GB1195158A - Detergent Compositions containing Substantially Water-Insoluble Particulate Solids - Google Patents

Detergent Compositions containing Substantially Water-Insoluble Particulate Solids

Info

Publication number
GB1195158A
GB1195158A GB46028/68A GB4602868A GB1195158A GB 1195158 A GB1195158 A GB 1195158A GB 46028/68 A GB46028/68 A GB 46028/68A GB 4602868 A GB4602868 A GB 4602868A GB 1195158 A GB1195158 A GB 1195158A
Authority
GB
United Kingdom
Prior art keywords
polymer
water
sodium
quaternized
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB46028/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1195158A publication Critical patent/GB1195158A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4933Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having sulfur as an exocyclic substituent, e.g. pyridinethione
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0036Soil deposition preventing compositions; Antiredeposition agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines or polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/225Polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/006Antidandruff preparations

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

1,195,158. Detergent compositions. PROCTER & GAMBLE CO. 27 Sept., 1968 [27 Sept., 1967], No. 46028/68. Heading C5D. A detergent composition comprises (1) an organic surfactant, (2) a water-soluble cationic nitrogen-containing polymer having a molecular weight from 2000-3,000,000 and a cationic charge density greater than 0À001, said polymer being (a) a quaternary-ammoniumsubstituted cellulose ether derivative, (b) a polymer at least 30 mole per cent of the molecular structure of which is composed of quaternizedvinylimidazole, quaternized diethylaminoethyl acrylate, quaternized dimethylaminoethyl methacrylate or quaternized p-dimethylaminomethyl styrene monomeric units, or a combination thereof, (c) a linear polyamine at least 50 mole per cent of the molecular structure of which is composed of monomeric units of the structure in which A is alkylene (C 2-3 ) of which at least two carbon atoms extend in a chain between the adjoining nitrogen atoms and R and R<SP>1</SP> are each hydrogen or methyl, or (d) a polymer of tetraethylene pentamine and epichlorohydrin having the structure in which x is an integer such that the polymer has viscosity of 21-42 centipoises at 74‹ F., and (3) a water-insoluble or sparingly soluble particulate substance capable of imparting a desired residual property to a surface to which it becomes affixed. In a modification, the water-soluble cationic nitrogen-containing polymer may be a polyalkylene polyamine with repeating -C-C-N groups in a highly branched structure or a water-soluble dimethyldialkyl quaternary ammonium chloride. The preferred water-insoluble or sparingly soluble particulate substances are heavy metal salts of 2 - pyridinethiol - 1 - oxide, 3,4,4<SP>1 </SP>- trichlorocarbanilide, 3,4,5 - tribromosalicylanilide, 4,4<SP>1</SP>- dichloro - 3 - (trifluoromethyl) carbanilide, bis - (2 - hydroxy - 3,5,6 - trichlorophenyl) methane, N - trichloromethylmercapto - 4 - cyclohexene - 1,2 - dicarboximide, N - (1,1<SP>1</SP>, 2,2<SP>1 </SP>- tetrachloroethylsulphenyl) - cis - A - 4 - cyclohexene - 1,2 - dicarboximide or mixtures thereof, which have anti-microbial, fabric brightening or whitening properties and which create a favourable skin feel after washing. The organic surfactant may be any amphoteric, anionic, polar non-ionic, non-ionic, zwittenonic or cationic. Additional additives include organic solvents, e.g. ethanol; thickeners, e.g. carboxymethylcellulose, magnesium aluminium silicate, hydroxyethylcellulose or methylcellulose; perfumes; sequestering agents, e.g. E.D.T.A. (Na salt); opacifiers, e.g. zinc or magnesium stearate; suds boosters, e.g. coconut acyl mono- or di-ethanolamides; salts, e.g. sodium chloride, sodium sulphate, or sodium carbonate; bases, e.g. sodium hydroxide or potassium hydroxide; sodium tripolyphosphate; potassium toluenesulphonate; dyes, e.g. ultramarine blue; diphosphonates; potassium silicate or sodium silicates; tarnish inhibitors, e.g. benzotriazole. The composition may be in granular, flake, liquid or tablet form.
GB46028/68A 1967-09-27 1968-09-27 Detergent Compositions containing Substantially Water-Insoluble Particulate Solids Expired GB1195158A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US67111767A 1967-09-27 1967-09-27

Publications (1)

Publication Number Publication Date
GB1195158A true GB1195158A (en) 1970-06-17

Family

ID=24693193

Family Applications (1)

Application Number Title Priority Date Filing Date
GB46028/68A Expired GB1195158A (en) 1967-09-27 1968-09-27 Detergent Compositions containing Substantially Water-Insoluble Particulate Solids

Country Status (12)

Country Link
US (1) US3580853A (en)
JP (1) JPS4720635B1 (en)
AT (1) AT310905B (en)
BE (1) BE721384A (en)
BR (1) BR6802634D0 (en)
CH (1) CH531041A (en)
DE (1) DE1792618C3 (en)
FR (1) FR1588952A (en)
GB (1) GB1195158A (en)
IT (1) IT1046452B (en)
NL (1) NL6813826A (en)
SE (1) SE353738B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4237016A (en) 1977-11-21 1980-12-02 The Procter & Gamble Company Textile conditioning compositions with low content of cationic materials
EP0047714A2 (en) * 1980-09-05 1982-03-17 Ciba-Geigy Ag Mixtures of polymeric high-molecular acrylic quaternary ammonium salts and detergents, their preparation and use in cosmetic formulations
EP0627217A2 (en) * 1993-05-17 1994-12-07 Helene Curtis, Inc. Stable conditioning shampoo having a high foam level containing a silicone conditioner, a cationic quaternary acrylate copolymer, an anionic surfactant and polyethyleneimine
DE102008001770A1 (en) * 2008-05-13 2009-11-19 Beiersdorf Ag Cosmetic preparations for dandruff
DE102005063339B4 (en) * 2005-10-18 2012-01-12 Henkel Ag & Co. Kgaa Use of halide-poor polymer solutions with cationic amino groups

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US3876760A (en) * 1969-10-23 1975-04-08 Bristol Myers Co Hair dressing compositions containing a hair substantive quaternary resin
US3912808A (en) * 1970-02-25 1975-10-14 Gillette Co Hair waving and straightening process and composition containing water-soluble amino and quaternary ammonium polymers
US4166845A (en) * 1970-11-16 1979-09-04 Colgate-Palmolive Company Antidandruff shampoo compositions containing an aminopolyureylene resin
US3940482A (en) * 1971-04-21 1976-02-24 Colgate-Palmolive Company Solubilization of the zinc salt of 1-hydroxy-2-pyridinethione
US3862310A (en) * 1971-12-22 1975-01-21 Gillette Co Cosmetic compositions containing formylated polyethylene polyamine
US3986825A (en) * 1972-06-29 1976-10-19 The Gillette Company Hair coloring composition containing water-soluble amino and quaternary ammonium polymers
US3959463A (en) * 1972-07-10 1976-05-25 Bristol-Myers Company Hair dressing compositions containing a hair substantive quaternary resin
US3950510A (en) * 1972-08-01 1976-04-13 Lever Brothers Company Conditioning shampoo containing a water-insoluble hair cosmetic agent
AT330930B (en) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES
CA1016464A (en) * 1973-06-22 1977-08-30 Terry Gerstein Shampoo conditioner formulations
US4009256A (en) * 1973-11-19 1977-02-22 National Starch And Chemical Corporation Novel shampoo composition containing a water-soluble cationic polymer
US3964500A (en) * 1973-12-26 1976-06-22 Lever Brothers Company Lusterizing shampoo containing a polysiloxane and a hair-bodying agent
US3962150A (en) * 1974-04-10 1976-06-08 Richardson-Merrell Inc. Foam producing cleansing compositions
GB1553201A (en) * 1975-04-18 1979-09-26 Colgate Palmolive Co Method of cleaning glass or glazed articles
US4027008A (en) * 1975-05-14 1977-05-31 The Gillette Company Hair bleaching composition containing water-soluble amino and quaternary ammonium polymers
US4089945A (en) * 1975-06-30 1978-05-16 The Procter & Gamble Company Antidandruff shampoos containing metallic cation complex to reduce in-use sulfide odor
GB1584364A (en) * 1976-06-21 1981-02-11 Unilever Ltd Shampoo
US4061602A (en) * 1976-08-03 1977-12-06 American Cyanamid Company Conditioning shampoo composition containing a cationic derivative of a natural gum (such as guar) as the active conditioning ingredient
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US4206195A (en) * 1978-06-06 1980-06-03 The Procter & Gamble Company Hair conditioning article and a method of its use
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DE2905257A1 (en) * 1979-02-12 1980-08-21 Wella Ag HAIR TREATMENT
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US4551506A (en) * 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4659802A (en) * 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4661288A (en) * 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
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US5104646A (en) * 1989-08-07 1992-04-14 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
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ATE131033T1 (en) * 1991-03-19 1995-12-15 Procter & Gamble COSMETIC COMPOSITIONS CONTAINING HYDROPHOBIC MODIFIED POLYMERS AND UNSATURATED QUATERNAER AMMONIUM SURFACTANTS.
US5807543A (en) * 1993-08-27 1998-09-15 The Procter & Gamble Co. Cosmetic compositions containing hydrophobically modified nonionic polymer and unsaturated quaternary ammonium surfactant
US5277899A (en) * 1991-10-15 1994-01-11 The Procter & Gamble Company Hair setting composition with combination of cationic conditioners
US5861367A (en) * 1993-08-04 1999-01-19 Colgate Palmolive Company Cleaning and disinfecting composition in microemulsion/liquid crystal form comprising aldehyde and mixture of partially esterified, fully esterified and non-esterified polyhydric alcohols
US5741760A (en) * 1993-08-04 1998-04-21 Colgate-Palmolive Company Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide-polydimethyl siloxane
US5731281A (en) * 1993-08-04 1998-03-24 Colgate-Palmolive Company Microemulsion liquid crystal cleaning compositions comprising esterified and non-esterfied ethoxylated glycerol mixture and sulfoxy anionic surfactant
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US5441664A (en) * 1993-11-15 1995-08-15 Colgate Palmolive Co. Gelled hard surface cleaning composition
US6103644A (en) 1993-12-22 2000-08-15 Nordico Marketing Development, Inc. Impregnated matrix and method for making same
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JPS4720635B1 (en) 1972-06-12
DE1792618B2 (en) 1977-07-07
AT310905B (en) 1973-10-25
DE1792618A1 (en) 1971-11-25
BE721384A (en) 1969-03-25
DE1792618C3 (en) 1978-03-02
SE353738B (en) 1973-02-12
US3580853A (en) 1971-05-25
IT1046452B (en) 1980-06-30
FR1588952A (en) 1970-03-16
BR6802634D0 (en) 1973-01-02
NL6813826A (en) 1969-03-31
CH531041A (en) 1972-11-30

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