GB1117971A - Unsaturated hydrocarbon compounds and process for their preparation - Google Patents

Unsaturated hydrocarbon compounds and process for their preparation

Info

Publication number
GB1117971A
GB1117971A GB1060466A GB1060466A GB1117971A GB 1117971 A GB1117971 A GB 1117971A GB 1060466 A GB1060466 A GB 1060466A GB 1060466 A GB1060466 A GB 1060466A GB 1117971 A GB1117971 A GB 1117971A
Authority
GB
United Kingdom
Prior art keywords
compound
decatriene
prepared
preparation
cyclobutene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1060466A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA, Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montedison SpA
Publication of GB1117971A publication Critical patent/GB1117971A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/06—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a four-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/31—Rearrangement of carbon atoms in the hydrocarbon skeleton changing the number of rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises per se the compound (A) of formula <FORM:1117971/C4-C5/1> and the compound (B) of formula <FORM:1117971/C4-C5/2> compound (A), named 3-(5-hexenyl)-cyclobutene, is prepared by irradiating trans-1,3,9-decatriene, preferably with u/v light at 10-50 DEG C. in the presence of an ether or hydrocarbon solvent. Compound (B), named 4-methyl-3-(41-pentenyl)-cyclobutene, is prepared by irradiating 2,4,9-decatriene under similar conditions. The starting material for compound (B), 2,4,9-decatriene, is prepared by heating 1,4,9-decatriene at 40-200 DEG C. in the presence of an alkali metal compound, e.g. NaOH, KOH or an alcoholate, to effect isomerization, optionally in the additional presence of a reaction medium which may be a mono- or poly-alcohol, or an ether, or a mixture of any of these with dimethyl sulphoxide.
GB1060466A 1965-03-16 1966-03-10 Unsaturated hydrocarbon compounds and process for their preparation Expired GB1117971A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT575965 1965-03-16
IT2665065 1965-12-02

Publications (1)

Publication Number Publication Date
GB1117971A true GB1117971A (en) 1968-06-26

Family

ID=26325722

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1060466A Expired GB1117971A (en) 1965-03-16 1966-03-10 Unsaturated hydrocarbon compounds and process for their preparation

Country Status (1)

Country Link
GB (1) GB1117971A (en)

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