GB1111708A - Antimicrobial detergent compositions - Google Patents

Antimicrobial detergent compositions

Info

Publication number
GB1111708A
GB1111708A GB34225/66A GB3422566A GB1111708A GB 1111708 A GB1111708 A GB 1111708A GB 34225/66 A GB34225/66 A GB 34225/66A GB 3422566 A GB3422566 A GB 3422566A GB 1111708 A GB1111708 A GB 1111708A
Authority
GB
United Kingdom
Prior art keywords
alkyl
ammonium chloride
surfactants
weight
total composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34225/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1111708A publication Critical patent/GB1111708A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4933Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having sulfur as an exocyclic substituent, e.g. pyridinethione
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/006Antidandruff preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines or polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Casting Devices For Molds (AREA)
  • Detergent Compositions (AREA)

Abstract

An antimicrobial detergent composition comprises (a) an organic surfactant; (b) a water-soluble cationic polymer selected from the group consisting of polyethyleneimines and alkoxylated polyethylenimines having molecular weight greater than 100; and (c) a particulate heavy metal salt of 2-pyridinethiol-1-oxide. For (a), anionic organic surfactants, e.g. alkyl glyceryl ether sulphonates, N-acyl sarcosinates, alkyl ether ethylene oxide sulphates, soaps and lower alkanolamine salts of fatty acids; polar nonionic surfactants, e.g. amine and phosphine oxides; and amphoteric surfactants, e.g. alkyl beta-iminodipropionates, alkyl beta-aminopropionates and certain long chain imidazole derivatives, are preferably used, excellent results being obtained with a mixture of from 4 to 20% by weight of the total composition of (i) a non-soap organic anionic surfactant; and (ii) a polar nonionic, zwitterionic or amophoteric surfactant. Nonionic surfactants, e.g. "Pluronics" (Registered Trade Mark), polyethylene oxide condensates of alkyl phenols, condensates of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine or with aliphatic alcohols; and cationic surfactants, e.g. distearyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, coconut alkyl dimethyl benzyl ammonium chloride, dicoconut alkyl dimethyl ammonium chloride, cetyl pyridinium chloride and cetyl trimethyl ammonium bromide, may also be used for (a). The polymers (b) preferably have a molecular weight within the range from 3000 to 100,000 and are preferably employed at a concentration within the range from 0.25 to 2.00% by weight of the total composition. The preferred salts for (c) are zinc, cadmium, tin and zirconium 2-pyridinethiol-1-oxides and are preferably used in the range from 0.5 to 2.0% by weight of the total composition. Additional additives include organic solvents, such as ethanol; thickeners, e.g. carboxymethyl cellulose, magnesium aluminium silicate, hydroxyethyl- or methyl-celluslose; perfumes; sequestering agents such as tetra-sodium ethylenediamine tetraacetate; opacifiers such as zinc or magnesium stearate; suds boosters such as coconut acyl mono- or diethanolamides; and salts such as sodium chloride or sulphate.ALSO:Antimicrobial detergent compositions particularly useful in the treatment of dandruff comprise (a) an organic surfactant, (b) a water-soluble cationic polymer selected from the group consisting of polyethylenimines and alkoxylated polyethylenimines having molecular weight greater than 100, and (c) a particulate heavy metal salt of 2-pyridinethiol-1-oxide. For (a), anionic organic surfactants, e.g. alkyl glyceryl ether sulphonates, N-acyl sarcosinates, alkyl ether ethylene oxide sulphates, soaps and lower alkanolamine salts of fatty acids; polar nonionic surfactants, e.g. amine and phosphine oxides; and amphoteric surfactants, e.g. alkyl beta-iminodipropionates, alkyl beta-aminopropionates and certain long chain imidazole derivatives, are preferably used, excellent results being obtained with a mixture of from 4 to 20% by weight of the total composition of (i) a non-soap organic anionic surfactant and (ii) a polar nonionic, zuritherionic or amphoteric surfactant. Nonionic surfactants, e.g. "Pluronics" (trade mark), polyethylene oxide condensates of alkyl phenols, condensates of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine or with aliphatic alcohols; and cationic surfactants, e.g. distearyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, coconut alkyl dimethyl benzyl ammonium chloride, dicoconut alkyl dimethyl ammonium chloride, cetyl pyridinium chloride and cetyl trimethyl ammonium chloride, may also be used for (a) the polymers (b) preferably have a molecular weight within the range from 3,000 to 100,000 and are preferably employed at a concentration within the range from 0.25 to 2.00% by weight of the total composition. The preferred salts for (c) are zinc, cadmium, tin and zirconium 2-pyridinethiol-1-oxides and are preferably used in the range from 0.5 to 2.0% by weight of the total composition. Additional additives include organic solvents, such as ethanol; thickeners, e.g. carboxymethyl cellulose, magnesium aluminium silicate, hydroxyethyl-or methyl-cellulose; perfumes; sequestering agents such as tetra-sodium ethylenediamine tetraacetate, opacifiers such as zinc or magnesium stearate; suds boosters such as coconut acyl mono- or diethanolamides; and salts such as sodium chloride or sulphate.
GB34225/66A 1965-07-30 1966-07-29 Antimicrobial detergent compositions Expired GB1111708A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US47617565A 1965-07-30 1965-07-30

Publications (1)

Publication Number Publication Date
GB1111708A true GB1111708A (en) 1968-05-01

Family

ID=23890808

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34225/66A Expired GB1111708A (en) 1965-07-30 1966-07-29 Antimicrobial detergent compositions

Country Status (12)

Country Link
BE (1) BE702495A (en)
CA (1) CA810625A (en)
CH (1) CH478233A (en)
DE (1) DE1617179C3 (en)
DK (1) DK129097B (en)
FI (1) FI46737C (en)
FR (1) FR1506349A (en)
GB (1) GB1111708A (en)
NL (1) NL146051B (en)
NO (1) NO121293B (en)
SE (1) SE344209B (en)
ZA (1) ZA687526B (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE31126E (en) 1975-01-06 1983-01-18 Alberto-Culver Company Quaternary ammonium compounds in pretreatment of hair before shampooing with an anionic shampoo
GB2135332A (en) * 1983-02-18 1984-08-30 Johnson & Johnson Baby Prod Detergent compositions
GB2147606A (en) * 1983-10-04 1985-05-15 Procter & Gamble Anti-dandruff compositions
US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
US4551506A (en) 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4597898A (en) * 1982-12-23 1986-07-01 The Proctor & Gamble Company Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties
US4659802A (en) 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4661288A (en) 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4664848A (en) 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
WO1996022074A1 (en) * 1995-01-20 1996-07-25 The Procter & Gamble Company Anti-dandruff shampoos with particulate active agent and cationic polymer
US5565145A (en) * 1994-05-25 1996-10-15 The Procter & Gamble Company Compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers as soil dispersing agents
GB2315770A (en) * 1996-07-31 1998-02-11 Procter & Gamble Conditioning shampoo compositions comprising polyalkoxylated polyalkyleneamine
WO2000033807A1 (en) * 1998-12-10 2000-06-15 Unilever Plc Washing compositions
EP1226814A1 (en) * 1999-11-04 2002-07-31 Kao Corporation Detergent composition
WO2003039499A1 (en) * 2001-11-02 2003-05-15 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
WO2004043860A1 (en) * 2002-11-14 2004-05-27 Ineos Silicas Limited Silicate compositions
US10081781B2 (en) 2015-08-21 2018-09-25 Ecolab Usa Inc. Pyrithione preservative system in solid rinse aid products

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE755674A (en) * 1969-09-04 1971-03-03 Oreal NEW COMPOUNDS DERIVED FROM PYRIDINE AND COSMETIC COMPOSITIONS CONTAINING THEM
FR2123148A1 (en) * 1971-01-25 1972-09-08 Contier Marcel Anti seborrhoeic compsns - contg cadmium sulphide and zinc pyridine thione
GB1390004A (en) * 1972-03-27 1975-04-09 Olin Corp Laundering method using a biocidal composition comprising a mercaptopyridine-1-oxide compound and a quaternary ammonium compound
LU65997A1 (en) * 1972-09-05 1974-03-14
AT352295B (en) * 1975-03-18 1979-09-10 Pharma Vertrieb Ag DISINFECTANT
GB1547361A (en) * 1975-03-24 1979-06-13 Unilever Ltd Hair shampoos
EP0007704A3 (en) * 1978-07-28 1980-02-20 Beecham Group Plc Method of preparing a hair conditioning product
JPS60139613A (en) * 1983-12-27 1985-07-24 Kao Corp Dispersion of antimicrobial agent and antimicrobial hair treatment composition
JPH0621050B2 (en) * 1985-07-11 1994-03-23 尚子 浮田 Antidandruff shampoo
CN100544704C (en) 1999-06-25 2009-09-30 宝洁公司 Topical anti-microbial compositions
EP3618616B8 (en) * 2017-05-03 2024-09-04 Wacker Chemie AG Antimicrobial nonwoven wet wipe bonded with a nonionic binder

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE31126E (en) 1975-01-06 1983-01-18 Alberto-Culver Company Quaternary ammonium compounds in pretreatment of hair before shampooing with an anionic shampoo
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
US4551506A (en) 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4597898A (en) * 1982-12-23 1986-07-01 The Proctor & Gamble Company Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties
US4659802A (en) 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4661288A (en) 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4664848A (en) 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
GB2135332A (en) * 1983-02-18 1984-08-30 Johnson & Johnson Baby Prod Detergent compositions
US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
GB2147606A (en) * 1983-10-04 1985-05-15 Procter & Gamble Anti-dandruff compositions
US5565145A (en) * 1994-05-25 1996-10-15 The Procter & Gamble Company Compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers as soil dispersing agents
AU713104B2 (en) * 1995-01-20 1999-11-25 Procter & Gamble Company, The Anti-dandruff shampoos with particulate active agent and cationic polymer
WO1996022074A1 (en) * 1995-01-20 1996-07-25 The Procter & Gamble Company Anti-dandruff shampoos with particulate active agent and cationic polymer
GB2315770A (en) * 1996-07-31 1998-02-11 Procter & Gamble Conditioning shampoo compositions comprising polyalkoxylated polyalkyleneamine
US6348188B1 (en) * 1998-12-10 2002-02-19 Unilever Home & Personal Care Usa Washing compositions
WO2000033807A1 (en) * 1998-12-10 2000-06-15 Unilever Plc Washing compositions
EP1226814A1 (en) * 1999-11-04 2002-07-31 Kao Corporation Detergent composition
EP1226814A4 (en) * 1999-11-04 2003-03-05 Kao Corp Detergent composition
US6624126B1 (en) 1999-11-04 2003-09-23 Kao Corporation Personal cleansing composition comprising a glyceryl ether
US6849584B2 (en) 2001-11-02 2005-02-01 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
WO2003039499A1 (en) * 2001-11-02 2003-05-15 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
WO2004043860A1 (en) * 2002-11-14 2004-05-27 Ineos Silicas Limited Silicate compositions
US10081781B2 (en) 2015-08-21 2018-09-25 Ecolab Usa Inc. Pyrithione preservative system in solid rinse aid products
US10781403B2 (en) 2015-08-21 2020-09-22 Ecolab Usa Inc. Pyrithione preservative system in solid rinse aid products
US10865363B2 (en) 2015-08-21 2020-12-15 Ecolab Usa Inc. Pyrithione preservative system in solid rinse aid products
US11312925B2 (en) 2015-08-21 2022-04-26 Ecolab Usa Inc. Pyrithione preservative system and C1-C12 ethoxylated alcohol in hard surface cleaning products
US11680229B2 (en) 2015-08-21 2023-06-20 Ecolab Usa Inc. Pyrithione preservative system and C1-C12 ethoxylated alcohol in solid rinse aid compositions

Also Published As

Publication number Publication date
FI46737B (en) 1973-02-28
CA810625A (en) 1969-04-15
SE344209B (en) 1972-04-04
NO121293B (en) 1971-02-08
FI46737C (en) 1973-06-11
NL6700896A (en) 1968-07-22
DE1617179A1 (en) 1971-02-18
ZA687526B (en)
DK129097B (en) 1974-08-19
BE702495A (en) 1968-02-09
DE1617179B2 (en) 1973-12-06
DE1617179C3 (en) 1974-07-18
CH478233A (en) 1969-09-15
NL146051B (en) 1975-06-16
FR1506349A (en) 1967-12-22

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