GB980239A - A process for preparing ª‡-acetoxypropionaldehyde - Google Patents

A process for preparing ª‡-acetoxypropionaldehyde

Info

Publication number
GB980239A
GB980239A GB2738463A GB2738463A GB980239A GB 980239 A GB980239 A GB 980239A GB 2738463 A GB2738463 A GB 2738463A GB 2738463 A GB2738463 A GB 2738463A GB 980239 A GB980239 A GB 980239A
Authority
GB
United Kingdom
Prior art keywords
rhodium
acetoxypropionaldehyde
carbon monoxide
pressure
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2738463A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Publication of GB980239A publication Critical patent/GB980239A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/28Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

a -Acetoxypropionaldehyde is prepared by reacting liquid vinyl acetate with carbon monoxide and hydrogen at elevated temperature and pressure in the presence of a rhodium carbonyl or rhodium-containing substance which is converted into a rhodium carbonyl under the reaction conditions. The reaction is usually performed at 30 DEG to 180 DEG C. at greater than 50 kgs./cm.2 pressure employing a carbon monoxide to hydrogen volume ratio of 1 to 0.1-10 in the absence or presence of an organic solvent. Specified catalysts are rhodium tricarbonyl, trichloride, hydroxide, sesquioxide and organic and inorganic acid salts, and rhodium metal.
GB2738463A 1962-07-12 1963-07-10 A process for preparing ª‡-acetoxypropionaldehyde Expired GB980239A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2872462 1962-07-12

Publications (1)

Publication Number Publication Date
GB980239A true GB980239A (en) 1965-01-13

Family

ID=12256371

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2738463A Expired GB980239A (en) 1962-07-12 1963-07-10 A process for preparing ª‡-acetoxypropionaldehyde

Country Status (4)

Country Link
CH (1) CH413813A (en)
DE (1) DE1225627B (en)
GB (1) GB980239A (en)
NL (1) NL295118A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072709A (en) 1975-05-27 1978-02-07 Monsanto Company Production of lactic acid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB646424A (en) * 1945-08-08 1950-11-22 Guilio Natta Process for producing aldehydes
FR924909A (en) * 1945-12-19 1947-08-20 Kellogg M W Co Improved process for hydrogenation of carbon oxides
US2610203A (en) * 1949-12-13 1952-09-09 Eastman Kodak Co Process of producing aldehyde esters
DE953605C (en) * 1952-06-18 1956-12-06 Chemische Verwertungsgesellsch Process for the preparation of oxygen-containing compounds
DE1112970B (en) * 1956-01-11 1961-08-24 Exxon Research Engineering Co Process for the preparation of carbonyl compounds by the oxo synthesis

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072709A (en) 1975-05-27 1978-02-07 Monsanto Company Production of lactic acid

Also Published As

Publication number Publication date
DE1225627B (en) 1966-09-29
CH413813A (en) 1966-05-31
NL295118A (en)

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