GB1400824A - Process of colouring glass bodies - Google Patents
Process of colouring glass bodiesInfo
- Publication number
- GB1400824A GB1400824A GB4212772A GB4212772A GB1400824A GB 1400824 A GB1400824 A GB 1400824A GB 4212772 A GB4212772 A GB 4212772A GB 4212772 A GB4212772 A GB 4212772A GB 1400824 A GB1400824 A GB 1400824A
- Authority
- GB
- United Kingdom
- Prior art keywords
- medium
- ions
- glass
- treatment
- metal ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/005—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to introduce in the glass such metals or metallic ions as Ag, Cu
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Abstract
1400824 Colouring glass GLAVERBEL 11 Sept 1972 [1 Oct 1971] 42127/72 Heading C1M [Also in Division B5] A process of colouring or modifying the colouration of a glass body containing reducing ions by causing a substance to diffuse into surface layers of the glass body from a contacting medium is characterized in that the said medium comprises a mixture of metal salts containing not more than 50% by weight of a salt providing reducible metal ions of a type capable of being reduced by said reducing ions, and in that after diffusion of reducible metal ions into said body from said medium, the final colouration is achieved by heating the body to a temperature above the strain point of the glass. The glass body may be formed from a soda-lime glass. The reduction is not relied upon for achieving the final colouration and in some cases there is no significant colouration of the glass body at the end of the first treatment stage. The process finds particular application in colouring bodies of flat soda-lime glass which may be produced by the so-called "float" process in which the reducing ions (Sn<SP>++</SP>) diffuse into the glass from the molten material the glass floats on. Alternatively the glass contains the reducing ions (Fe<SP>++</SP>) prior to being drawn into a glass body using a conventional drawing machine. The treatment medium may contain less than 10% by weight of salt(s) providing the reducible metal ions and such ions are wholly or predominantly silver ions. Such ions produce a yellow colouration. Other reducible metal ions used are of copper and gold. Preferably the treatment medium is a salt medium in molten state, the medium being agitated if necessary as by propellers or bubbling gas therethrough. However the treatment medium may comprise the mixture of metal salts in vapourifed condition. The molten medium may be sprayed on to the body, but preferably the body is immersed in a quantity of the molten medium. Only part of the surface of the body (flat or curved sheet) may be coloured or modified in colour and in such cases those parts of the surface not to be so modified are shielded from the treatment medium by a temporary coating. In further alternatives the medium may be kept in contact with the surface portion to be treated by retaining such medium within an endless retaining wall contacting the body along the boundary of the surface area to be treated or the medium may be caused to stream along the surface area to be coloured. The treatment medium advantageously contains one or more zinc salts which promote the diffusion of the reducible metal ions into the surface of the glass body. The said reducible metal ions preferably derive from a metal salt selected from nitrates, chlorides and sulphates. The balance of the treatment medium comprises alkali metal salts, e.g. NaNO 3 , KNO 3 , Na 2 SO 4 , K 2 SO 4 . When silver salts are used in the treatment medium the first treatment step is preferably carried out while the body is at a temperature less than 350 C.; in the second step the body is heated to a temperature of at least 500 C. after the diffusion of reducible metal ions thereon. The colouration development in the second stage may be promoted by bringing the treated surface of the body into contact with a reducing gas, e.g. H 2 . The salt with which the salt providing the said reducible metal ions is mixed may comprise a metal salt providing metal ions which diffuse into the glass body in exchange for other ions. After heating the glass body the body may be rapidly cooled to produce compressive surface stresses therein. In one embodiment during the heating of the body while at a temperature above the strain point of the glass ions, e.g. Li<SP>+</SP>, which confer a lower coefficient of thermal expansion on surface layers of said body are caused to diffuse into such surface layers in exchange for other ions. The body may be tempered either during or subsequent to the colouring treatment. During the final heat treatment the body may be bent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IE129272A IE36958B1 (en) | 1971-10-01 | 1972-09-21 | Process of colouring glass bodies |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU63992 | 1971-10-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1400824A true GB1400824A (en) | 1975-07-23 |
Family
ID=19726840
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4212672A Expired GB1400823A (en) | 1971-10-01 | 1972-09-11 | Process of forming coloured glass bodies |
GB4212772A Expired GB1400824A (en) | 1971-10-01 | 1972-09-11 | Process of colouring glass bodies |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4212672A Expired GB1400823A (en) | 1971-10-01 | 1972-09-11 | Process of forming coloured glass bodies |
Country Status (25)
Country | Link |
---|---|
JP (2) | JPS4843715A (en) |
AR (1) | AR198188A1 (en) |
AT (2) | AT324605B (en) |
AU (2) | AU472167B2 (en) |
BE (2) | BE789068A (en) |
BG (1) | BG22378A3 (en) |
BR (2) | BR7206799D0 (en) |
CA (2) | CA1006699A (en) |
CH (2) | CH557309A (en) |
CS (2) | CS174855B2 (en) |
DD (2) | DD100928A5 (en) |
DE (2) | DE2247992A1 (en) |
DK (1) | DK135344B (en) |
ES (2) | ES407281A1 (en) |
FR (2) | FR2161901B1 (en) |
GB (2) | GB1400823A (en) |
HU (2) | HU166704B (en) |
IL (2) | IL40403A (en) |
IT (2) | IT975072B (en) |
NL (2) | NL7213185A (en) |
NO (2) | NO132797C (en) |
PL (1) | PL82050B1 (en) |
RO (2) | RO61175A (en) |
SE (2) | SE380246B (en) |
ZA (2) | ZA726555B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0691199A3 (en) * | 1994-07-05 | 1996-05-01 | Ppg Industries Inc | Composite transparency |
CN109071333A (en) * | 2016-04-29 | 2018-12-21 | 陆逊梯卡有限公司 | Method and relevant glass lens for coloured glass eyeglass |
CN110104965A (en) * | 2019-05-22 | 2019-08-09 | 深圳市东丽华科技有限公司 | With soda acid durability chemically reinforced glass and preparation method thereof |
CN114291801A (en) * | 2021-11-17 | 2022-04-08 | 河北光兴半导体技术有限公司 | Solid electrolyte material, preparation method thereof and all-solid-state battery |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4017318A (en) * | 1976-01-02 | 1977-04-12 | Corning Glass Works | Photosensitive colored glasses |
DE2758581C2 (en) * | 1977-12-29 | 1980-01-03 | Bfg Glassgroup, Paris | Windshields, in particular for motor vehicles, with an inner pane made of chemically toughened silicate glass |
JPS6241010Y2 (en) * | 1979-06-22 | 1987-10-20 | ||
JPS5914413B2 (en) * | 1980-12-09 | 1984-04-04 | セントラル硝子株式会社 | How to color plate glass |
JPS58190841A (en) * | 1982-04-30 | 1983-11-07 | Okuno Seiyaku Kogyo Kk | Composition of coloring agent for glass |
JPS60122751U (en) * | 1984-01-30 | 1985-08-19 | 東京電力株式会社 | feeding device |
EP1894899A1 (en) * | 2006-08-31 | 2008-03-05 | Corning Incorporated | Glass articles and process for making the same |
ES2303783B1 (en) * | 2007-01-26 | 2009-07-06 | Universidad De Granada | COLOR PROCEDURE IN COMMON GLASSES OF CALCICO SODIUM SILICATE BY THERMAL TREATMENT. |
DE102008052339B4 (en) * | 2008-10-20 | 2020-09-03 | Ferro Gmbh | Process for coloring temperature-resistant substrates |
KR102299069B1 (en) | 2017-09-06 | 2021-09-07 | 후지필름 가부시키가이샤 | drug receptor |
EP3768280A4 (en) * | 2018-05-08 | 2022-05-18 | Rise Nano Optics Ltd. | Products using gold and silver nanoparticles and ions to absorb visible and uv light |
US11994755B2 (en) | 2021-10-28 | 2024-05-28 | Rise Nano Optics Ltd. | Diffusion of nanoparticles into transparent plastic |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1297144A (en) * | 1961-03-13 | 1962-06-29 | Saint Gobain | Glass coloring process |
FR1395436A (en) * | 1963-05-24 | 1965-04-09 | Ici Ltd | Glass reinforcement and protection process |
GB1107886A (en) * | 1964-06-23 | 1968-03-27 | Pilkington Brothers Ltd | Improvements in or relating to glass articles |
FR1449761A (en) * | 1964-06-23 | 1966-05-06 | Pilkington Brothers Ltd | Improvements to glass articles, and to processes for their manufacture and treatment |
NL6500068A (en) * | 1965-01-06 | 1966-07-07 | ||
US3495963A (en) * | 1965-04-13 | 1970-02-17 | Ppg Industries Inc | Simultaneous staining and strengthening of glass |
-
1972
- 1972-09-11 GB GB4212672A patent/GB1400823A/en not_active Expired
- 1972-09-11 GB GB4212772A patent/GB1400824A/en not_active Expired
- 1972-09-19 DK DK461572AA patent/DK135344B/en unknown
- 1972-09-19 SE SE7212071A patent/SE380246B/en unknown
- 1972-09-19 NO NO3345/72A patent/NO132797C/no unknown
- 1972-09-19 SE SE7212070A patent/SE386430B/en unknown
- 1972-09-19 NO NO3346/72A patent/NO133586C/no unknown
- 1972-09-20 HU HUGA1114A patent/HU166704B/hu unknown
- 1972-09-20 HU HUGA1115A patent/HU166228B/hu unknown
- 1972-09-20 IL IL40403A patent/IL40403A/en unknown
- 1972-09-20 IL IL40405A patent/IL40405A/en unknown
- 1972-09-21 BE BE789068A patent/BE789068A/xx unknown
- 1972-09-21 FR FR7233598A patent/FR2161901B1/fr not_active Expired
- 1972-09-21 BE BE789069A patent/BE789069A/xx unknown
- 1972-09-21 FR FR7233597A patent/FR2165855B1/fr not_active Expired
- 1972-09-22 CH CH1387172A patent/CH557309A/en not_active IP Right Cessation
- 1972-09-22 AU AU46981/72A patent/AU472167B2/en not_active Expired
- 1972-09-22 AU AU46980/72A patent/AU473684B2/en not_active Expired
- 1972-09-22 CH CH1387272A patent/CH557310A/en not_active IP Right Cessation
- 1972-09-22 BG BG21448A patent/BG22378A3/xx unknown
- 1972-09-25 IT IT70019/72A patent/IT975072B/en active
- 1972-09-25 IT IT70020/72A patent/IT975073B/en active
- 1972-09-26 ZA ZA726555A patent/ZA726555B/en unknown
- 1972-09-26 AT AT827372A patent/AT324605B/en not_active IP Right Cessation
- 1972-09-26 AT AT827472A patent/AT326293B/en not_active IP Right Cessation
- 1972-09-26 ZA ZA726556A patent/ZA726556B/en unknown
- 1972-09-27 ES ES407281A patent/ES407281A1/en not_active Expired
- 1972-09-27 ES ES407280A patent/ES407280A1/en not_active Expired
- 1972-09-28 RO RO72357A patent/RO61175A/ro unknown
- 1972-09-28 RO RO72355A patent/RO61173A/ro unknown
- 1972-09-28 NL NL7213185A patent/NL7213185A/xx not_active Application Discontinuation
- 1972-09-28 CA CA152,837A patent/CA1006699A/en not_active Expired
- 1972-09-28 CS CS6606A patent/CS174855B2/cs unknown
- 1972-09-28 CA CA152,838A patent/CA1006700A/en not_active Expired
- 1972-09-28 NL NL7213184A patent/NL7213184A/xx not_active Application Discontinuation
- 1972-09-28 CS CS6605A patent/CS174854B2/cs unknown
- 1972-09-29 PL PL1972158004A patent/PL82050B1/pl unknown
- 1972-09-29 DD DD165951A patent/DD100928A5/xx unknown
- 1972-09-29 BR BR6799/72A patent/BR7206799D0/en unknown
- 1972-09-29 DD DD165949A patent/DD101376A5/xx unknown
- 1972-09-29 JP JP47098567A patent/JPS4843715A/ja active Pending
- 1972-09-29 DE DE19722247992 patent/DE2247992A1/en active Pending
- 1972-09-29 DE DE19722247991 patent/DE2247991A1/en active Pending
- 1972-09-29 BR BR6802/72A patent/BR7206802D0/en unknown
- 1972-09-29 JP JP47098566A patent/JPS4843714A/ja active Pending
- 1972-09-29 AR AR244403A patent/AR198188A1/en active
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0691199A3 (en) * | 1994-07-05 | 1996-05-01 | Ppg Industries Inc | Composite transparency |
US5792559A (en) * | 1994-07-05 | 1998-08-11 | Ppg Industries, Inc. | Composite transparency |
CN109071333A (en) * | 2016-04-29 | 2018-12-21 | 陆逊梯卡有限公司 | Method and relevant glass lens for coloured glass eyeglass |
CN110104965A (en) * | 2019-05-22 | 2019-08-09 | 深圳市东丽华科技有限公司 | With soda acid durability chemically reinforced glass and preparation method thereof |
CN114291801A (en) * | 2021-11-17 | 2022-04-08 | 河北光兴半导体技术有限公司 | Solid electrolyte material, preparation method thereof and all-solid-state battery |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
435 | Patent endorsed 'licences of right' on the date specified (sect. 35/1949) | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |