GB615404A - A process for the preparation of unsaturated derivatives of 2-methyl-2-hydroxy-3-halogen-teterahydrofurane and for their conversion to vitamin b and the like - Google Patents
A process for the preparation of unsaturated derivatives of 2-methyl-2-hydroxy-3-halogen-teterahydrofurane and for their conversion to vitamin b and the likeInfo
- Publication number
- GB615404A GB615404A GB12641/41A GB1264141A GB615404A GB 615404 A GB615404 A GB 615404A GB 12641/41 A GB12641/41 A GB 12641/41A GB 1264141 A GB1264141 A GB 1264141A GB 615404 A GB615404 A GB 615404A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- hydroxy
- halogen
- vitamin
- unsaturated derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/20—Oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Unsaturated derivatives of 2 - methyl - 2 - hydroxy-3-halogen-tetrahydrofuranes containing one molecule of water less than the parent compound are prepared and converted to Vitamin B1 by a process which comprises subjecting 2-methyl-2,3-dihalogen-tetrahydrofuranes or reaction mixtures containing these compounds to the action of reagents which are capable of splitting of halide acid, e.g. pyridine and, if desired, subjecting to the action of 2-alkyl-4-amino-5-(thioformanidoalkyl)-pyrimidine to produce Vitamin B1. The unsaturated derivatives of 2-methyl-2-hydroxy-3-halogen-tetrahydrofuranes containing one molecule of water less than the parent compound may also be prepared by treating aceto-chloro-propyl alcohol with phosphorous halogenides and treating the reaction mixture with agents capable of splitting off a halide acid. Detailed examples are given. Specification 609,803 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU615404X | 1940-05-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB615404A true GB615404A (en) | 1949-01-06 |
Family
ID=10979760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12641/41A Expired GB615404A (en) | 1940-05-27 | 1941-09-30 | A process for the preparation of unsaturated derivatives of 2-methyl-2-hydroxy-3-halogen-teterahydrofurane and for their conversion to vitamin b and the like |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB615404A (en) |
-
1941
- 1941-09-30 GB GB12641/41A patent/GB615404A/en not_active Expired
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