GB723925A - Process for preparing all-purpose detergent compositions - Google Patents
Process for preparing all-purpose detergent compositionsInfo
- Publication number
- GB723925A GB723925A GB13599/52A GB1359952A GB723925A GB 723925 A GB723925 A GB 723925A GB 13599/52 A GB13599/52 A GB 13599/52A GB 1359952 A GB1359952 A GB 1359952A GB 723925 A GB723925 A GB 723925A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- fatty acid
- alkyl
- fatty
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Abstract
Detergent compositions are made by forming a liquid mixture of a soap-forming fatty glyceride material and a proportion of a soap-compatible anionic or non-ionic synthetic detergent which is less than the fatty acid content of the final product, adding, in the presence of water, an alkali compatible with the synthetic detergent and capable of forming water-soluble soap with the fatty acid of the glyceride material, mixing the ingredients under such conditions that the glyceride material is partly or completely saponified, and thereafter solidifying the mixture. The fatty glyceride material may be beef or mutton tallow, lard, lard oil, horse fat, greases or coconut palm-kernel, palmo or babassic oil. The anionic detergents may be sulphated materials having an alkyl substituent containing 8-26 (preferably at least 10 and particularly 12-22) carbon atoms per molecule, e.g. the sulphuric acid esters of polyhydric alcohols incompletely esterified with higher fatty acids, such as coconut oil monoglyceride monosulphates and tallow diglyceride monosulphates; the long-chain pure or mixed alkyl sulphates, e.g. lauryl sulphate, cetyl sulphate and higher fatty alcohol sulphates derived from coconut oil; the higher fatty acid esters of low molecular weight alkylol sulphonic acids, e.g. higher fatty acid esters of 2, 3-dihydroxy propane sulphonic acid or the oleic acid esters of isethionic acid; the sulphated fatty acid alkylolamides, e.g., ethanolamide sulphates; or the higher fatty acid amides of amino alkyl sulphonic acids, e.g., lauric acid tauride. The anionic synthetic detergents may alternatively be sulphonated alkylated mono or polynuclear compounds which may contain substituents such as hydroxyl groups. The alkyl substituent should contain 8-26 carbon atoms, is preferably saturated and may be straight or branched; it may be mixed alkyls derived from fatty compounds, cracked paraffin wax olefines, or polymers of lower mono olefines. The average chain length of the alkyl substituents should be 9-15 and preferably 12-14 carbon atoms. Nonionic detergents which may be used include reaction products of ethylene oxide with organic acids, anhydrides, alcohols and amides of high molecular weight; high molecular weight derivatives of polyhydroxy compounds such as polyalkylene glycols and polyglycerols, e.g. alkyl thio-, sterol and alkyl phenol ethers of polyethylene glycol; polyethylene glycol esters of fatty and other high molecular weight carboxylic acids, the corresponding ethers and esters of polypropylene glycol, polybutylene glycol and polyglycerol; and polyalkylene glycol ethers of partially esterified glycol, glycerol, sorbitol, mannitol and partially dehydrated derivatives of such esters. The anionic synthetic detergent may be introduced into the mixture in the form of its water-soluble alkali or alkaline earth metal salt, or may be introduced in unneutralized form and then neutralized in the mixture by a portion of the alkali employed in the process. The alkali used may be sodium or potassium hydroxide, sodium or potassium carbonate, or mono-, di-, or tri-ethanolamine. The ingredients may be mixed at 85-200 DEG F. The proportion of glyceride material in the mixture should generally be about 30-80 (preferably 40-75) per cent of the total weight of the mixture. The proportion of synthetic detergent in the mixture may be 10-35 (preferably 10-25) per cent by weight. The final composition should contain about 15-30 and preferably 20-25 per cent of moisture. Optional constituents of the compositions are alkali-metal carbonates, silicates, borates, phosphates and nitrates, carboxymethyl cellulose, disinfectants, e.g. mercury compounds or phenols, and abrasives, e.g. silica or pumice. In an example, 36 parts by weight of babassic oil, 10 parts of water, 27 parts of the sodium salt of the sulphuric acid esters of coconut oil fatty acid monoglycerides, and 4 parts of the fatty acids obtained from grease are mixed at about 110 DEG F., one part of sodium carbonate, 12 parts of a 50 DEG B<\>ae aqueous solution of caustic soda and 9 parts of water are added, and when the temperature has risen to about 160 DEG F. the mixture is thoroughly stirred for about 10 minutes, poured into frames and allowed to solidify.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US723925XA | 1951-10-06 | 1951-10-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB723925A true GB723925A (en) | 1955-02-16 |
Family
ID=22107259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13599/52A Expired GB723925A (en) | 1951-10-06 | 1952-05-28 | Process for preparing all-purpose detergent compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB723925A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2944977A (en) * | 1955-08-09 | 1960-07-12 | Colgate Palmolive Co | Process for preparing aqueous soapsynthetic detergent mixtures in ribbon form |
US3150097A (en) * | 1961-04-18 | 1964-09-22 | Lever Brothers Ltd | Soap compositions |
US3622516A (en) * | 1967-10-06 | 1971-11-23 | Monsanto Co | Built-soap manufacturing process |
GB2181739A (en) * | 1985-10-16 | 1987-04-29 | Unilever Plc | Detergent bar comprising soap and a rosin derivative or synthetic anionic surfactant |
US4867899A (en) * | 1987-11-30 | 1989-09-19 | Colgate-Palmolive Company | Sodium monoglyceride sulfate detergent composition bar and process for manufacture thereof |
CN106118892A (en) * | 2016-06-30 | 2016-11-16 | 江绍玫 | A kind of omnipotent food stage cleaning agent and preparation method thereof |
CN106118893A (en) * | 2016-06-30 | 2016-11-16 | 江绍玫 | A kind of gentleness, green cleaning agent and preparation method thereof |
-
1952
- 1952-05-28 GB GB13599/52A patent/GB723925A/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2944977A (en) * | 1955-08-09 | 1960-07-12 | Colgate Palmolive Co | Process for preparing aqueous soapsynthetic detergent mixtures in ribbon form |
US3150097A (en) * | 1961-04-18 | 1964-09-22 | Lever Brothers Ltd | Soap compositions |
US3622516A (en) * | 1967-10-06 | 1971-11-23 | Monsanto Co | Built-soap manufacturing process |
GB2181739A (en) * | 1985-10-16 | 1987-04-29 | Unilever Plc | Detergent bar comprising soap and a rosin derivative or synthetic anionic surfactant |
GB2181739B (en) * | 1985-10-16 | 1989-09-13 | Unilever Plc | Detergent component and process for making a detergent component |
US4867899A (en) * | 1987-11-30 | 1989-09-19 | Colgate-Palmolive Company | Sodium monoglyceride sulfate detergent composition bar and process for manufacture thereof |
CN106118892A (en) * | 2016-06-30 | 2016-11-16 | 江绍玫 | A kind of omnipotent food stage cleaning agent and preparation method thereof |
CN106118893A (en) * | 2016-06-30 | 2016-11-16 | 江绍玫 | A kind of gentleness, green cleaning agent and preparation method thereof |
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