GB1072429A - N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone - Google Patents
N-(ª‰-hydroxyethyl)-ª‡-pyrrolidoneInfo
- Publication number
- GB1072429A GB1072429A GB2280066A GB2280066A GB1072429A GB 1072429 A GB1072429 A GB 1072429A GB 2280066 A GB2280066 A GB 2280066A GB 2280066 A GB2280066 A GB 2280066A GB 1072429 A GB1072429 A GB 1072429A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cobalt
- hydroxyethyl
- carbon atoms
- rhodium
- pyrrolidone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
- C07D207/27—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
N-(b -hydroxyethyl)-a -pyrrolidone is produced by contacting N-(b -hydroxyethyl)alkylamine with carbon monoxide, in the liquid phase in an inert reaction diluent at a temperature of 125-350 DEG C. and a pressure of 75-450 atm., in the presence of a cobalt or rhodium carbonyl carbonylation catalyst, the ratio of the gramatoms of cobalt or rhodium to moles of N-(b -hydroxymethyl)allylamine being from 0.004 to 0.4. The cobalt or rhodium may be introduced into the mixture as the metal, a salt of an organic acid, e.g. the naphthenate or octanoate, or as a metal oxide. Suitable diluents include hydrocarbons containing 6-12 carbon atoms and free from non-aromatic unsaturation, alcohols containing 1-5 carbon atoms, N-lower alkyl-pyrrolidones and, particularly ethers containing 4-14 carbon atoms and up to 3 ether oxygen atoms.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US45840265A | 1965-05-24 | 1965-05-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1072429A true GB1072429A (en) | 1967-06-14 |
Family
ID=23820642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2280066A Expired GB1072429A (en) | 1965-05-24 | 1966-05-23 | N-(ª‰-hydroxyethyl)-ª‡-pyrrolidone |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE681405A (en) |
GB (1) | GB1072429A (en) |
NL (1) | NL6607028A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006036350A1 (en) * | 2004-09-15 | 2006-04-06 | Lyondell Chemical Technology, L.P. | Method for purifying n-(2-hydroxyethyl)-2-pyrrolidone |
-
1966
- 1966-05-23 GB GB2280066A patent/GB1072429A/en not_active Expired
- 1966-05-23 BE BE681405D patent/BE681405A/xx unknown
- 1966-05-23 NL NL6607028A patent/NL6607028A/xx unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006036350A1 (en) * | 2004-09-15 | 2006-04-06 | Lyondell Chemical Technology, L.P. | Method for purifying n-(2-hydroxyethyl)-2-pyrrolidone |
US7045639B2 (en) | 2004-09-15 | 2006-05-16 | Lyondell Chemical Technology, L.P. | Method for purifying N-(2-hydroxyethyl)-2-pyrrolidone |
Also Published As
Publication number | Publication date |
---|---|
BE681405A (en) | 1966-11-23 |
NL6607028A (en) | 1966-11-25 |
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