FR2374280A1 - Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid - Google Patents

Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid

Info

Publication number
FR2374280A1
FR2374280A1 FR7632940A FR7632940A FR2374280A1 FR 2374280 A1 FR2374280 A1 FR 2374280A1 FR 7632940 A FR7632940 A FR 7632940A FR 7632940 A FR7632940 A FR 7632940A FR 2374280 A1 FR2374280 A1 FR 2374280A1
Authority
FR
France
Prior art keywords
esp
pref
inert liquid
catalyst
prepn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7632940A
Other languages
French (fr)
Other versions
FR2374280B1 (en
Inventor
Yves Chauvin
Dominique Commereuc
Igor Tkatchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7632940A priority Critical patent/FR2374280A1/en
Publication of FR2374280A1 publication Critical patent/FR2374280A1/en
Application granted granted Critical
Publication of FR2374280B1 publication Critical patent/FR2374280B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Prepn. of methane comprises reacting carbon monoxide and hydrogen in an inert liquid medium in the presence of a catalyst which is the product of reacting at least one Ni cpd. with at least one reducing aluminium cpd. in an inert liquid. The quasi-homogeneity of the catalyst ensures both a good thermal diffusion with a good removal of heat from the strongly exothermic reaction and also good accessibility of the catalyst to the reactants; these conditions not having been simultaneously obtd. by previous catalysts. Pref. Ni cpds. are carboxylates of 6-20C fatty acids, esp. an 8-10C mixture. The Al cpd. is pref. of formula Al(R)3 at least one R being hydrocarbyl, the remainder H, hydrocarbyl or alkoxy; esp. a trialkyl aluminium. The Al/Ni atomic ratio is pref. from 1:1 to 20:1 esp. 2:1 to 10:1. The inert liquid pref. comprises at least one saturated hydrocarbon. The pref. reaction conditions are 1-50 esp. 1-20, bars pressure; 100-450 degrees C. temp. esp. above 200 degrees C.
FR7632940A 1976-10-27 1976-10-27 Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid Granted FR2374280A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7632940A FR2374280A1 (en) 1976-10-27 1976-10-27 Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7632940A FR2374280A1 (en) 1976-10-27 1976-10-27 Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid

Publications (2)

Publication Number Publication Date
FR2374280A1 true FR2374280A1 (en) 1978-07-13
FR2374280B1 FR2374280B1 (en) 1979-03-30

Family

ID=9179434

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7632940A Granted FR2374280A1 (en) 1976-10-27 1976-10-27 Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid

Country Status (1)

Country Link
FR (1) FR2374280A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491058A1 (en) * 1980-09-30 1982-04-02 Inst Francais Du Petrole IMPROVED PROCESS FOR THE CATALYTIC SYNTHESIS OF METHANE BY REACTING HYDROGEN WITH CARBON MONOXIDE
FR2564748A1 (en) * 1984-05-24 1985-11-29 Charbonnages Ste Chimique Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds
FR2573998A1 (en) * 1984-12-05 1986-06-06 Charbonnages Ste Chimique CARBON MONOXIDE HYDROCONDENSATION CATALYST, PROCESS FOR PREPARING THE SAME AND APPLICATION THEREOF TO THE MANUFACTURE OF HYDROCARBONS AND ALIPHATIC OXYGEN COMPOUNDS

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491058A1 (en) * 1980-09-30 1982-04-02 Inst Francais Du Petrole IMPROVED PROCESS FOR THE CATALYTIC SYNTHESIS OF METHANE BY REACTING HYDROGEN WITH CARBON MONOXIDE
FR2564748A1 (en) * 1984-05-24 1985-11-29 Charbonnages Ste Chimique Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds
FR2573998A1 (en) * 1984-12-05 1986-06-06 Charbonnages Ste Chimique CARBON MONOXIDE HYDROCONDENSATION CATALYST, PROCESS FOR PREPARING THE SAME AND APPLICATION THEREOF TO THE MANUFACTURE OF HYDROCARBONS AND ALIPHATIC OXYGEN COMPOUNDS
EP0190518A1 (en) * 1984-12-05 1986-08-13 Norsolor S.A. Carbon monoxide hydrocondensation catalyst

Also Published As

Publication number Publication date
FR2374280B1 (en) 1979-03-30

Similar Documents

Publication Publication Date Title
CA2197574A1 (en) Process of producing methanol
KR940014744A (en) Method for producing gas rich in carbon monoxide
GB1002429A (en) Process for the preparation of alcohols
GB1265481A (en)
ES291987A1 (en) Catalytic process for the preparation of nitriles
ES469295A1 (en) Methanation process
ES429500A1 (en) Process for the carboxylation of alcohols in heterogeneous phase
ES407581A1 (en) Reactor for producing methanol and process
GB1129597A (en) Production of hydrogen
GB1306863A (en) Production of acetic acid
FR2374280A1 (en) Methane prepn. from carbon mon:oxide and hydrogen - using catalyst prepd. from nickel and aluminium cpds. in inert liquid
GB1072221A (en) Low-temperature, high pressure, catalytic conversion of hydrocarbons to hydrogen
ES2226406T3 (en) CATALYTIC SYSTEMS FOR PRODUCTION IN THE GASEOUS PHASE IN A SINGLE STAGE OF ACETIC ACID FROM ETHYLENE.
GB1047627A (en) Improvements in or relating to the reformation of light hydrocarbon feeds
ES478270A1 (en) Process for preparing town gas from methanol.
GB1458801A (en) Reactor for cracking hydrocarbons at an indirectly heated catalyst
Schreiner et al. Reversible homogeneous catalysis of carbon dioxide hydrogenation/reduction at room temperature and low pressures
JPS56169634A (en) Synthetic method of organic compound containing oxygen
Sugi et al. The homologation of methanol. The modification of cobalt catalyst by diphosphines
US2204978A (en) Method for producing cyclohexane and acetone
US3578423A (en) Process for catalytically splitting isobutyraldehyde to produce carbon monoxide and hydrogen
JPS55153732A (en) Alcohol manufacture
US3444260A (en) Method for preparing butadiene
GB1103592A (en) Synthesis pressure vessel
JPS60139341A (en) Oxidation to alpha, beta-unsaturated carboxylic acid of olefin by catalyst

Legal Events

Date Code Title Description
ST Notification of lapse