abstract 1
- VUUGNEJAZJKDCM-UHFFFAOYSA-N 3-(2-sulfanylideneimidazolidin-1-yl)propanoic acid Chemical compound C(=O)(O)CCN1C(NCC1)=S VUUGNEJAZJKDCM-UHFFFAOYSA-N 0.000 abstract 1
- CEXKMXQBLPBNMK-UHFFFAOYSA-N 4-(hydroxymethyl)-5h-1,3-thiazole-2-thione Chemical compound OCC1=NC(=S)SC1 CEXKMXQBLPBNMK-UHFFFAOYSA-N 0.000 abstract 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 abstract 1
- 229940100890 silver compound Drugs 0.000 abstract 1
- 150000003379 silver compounds Chemical class 0.000 abstract 1
- KZJPVUDYAMEDRM-UHFFFAOYSA-M silver;2,2,2-trifluoroacetate Chemical compound [Ag+].[O-]C(=O)C(F)(F)F KZJPVUDYAMEDRM-UHFFFAOYSA-M 0.000 abstract 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49809—Organic silver compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/133—Binder-free emulsion
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
1427966 Heat processable photographic silver halide material EASTMAN KODAK CO 14 June 1973 [14 June 1972] 28364/73 Heading G2C A sensitive photographic material comprises a support coated on one side with a heat-processable photo-sensitive composition containing a photographic silver halide, a reducing agent and a silver salt of a thione having the Formula:- where R' completes an optionally substituted heterocyclic nucleus having a 5-membered heterocyclic ring and Z is optionally substituted 1-10C alkylene, the components of the photo-sensitive composition being in one or more layers. R' may complete a 4-methylthiazoline -2-thione, benzothiazoline -2-thione, 5-phenyl-1,3, 4, oxadiazoline-2-thione, 5-phenyl-1,3,4,-thiadiazoline -2-thione, 4-methylthiazoline-2-thione, 1-phenyl- 1,3,4,- triazoline -2-thione, 1-(2-carboxyethyl) imidazoline -2-thione, 1-(2-carboxyethyl) benzimidazoline -2-thione, 1-methylimidazoline -2-thione, benzoxazoline -2-thione, 4-methylthiazoline -2- thione or 4-(hydroxymethyl)- thiazoline -2-thione. Z may be methylene, ethylene or propylene. The silver salt of the thione may be formed in situ from the thione and a soluble silver compound e.g. silver trifluoroacetate. The silver halide may be silver bromide or iodide and may be formed in situ. Sulpholane (thiocyclopentane -1-dioxide) may be used as a toner (Ex 3). U.K. Specification 1280724 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26290772A | 1972-06-14 | 1972-06-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1427966A true GB1427966A (en) | 1976-03-10 |
Family
ID=22999580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2836473A Expired GB1427966A (en) | 1972-06-14 | 1973-06-14 | Heat-processable photographic silver salt material |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3785830A (en) |
| JP (1) | JPS5234451B2 (en) |
| BE (1) | BE800925A (en) |
| CA (1) | CA1007091A (en) |
| DE (1) | DE2329170A1 (en) |
| FR (1) | FR2188191B1 (en) |
| GB (1) | GB1427966A (en) |
| IT (1) | IT985421B (en) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4201582A (en) * | 1974-05-02 | 1980-05-06 | Eastman Kodak Company | Photothermographic and thermographic element, composition and process |
| US3893860A (en) * | 1974-07-16 | 1975-07-08 | Eastman Kodak Co | Photothermographic element and process |
| US4022617A (en) * | 1974-07-25 | 1977-05-10 | Eastman Kodak Company | Photothermographic element, composition and process for producing a color image from leuco dye |
| JPS51106173U (en) * | 1975-02-22 | 1976-08-25 | ||
| US4105451A (en) * | 1976-12-22 | 1978-08-08 | Eastman Kodak Company | Photothermographic material, composition and process |
| US4123274A (en) * | 1977-03-16 | 1978-10-31 | Eastman Kodak Company | Heat developable imaging materials and process |
| US4161408A (en) * | 1977-06-06 | 1979-07-17 | Minnesota Mining And Manufacturing Company | Method for the preparation of a photothermographic system |
| US4168980A (en) * | 1977-08-19 | 1979-09-25 | Eastman Kodak Company | Heat developable photographic material and process |
| US4186009A (en) * | 1978-05-30 | 1980-01-29 | Eastman Kodak Company | Covering power photothermographic material and process |
| US4283477A (en) * | 1978-11-02 | 1981-08-11 | Eastman Kodak Company | Photothermographic material and process |
| US4235957A (en) * | 1979-01-25 | 1980-11-25 | Eastman Kodak Company | Thermal silver-dye bleach element and process |
| US5240809A (en) * | 1992-04-20 | 1993-08-31 | Minnesota Mining And Manufacturing Company | Imageable articles having dye selective interlayers |
| US5238792A (en) * | 1992-04-20 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Imageable articles having dye selective interlayers |
| US5264321A (en) * | 1992-07-16 | 1993-11-23 | Minnesota Mining And Manufacturing Company | Photothermographic elements with novel layer structures |
| US5275927A (en) * | 1992-07-16 | 1994-01-04 | Minnesota Mining And Manufacturing Company | Photothermographic articles containing novel barrier layers |
| US5262272A (en) * | 1992-10-08 | 1993-11-16 | Minnesota Mining And Manufacturing Company | Dye permeable polymer interlayers |
| US5369000A (en) * | 1993-04-29 | 1994-11-29 | Minnesota Mining And Manufacturing Company | Post-processing stabilizers for photothermographic articles |
| US6171707B1 (en) | 1994-01-18 | 2001-01-09 | 3M Innovative Properties Company | Polymeric film base having a coating layer of organic solvent based polymer with a fluorinated antistatic agent |
| US5492805A (en) * | 1994-06-30 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Blocked leuco dyes for photothermographic elements |
| US5492804A (en) * | 1994-06-30 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Chromogenic leuco redox-dye-releasing compounds for photothermographic elements |
| US5928857A (en) * | 1994-11-16 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Photothermographic element with improved adherence between layers |
| US5492803A (en) * | 1995-01-06 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Hydrazide redox-dye-releasing compounds for photothermographic elements |
| US6132949A (en) * | 1996-12-25 | 2000-10-17 | Fuji Photo Film Co., Ltd. | Photothermographic material |
| US5891615A (en) * | 1997-04-08 | 1999-04-06 | Imation Corp. | Chemical sensitization of photothermographic silver halide emulsions |
| US5939249A (en) * | 1997-06-24 | 1999-08-17 | Imation Corp. | Photothermographic element with iridium and copper doped silver halide grains |
| DE60113974T3 (en) * | 2000-01-19 | 2011-03-17 | Sekisui Chemical Co., Ltd. | A heat-developable photosensitive material comprising a polyvinyl acetal resin |
| JP2002006445A (en) | 2000-06-27 | 2002-01-09 | Konica Corp | Heat developable photosensitive material |
| KR100897079B1 (en) * | 2001-09-21 | 2009-05-14 | 세키스이가가쿠 고교가부시키가이샤 | Modified Polyvinyl Acetal Resin |
| US20040053173A1 (en) * | 2002-09-18 | 2004-03-18 | Eastman Kodak Company | Photothermographic materials containing high iodide emulsions |
| US7468241B1 (en) | 2007-09-21 | 2008-12-23 | Carestream Health, Inc. | Processing latitude stabilizers for photothermographic materials |
| US7524621B2 (en) * | 2007-09-21 | 2009-04-28 | Carestream Health, Inc. | Method of preparing silver carboxylate soaps |
| US7622247B2 (en) * | 2008-01-14 | 2009-11-24 | Carestream Health, Inc. | Protective overcoats for thermally developable materials |
| US9335623B2 (en) | 2014-03-24 | 2016-05-10 | Carestream Health, Inc. | Thermally developable imaging materials |
| US9523915B2 (en) | 2014-11-04 | 2016-12-20 | Carestream Health, Inc. | Image forming materials, preparations, and compositions |
| US9746770B2 (en) | 2015-06-02 | 2017-08-29 | Carestream Health, Inc. | Thermally developable imaging materials and methods |
| WO2017123444A1 (en) | 2016-01-15 | 2017-07-20 | Carestream Health, Inc. | Method of preparing silver carboxylate soaps |
-
1972
- 1972-06-14 US US00262907A patent/US3785830A/en not_active Expired - Lifetime
-
1973
- 1973-05-11 CA CA171,001A patent/CA1007091A/en not_active Expired
- 1973-06-07 DE DE2329170A patent/DE2329170A1/en active Pending
- 1973-06-08 FR FR7320890A patent/FR2188191B1/fr not_active Expired
- 1973-06-11 IT IT50695/73A patent/IT985421B/en active
- 1973-06-14 GB GB2836473A patent/GB1427966A/en not_active Expired
- 1973-06-14 BE BE132280A patent/BE800925A/en not_active IP Right Cessation
- 1973-06-14 JP JP48067335A patent/JPS5234451B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2188191B1 (en) | 1978-11-17 |
| US3785830A (en) | 1974-01-15 |
| BE800925A (en) | 1973-12-14 |
| CA1007091A (en) | 1977-03-22 |
| FR2188191A1 (en) | 1974-01-18 |
| DE2329170A1 (en) | 1973-12-20 |
| JPS5234451B2 (en) | 1977-09-03 |
| JPS4952626A (en) | 1974-05-22 |
| IT985421B (en) | 1974-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |