GB1024022A - Process and materials for protection of organic materials against micro-organism contamination - Google Patents
Process and materials for protection of organic materials against micro-organism contaminationInfo
- Publication number
- GB1024022A GB1024022A GB739964A GB739964A GB1024022A GB 1024022 A GB1024022 A GB 1024022A GB 739964 A GB739964 A GB 739964A GB 739964 A GB739964 A GB 739964A GB 1024022 A GB1024022 A GB 1024022A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogenated
- acid
- halogen
- corresponding compounds
- diphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/136—Phenols containing halogens
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Antimicrobic detergent compositions comprise a detergent substance and as active ingredient, a halogen-o-hydroxy-diphenyl ether of formula <FORM:1024022/C4-C5/1> where p is 1 to 5, Hal represents a halogen atom, and where p is greater than 1 such halogen atoms may be the same or different, corresponding compounds in which one or both of the benzene rings A and B further contain substituents selected from C1-C4 alkyl or halogenated alkyl groups, C1-C4 alkoxy groups, cyano, allyl, amino and acetyl groups, and corresponding compounds in which the indicated hydroxy group is acylated. Detergent substances specified are anionic active compounds, e.g. sodium dodecyl benzene sulphonate, water-soluble salts of dodecyl alcohol sulphate or of dodecyl alcohol polyglycol ether sulphate and C12-C24 soaps; non-ionic substances, e.g. polyglycol ethers of C12-C24 fatty alcohols, and polyglycol ethers of C5-C20 alkylated phenols; and ampholenic substances, e.g. the reaction products of alkali metal salts of halogen fatty acids and polyalkylene polyamines. The compositions may also contain other antimicrobial agents (examples given), water-soluble perborates, polyphosphates, carbonates, silicates, optical brightening agents, plasticizers, salts having an acid reaction, e.g. ammonium or zinc silico flouride, oxalic acids and dressing agents, e.g. those having a basis of synthetic resin or starch. Examples describe washing liquors and soap tablets, in the former of which ethylene glycol monomethylether is used as a solvent for the antimicrobral agent.ALSO:An antimicrobiol polyamide composition comprises polyamide 6- and 4,41-dichloro-2-hydroxydiphenyl ether. An antimicrobial polyvinyl chloride composition comprises polyvinyl chloride powder, dibutyl sebacate, dibutyl tin dilaurate and 4,41 - dichloro - 2 - hydroxydiphenyl ether as antimicrobial agent.ALSO:The Specification lists a number of specific compounds, prepared by known methods, within the formula <FORM:1024022/C2/1> where p is to 5, Hal represents a halogen atom and, where p is greater than 1 such halogen atoms may be the same or different, corresponding compounds in which one or both of the benzene rings A and B further contain substituents selected from C1-C4 alkyl and halogenated alkyl groups, C1-C4 alkoxy groups, cyano, allyl, amino and acetyl groups, and corresponding compounds in which the indicated hydroxy group is acylated.ALSO:A process for protecting organic materials against contamination by micro-organisms comprises incorporating in such materials a halogen-o-hydroxydiphenyl ether of formula: <FORM:1024022/A5-A6/1> where p is 1 to 5, Hal represent a halogen atom and, where p is greater than 1, such halogen atoms may be the same or different, corresponding compounds in which one or both of the benzene rings A and B further contain substituents selected from C1-C4 alkyl or halogenated alkyl groups, C1-C4 alkoxy groups, cyano, allyl, amino and acetyl groups, and corresponding compounds to any of these in which the indicated hydroxy group is acylated. Acylated compounds may be esters of acetic acid, chloroacetic acid, methyl or dimethyl carbamic aicd, benzoic acid, chlorobenzoic acid, methyl sulphonic acid or chloromethyl sulphonic acid. The diphenyl ethers may be applied to said organic materials in the form of compositions, e.g. dissolved in solutions of wetting or cleansing agents, in paints or lacquers, in plasticisers or in ethylene glycol monoethyl ether. They can also be applied in combination with other antimicrobially active substances e.g. with halogenated salicyclic acid alkyl amides and anilides, halogenated diphenyl ureas, halogenated benzoxazoles or benzoxazolones, polychloro-hydroxydiphenyl methanes, halogenated dihydroxy-diphenyl sulphides, 2-mino-unidazolidines or -tetrahydropyrimidines and tetra methyl thiuram disulphide. The process of the invention can be applied, for example, in the treatment of paper, wood and other cellulosic materials, leather, cotton, and wool. The diphenyl ethers may also be incorporated in cosmetic articles, e.g. soaps, ointments or powders to render them antimicrobial.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH225063A CH406127A (en) | 1963-02-22 | 1963-02-22 | Process for the antimicrobial finishing of textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1024022A true GB1024022A (en) | 1966-03-30 |
Family
ID=4229370
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB732964A Expired GB1022744A (en) | 1963-02-22 | 1964-02-21 | New phenolic antimicrobial compositions |
| GB732864A Expired GB1038185A (en) | 1963-02-22 | 1964-02-21 | New diphenyl ethers and processes for their production, and pharmaceutical compositions containing them |
| GB739964A Expired GB1024022A (en) | 1963-02-22 | 1964-02-21 | Process and materials for protection of organic materials against micro-organism contamination |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB732964A Expired GB1022744A (en) | 1963-02-22 | 1964-02-21 | New phenolic antimicrobial compositions |
| GB732864A Expired GB1038185A (en) | 1963-02-22 | 1964-02-21 | New diphenyl ethers and processes for their production, and pharmaceutical compositions containing them |
Country Status (15)
| Country | Link |
|---|---|
| AT (5) | AT277471B (en) |
| AU (1) | AU278661B2 (en) |
| BE (2) | BE644153A (en) |
| BR (2) | BR6457019D0 (en) |
| CH (4) | CH431780A (en) |
| DE (2) | DE1216882B (en) |
| DK (3) | DK109518C (en) |
| ES (4) | ES296710A1 (en) |
| FI (1) | FI41831B (en) |
| FR (3) | FR1386731A (en) |
| GB (3) | GB1022744A (en) |
| IT (1) | IT1149232B (en) |
| MY (2) | MY6900160A (en) |
| NL (2) | NL123731C (en) |
| SE (3) | SE301324B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4326978A (en) * | 1979-11-16 | 1982-04-27 | Ciba-Geigy Corporation | Soap bar with antimicrobial action |
| US5286492A (en) * | 1990-05-03 | 1994-02-15 | Reckitt & Colman Products Limited | Method of treatment of Heliobacter pylori infections with triclosan |
| WO2005089552A1 (en) * | 2004-03-23 | 2005-09-29 | Ciba Specialty Chemicals Holding Inc. | Fungicidal detergent compositions |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4118332A (en) * | 1965-10-22 | 1978-10-03 | Colgate-Palmolive Company | Synergistic antibacterial composition containing mixtures of certain halogenated diphenyl ethers and trichlorocarbanilides |
| CH1085667A4 (en) * | 1967-08-01 | 1969-03-14 | ||
| US4057648A (en) | 1970-05-16 | 1977-11-08 | Ciba-Geigy Corporation | Compositions for the control of microorganisms |
| BE750969A (en) | 1970-05-26 | 1970-11-03 | Geigy Ag J R | COMPOSITION TO FIGHT MICRO-ORGANISMS, |
| US4284828A (en) * | 1978-11-21 | 1981-08-18 | Ciba-Geigy Corporation | Process for the manufacture of 4,5-dichloro-2-(4-chlorophenoxy)phenol |
| DE3004610A1 (en) * | 1980-02-08 | 1981-08-13 | Hoechst Ag, 6000 Frankfurt | METHOD FOR PRODUCING 4-PHENOXYPHENOLS |
| US4490562A (en) * | 1982-02-11 | 1984-12-25 | Ciba-Geigy Corporation | Process for the preparation of a very pure commercial form of 4,2',4'-trichloro-2-hydroxydiphenyl ether |
| GB8313634D0 (en) * | 1982-06-18 | 1983-06-22 | Ici Plc | Halogenophenyl glyceride esters |
| US4512987A (en) * | 1982-07-15 | 1985-04-23 | Ciba-Geigy Corporation | New pharmaceutical preparations |
| JPS611615A (en) * | 1984-06-12 | 1986-01-07 | Yougo Takaoka | External drug for athlete's foot |
| WO1995008332A1 (en) * | 1993-09-20 | 1995-03-30 | The Procter & Gamble Company | Use of triclosan phosphates for the treatment of gastrointestinal disorders due to heliobacter infection |
| FR2765469B1 (en) * | 1997-07-07 | 1999-09-24 | Elysees Balzac Financiere | MATERIAL BASED ON REGENERATED CELLULOSE HAVING SUSTAINABLE RESISTANCE TO MICROORGANISMS AND PREPARATION THEREOF |
| EP0908553A3 (en) * | 1997-10-13 | 2001-03-07 | Ciba SC Holding AG | Process for the treatment of textile materials with an antimicrobial agent |
| US5968207A (en) * | 1998-02-20 | 1999-10-19 | Milliken & Company | Esterified triclosan derivatives as improved textile antimicrobial agents |
| US6258455B1 (en) * | 1999-03-29 | 2001-07-10 | Sweports Limited | Antimicrobial ultra-microfiber cloth |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE569726C (en) * | 1930-05-09 | 1933-02-07 | Ig Farbenindustrie Ag | Process for the preparation of bis (halo-oxyaryl) oxides |
-
1963
- 1963-02-22 CH CH1764066A patent/CH431780A/en unknown
- 1963-02-22 CH CH225063A patent/CH406127A/en unknown
-
1964
- 1964-02-01 BR BR15701964A patent/BR6457019D0/en unknown
- 1964-02-19 CH CH196564A patent/CH450347A/en unknown
- 1964-02-19 CH CH1509564A patent/CH450348A/en unknown
- 1964-02-20 FI FI33364A patent/FI41831B/fi active
- 1964-02-21 AT AT345167A patent/AT277471B/en not_active IP Right Cessation
- 1964-02-21 AT AT357665A patent/AT245555B/en active
- 1964-02-21 DK DK96066A patent/DK109518C/en active
- 1964-02-21 AT AT357565A patent/AT246725B/en active
- 1964-02-21 ES ES296710A patent/ES296710A1/en not_active Expired
- 1964-02-21 SE SE215764A patent/SE301324B/xx unknown
- 1964-02-21 DK DK85864A patent/DK108923C/en active
- 1964-02-21 BE BE644153A patent/BE644153A/xx unknown
- 1964-02-21 BE BE644154D patent/BE644154A/xx unknown
- 1964-02-21 NL NL6401661A patent/NL123731C/xx active
- 1964-02-21 GB GB732964A patent/GB1022744A/en not_active Expired
- 1964-02-21 GB GB732864A patent/GB1038185A/en not_active Expired
- 1964-02-21 DE DEG39916A patent/DE1216882B/en active Pending
- 1964-02-21 FR FR964735A patent/FR1386731A/en not_active Expired
- 1964-02-21 ES ES296708A patent/ES296708A1/en not_active Expired
- 1964-02-21 DE DE1964G0039915 patent/DE1492346A1/de not_active Ceased
- 1964-02-21 BR BR15701864A patent/BR6457018D0/en unknown
- 1964-02-21 FR FR964734A patent/FR1385825A/en not_active Expired
- 1964-02-21 AU AU41194/64A patent/AU278661B2/en not_active Expired
- 1964-02-21 GB GB739964A patent/GB1024022A/en not_active Expired
- 1964-02-21 NL NL6401664A patent/NL6401664A/xx unknown
- 1964-02-21 AT AT148064A patent/AT262512B/en active
- 1964-02-21 AT AT148164A patent/AT245554B/en active
- 1964-02-21 IT IT393764A patent/IT1149232B/en active
- 1964-02-21 ES ES296709A patent/ES296709A1/en not_active Expired
- 1964-02-21 ES ES296707A patent/ES296707A1/en not_active Expired
- 1964-02-21 DK DK95966A patent/DK109146C/en active
- 1964-05-20 FR FR975146A patent/FR3486M/fr not_active Expired
-
1966
- 1966-02-21 SE SE219166A patent/SE309780B/xx unknown
- 1966-02-21 SE SE219266A patent/SE309781B/xx unknown
-
1969
- 1969-12-30 MY MY6900160A patent/MY6900160A/en unknown
- 1969-12-30 MY MY6900159A patent/MY6900159A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4326978A (en) * | 1979-11-16 | 1982-04-27 | Ciba-Geigy Corporation | Soap bar with antimicrobial action |
| US5286492A (en) * | 1990-05-03 | 1994-02-15 | Reckitt & Colman Products Limited | Method of treatment of Heliobacter pylori infections with triclosan |
| WO2005089552A1 (en) * | 2004-03-23 | 2005-09-29 | Ciba Specialty Chemicals Holding Inc. | Fungicidal detergent compositions |
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