GB1072429A - N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone - Google Patents

N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone

Info

Publication number
GB1072429A
GB1072429A GB2280066A GB2280066A GB1072429A GB 1072429 A GB1072429 A GB 1072429A GB 2280066 A GB2280066 A GB 2280066A GB 2280066 A GB2280066 A GB 2280066A GB 1072429 A GB1072429 A GB 1072429A
Authority
GB
United Kingdom
Prior art keywords
cobalt
hydroxyethyl
carbon atoms
rhodium
pyrrolidone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2280066A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1072429A publication Critical patent/GB1072429A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
    • C07D207/27—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

N-(b -hydroxyethyl)-a -pyrrolidone is produced by contacting N-(b -hydroxyethyl)alkylamine with carbon monoxide, in the liquid phase in an inert reaction diluent at a temperature of 125-350 DEG C. and a pressure of 75-450 atm., in the presence of a cobalt or rhodium carbonyl carbonylation catalyst, the ratio of the gramatoms of cobalt or rhodium to moles of N-(b -hydroxymethyl)allylamine being from 0.004 to 0.4. The cobalt or rhodium may be introduced into the mixture as the metal, a salt of an organic acid, e.g. the naphthenate or octanoate, or as a metal oxide. Suitable diluents include hydrocarbons containing 6-12 carbon atoms and free from non-aromatic unsaturation, alcohols containing 1-5 carbon atoms, N-lower alkyl-pyrrolidones and, particularly ethers containing 4-14 carbon atoms and up to 3 ether oxygen atoms.
GB2280066A 1965-05-24 1966-05-23 N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone Expired GB1072429A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US45840265A 1965-05-24 1965-05-24

Publications (1)

Publication Number Publication Date
GB1072429A true GB1072429A (en) 1967-06-14

Family

ID=23820642

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2280066A Expired GB1072429A (en) 1965-05-24 1966-05-23 N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone

Country Status (3)

Country Link
BE (1) BE681405A (en)
GB (1) GB1072429A (en)
NL (1) NL6607028A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006036350A1 (en) * 2004-09-15 2006-04-06 Lyondell Chemical Technology, L.P. Method for purifying n-(2-hydroxyethyl)-2-pyrrolidone

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006036350A1 (en) * 2004-09-15 2006-04-06 Lyondell Chemical Technology, L.P. Method for purifying n-(2-hydroxyethyl)-2-pyrrolidone
US7045639B2 (en) 2004-09-15 2006-05-16 Lyondell Chemical Technology, L.P. Method for purifying N-(2-hydroxyethyl)-2-pyrrolidone

Also Published As

Publication number Publication date
BE681405A (en) 1966-11-23
NL6607028A (en) 1966-11-25

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