GB641297A - Germicidal detergent compositions - Google Patents

Germicidal detergent compositions

Info

Publication number
GB641297A
GB641297A GB5130/48A GB513048A GB641297A GB 641297 A GB641297 A GB 641297A GB 5130/48 A GB5130/48 A GB 5130/48A GB 513048 A GB513048 A GB 513048A GB 641297 A GB641297 A GB 641297A
Authority
GB
United Kingdom
Prior art keywords
alkyl
phenols
sodium
surface active
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5130/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Publication of GB641297A publication Critical patent/GB641297A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A wetting agent having germicidal detergent properties comprises a mixture of an organic anionic detergent, an organic cationic germicide and a water-soluble non-ionic surface active agent containing a polyglycol ether group, said anionic detergent and said cationic germicide being present in relative proportions by weight of 1 : 4 to 12 : 1 and said non-ionic surface active agent being present in an amount equal to at least 10 per cent of the combined weight of said anionic and cationic agents. Specified anionic detergents are alkali metal soaps of higher fatty acids of vegetable and animal origin, e.g. hydrogenated cotton-seed oil stearic, lauric and palmitic acids or mixtures thereof, alkali metal soaps of alkyl sulphates and sulphonates, alkyl aryl sulphonates, e.g. sodium cetyl sulphate, sodium hexadecanesulphonate and sodium di-isobutyl-naphthalene-1-sulphonate. Specified cationic germicides are quaternary ammonium compounds, pyridinium compounds, e.g. 8-hydroxy-quinolinium sulphate, cetyl pyridinium chloride, octyl-phenoxy ethoxy ethyl (benzyl) dimethyl ammonium chloride, alkyl (8 to 18 carbon atoms) dimethyl-3.4-dichlorobenzyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride. The non-ionic surface active agents have the general formula <FORM:0641297/IV (c)/1> in which A=residue of a monomeric organic compound containing an active hydrogen (i.e. alcohols, phenols, amides, primary and secondary amines and carboxylic acids) and R1 and R2=hydrogen or alkyl and n=integer greater than three. Such materials are described in U.S.A. Specifications 1,970,578 and 2,213,477, and include polyalkylene oxide derivatives (e.g. polyethylene oxide, polypropylene oxide and polybutylene oxide) of (a) higher fatty acid such as lauric, oleic, palmitic, stearic and mixtures thereof of animal, vegetable or mineral origin, (b) water insoluble organic hydroxy compounds, e.g. fatty acid alcohols, phenols especially alkyl phenols containing at least six alkyl carbon atoms such as iso-octyl, di-tertiary butyl, tri-isopropyl, nonyl-do-decyl phenols or naphthols, (c) aromatic alcohols such as benzyl and cinnamyl alcohol, (d) water-soluble partial vegetable fatty acid esters of anhydro-sorbitol, e.g. sorbitan monolaurate, sorbitan monostearate and sorbitan monooleate, (e) stearyl, lauryl, dicyclohexyl and dibutyl amines. In addition there may be added inorganic alkali metal salts, e.g. sodium or potassium phosphates, carbonates, borates and silicates and mutual solvents for the water and the surface active agents, e.g. isopropyl alcohol. Specification 505,429, [Group III], is referred to.ALSO:A germicidal detergent composition comprises a mixture of an organic anionic detergent, an organic cationic germicide and a water-soluble non-ionic surface active agent containing a polyglycol ether group, said anionic detergent and said cationic germicide being present in relative proportions by weight of 1 : 4 to 12 : 1 and said non-ionic surface active agent being present in an amount equal to at least 10 per cent of the combined weight of said anionic and cationic agents. Specified anionic detergents are alkali metal soaps of higher fatty acids of vegetable and animal origin, e.g. hydrogenated cottonseed oil, stearic, lauric and palmitic acids or mixtures thereof, alkali metal soaps of alkyl sulphates and sulphonates, alkyl aryl sulphonates, e.g. sodium cetyl sulphate, sodium hexadecanesulphonate and sodium di-isobutyl-naphthalene-1-sulphonate. Specified cationic germicides are quaternary ammonium compounds, pyridinium compounds, e.g. 8-hydroxy-quinolinium sulphate, cetyl pyridinium chloride, octyl-phenoxy ethoxy ethyl (benzyl) dimethyl ammonium chloride, alkyl (8 to 18 carbon atoms) dimethyl-3.4-dichlorobenzyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride. The non-ionic surface active agents have the general formula <FORM:0641297/III/1> in which A=residue of a monomeric organic compound containing an active hydrogen (i.e. alcohols, phenols, amides, primary and secondary amines and carboxylic acids) and R1 and R2 = hydrogen or alkyl and n = integer greater than three. Such materials are described in U.S.A. Specifications 1,970,578 and 2,213,477, and include polyalkylene oxide derivatives (e.g. polyethylene oxide, polypropylene oxide and polybutylene oxide) of (a) higher fatty acids such as lauric, oleic, palmitic, stearic and mixtures thereof of animal, vegetable or mineral origin; (b) water-insoluble organic hydroxy compounds, e.g. fatty acid alcohols, phenols, especially alkyl phenols containing at least six alkyl carbon atoms such as iso-octyl, di-tertiary butyl, tri-isopropyl, nonyl-dodecyl phenols or naphthols; (c) aromatic p alcohols such as benzyl and cinnamyl alcohol; (d) water-soluble partial vegetable fatty acid esters of anhydro-sorbitol, e.g. sorbitan monolaurate, sorbitan monostearate and sorbitan mono-oleate; (e) stearyl, lauryl, dicyclohexyl and dibutyl amines. In addition there may be added inorganic alkali metal salts, e.g. sodium or potassium phosphates, carbonates, borates and silicates and mutual solvents for the water and the surface active agents, e.g. isopropyl alcohol. Specification 505,429 is referred to.ALSO:A germicidal detergent composition comprises a mixture of an organic anionic detergent, an organic cationic germicide and a water-soluble non-ionic surface active agent containing a polyglycol ether group, said anionic detergent and said cationic germicide being present in relative proportions by weight of 1:4 to 12:1, and said non-ionic surface active agent being present in an amount equal to at least 10 per cent of the combined weight of said anionic and cationic agents. Specified anionic detergents are alkali metal soaps of higher fatty acids of vegetable and animal origin, e.g., hydrogenated cottonseed oil, stearic, lauric and palmitic acids or mixtures thereof; alkali metal soaps of alkyl sulphates and sulphonates, alkyl aryl sulphonates, e.g., sodium cetyl sulphate, sodium hexadecanesulphonate and sodium di-isobutyl-naphthalene-1-sulphonate. Specified cationic germicides are quaternary ammonium compounds, pyridinium compounds, e.g., 8-hydroxy-quinolinium sulphate, cetyl pyridinium chloride, octyl-phenoxy ethoxy ethyl (benzyl) dimethyl ammonium chloride, alkyl (8 to 18 carbon atoms) dimethyl-3,4-dichloro benzyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride. The non-ionic surface active agents have the general formula <FORM:0641297/VI/1> in which A=residue of a monomeric organic compound containing an active hydrogen (i.e., alcohols, phenols, amides, primary and secondary amines and carboxylic acids) and R1 and R2=hydrogen or alkyl and n=integer greater than three. Such materials are described in U.S.A. Specifications 1,970,578 and 2,213,477 and include polyalkylene oxide derivatives (e.g., polyethylene oxide, polypropylene oxide and polybutylene oxide) of (a) higher fatty acids such as lauric, oleic, palmitic, stearic and mixtures thereof of animal, vegetable or mineral origin; (b) water-in-soluble organic hydroxy compounds, e.g., fatty acid alcohols, phenols especially alkyl phenols containing at least six alkyl carbon atoms such as isooctyl, di-tertiary butyl, tri-isopropyl, nonyl and dodecyl phenols or naphthols; (c) aromatic alcohols such as benzyl and cinnamyl alcohol; (d) water-soluble partial vegetable fatty acid esters of anhydro-sorbitol, e.g., sorbitan monolaurate, sorbitan monostearate and sorbitan monooleate; (e) stearyl, lauryl, dicyclohexyl and dibutyl amines. In addition there may be added inorganic alkali metal salts, e.g., sodium or potassium phosphates, carbonates, borates and silicates and mutual solvents for the water and the surface active agents, e.g., isopropyl alcohol. Specification 505,429 is referred to.
GB5130/48A 1947-03-26 1948-02-20 Germicidal detergent compositions Expired GB641297A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US737437A US2577773A (en) 1947-03-26 1947-03-26 Ternary detergent compositions

Publications (1)

Publication Number Publication Date
GB641297A true GB641297A (en) 1950-08-09

Family

ID=24963921

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5130/48A Expired GB641297A (en) 1947-03-26 1948-02-20 Germicidal detergent compositions

Country Status (2)

Country Link
US (1) US2577773A (en)
GB (1) GB641297A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302364A (en) 1978-08-10 1981-11-24 The Procter & Gamble Company Liquid detergent compositions comprising anionic, nonionic and cationic surfactants
US4303543A (en) 1979-02-27 1981-12-01 The Procter & Gamble Company Method for cleansing and conditioning the skin
US4321165A (en) 1977-06-29 1982-03-23 The Procter & Gamble Company Detergent compositions comprising cationic, anionic and nonionic surfactants
GB2132087A (en) * 1982-12-10 1984-07-04 Chemical Medic Hall Limited Germicidal and disinfectant composition
US4810409A (en) * 1987-12-16 1989-03-07 Sterling Drug Inc. Stable, isotropic liquid laundry detergents
US20170303537A1 (en) * 2016-04-21 2017-10-26 Oms Investments, Inc. Compositions of a quaternary ammonium compound with a monocarboxylic fatty acid

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US3125487A (en) * 1964-03-17 Bacteriostatic compositions and meth-
US2692231A (en) * 1950-09-05 1954-10-19 California Research Corp Microbiocidal water treatment
US2940902A (en) * 1952-01-03 1960-06-14 Vorsatz Fritz Arthur Process for the prodction of cosmetic creams and thickening agents therefor
US2742434A (en) * 1952-01-19 1956-04-17 Gen Aniline & Film Corp Cleaner-sanitizer
NL189533C (en) * 1953-07-29 Ates Componenti Elettron PROCEDURE FOR APPLYING A PLASTIC HOLDER WITH HEAT DISCHARGE AROUND AN INTEGRATED CIRCUIT, AS WELL AS COMBINATION OF A MOLD AND A HEAT DISCHARGE ELEMENT FOR USE IN THIS PROCEDURE.
US2904468A (en) * 1954-04-13 1959-09-15 Carlen Corp Skin disinfectant containing polyoxyethylene alkyl phenol, calcium chelating agent and either an organic sulfate or sulfonate salt
US2861955A (en) * 1954-10-22 1958-11-25 Emery Industries Inc Detergent for hard water
US2921885A (en) * 1955-11-25 1960-01-19 Colgate Palmolive Co Antibacterial composition
US2950255A (en) * 1956-07-03 1960-08-23 Gillette Co Detergent composition
US3093591A (en) * 1957-05-03 1963-06-11 Gen Mills Inc Compositions containing nu-alkyl-betaamino propionates and germicidal quaternary ammonium compounds
US3034965A (en) * 1958-06-12 1962-05-15 Rose P Drake Composition and method for treating nails
US3088916A (en) * 1958-08-11 1963-05-07 Monsanto Chemicals Bacteriostatic and fungistatic cleansing compositions
US3154489A (en) * 1960-07-18 1964-10-27 Armour & Co Surface active compositions
US3214378A (en) * 1960-09-01 1965-10-26 R G H Company Inc Composition for magnetic particle testing
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US3178366A (en) * 1962-05-28 1965-04-13 Armour & Co Treating compositions for softening fibers
US3297638A (en) * 1963-04-30 1967-01-10 Monsanto Co Composition consisting of an admixture of a phenol-aldehyde resin, an alkyl phenol-ethylene oxide condensate and a polyoxypropylene-ethylene oxide reaction product
US3281365A (en) * 1963-12-23 1966-10-25 Monsanto Co Antiseptic detergent compositions
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US3859227A (en) * 1968-11-14 1975-01-07 Chevron Res Stable slow-setting cationic bituminous emulsions and their preparation
US4255294A (en) * 1975-04-01 1981-03-10 Lever Brothers Fabric softening composition
DE2712900C2 (en) * 1977-03-24 1986-04-10 Henkel KGaA, 4000 Düsseldorf Process for cleaning metals by spraying
EP0051986B1 (en) * 1980-11-06 1985-05-29 THE PROCTER &amp; GAMBLE COMPANY Detergent compositions
US4336151A (en) * 1981-07-06 1982-06-22 American Cyanamid Company Disinfectant/cleanser compositions exhibiting reduced eye irritancy potential
US4336152A (en) * 1981-07-06 1982-06-22 American Cyanamid Company Disinfectant/cleanser compositions exhibiting reduced eye irritancy potential
US4496534A (en) * 1981-12-16 1985-01-29 Union Oil Company Of California Method for reconditioning bacteria-contaminated hydrogen sulfide removing systems
US5661170A (en) * 1994-03-21 1997-08-26 Woodward Laboratories, Inc. Antimicrobial compositions and methods for using the same
US5968986A (en) * 1997-12-18 1999-10-19 Woodward Laboratories, Inc. Antimicrobial nail coating composition
US5994383A (en) * 1997-11-18 1999-11-30 Woodward Laboratories, Inc. Surfactant-based antimicrobial compositions and methods for using the same
US6479039B1 (en) 1999-07-13 2002-11-12 Woodward Laboratories, Inc. Antimicrobial artificial nail composition and methods for preparing and using same
US9295251B1 (en) 2011-04-08 2016-03-29 Safehands Solutions, LLC Synergistic antimicrobial compositions of PCMX and carboxylic acid and related methods
US9693564B2 (en) 2011-06-21 2017-07-04 Safehands Solutions, LLC Water based antimicrobial composition using benzalkonium chloride and cocamidopropyl PG-dimonium chloride phosphate
CN116043233B (en) * 2022-10-09 2024-06-18 上海承鲁科技有限公司 Water-based cleaning agent and preparation method thereof

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US2060850A (en) * 1932-11-08 1936-11-17 Du Pont Quaternary ammonium compounds and process for the production thereof
GB453523A (en) * 1935-03-13 1936-09-14 Ici Ltd Improved process of dry cleaning
US2089212A (en) * 1936-06-08 1937-08-10 Kritchevsky Wolf Hydrotropic fatty material and method of making same
US2184951A (en) * 1936-08-13 1939-12-26 Winthrop Chem Co Inc Mothproofing detergent composition
US2263948A (en) * 1938-10-31 1941-11-25 Economics Lab Germicidal detergent
US2284086A (en) * 1939-05-09 1942-05-26 American Cyanamid Co Detergent composition
US2302697A (en) * 1941-08-04 1942-11-24 Emulsol Corp Surface modifying composition

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4321165A (en) 1977-06-29 1982-03-23 The Procter & Gamble Company Detergent compositions comprising cationic, anionic and nonionic surfactants
US4302364A (en) 1978-08-10 1981-11-24 The Procter & Gamble Company Liquid detergent compositions comprising anionic, nonionic and cationic surfactants
US4303543A (en) 1979-02-27 1981-12-01 The Procter & Gamble Company Method for cleansing and conditioning the skin
GB2132087A (en) * 1982-12-10 1984-07-04 Chemical Medic Hall Limited Germicidal and disinfectant composition
US4810409A (en) * 1987-12-16 1989-03-07 Sterling Drug Inc. Stable, isotropic liquid laundry detergents
US20170303537A1 (en) * 2016-04-21 2017-10-26 Oms Investments, Inc. Compositions of a quaternary ammonium compound with a monocarboxylic fatty acid

Also Published As

Publication number Publication date
US2577773A (en) 1951-12-11

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