GB1069625A - Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous material - Google Patents
Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous materialInfo
- Publication number
- GB1069625A GB1069625A GB45854/62A GB4585462A GB1069625A GB 1069625 A GB1069625 A GB 1069625A GB 45854/62 A GB45854/62 A GB 45854/62A GB 4585462 A GB4585462 A GB 4585462A GB 1069625 A GB1069625 A GB 1069625A
- Authority
- GB
- United Kingdom
- Prior art keywords
- blowing agent
- resin
- impregnated
- fibrous sheet
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/245—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using natural fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/247—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using fibres of at least two types
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
Abstract
Sheet materials which may subsequently be moulded and used to form laminates comprise sheeted cellulosic fibrous materials, impregnated with a composition comprising a hardenable synthetic resin and a blowing agent which is stable at normal storage temperatures. The fibrous sheet materials may be impregnated with a solution or dispersion containing the resin and blowing agent in a volatile carrier and dried at a temperature sufficient to remove the carrier, e.g. an alcohol or water, but insufficient to cause hardening of the resin and decomposition of the blowing agent. Alternatively the fibrous sheet material may be impregnated with a liquid resin comprising the blowing agent, the resin being reacted to a solid, still fusible state while in situ in the material at a temperature below that at which the blowing agent decomposes. If the fibrous sheet material is a felt the powdered synthetic resin and powdered blowing agent may be incorporated therein during its manufacture. Suitable synthetic resins are phenolic, epoxy, polyester and urea- or melamineformaldehyde resins. The blowing agent may be dinitrosopentamethylenetetramine, p,p1-oxybis (benzene sulphonyl hydrazide), benzene sulphonyl hydrazide, urea oxalate or an inorganic blowing agent. The composition may also contain salicylic acid, stearic acid, dyes, pigments, fillers, waxes and surfactants. Fibre-reinforced expanded synthetic resin articles may subsequently be produced by heating in or on a mould one or more of the impregnated fibrous sheet materials at a temperature above the decomposition temperature of the blowing agent and the hardening temperature of the resin. The fibrous sheet material may be in the form of knitted fabrics, cross-creped paper, loosely woven or netted fabric, felts, paper creped only in one direction or tightly woven fabrics depending upon the amount of extension required during the subsequent moulding process. Fabrics comprising cotton fibres alone or in admixture with wool and viscose rayon fibres may be treated.ALSO:Sheet materials which may subsequently be moulded and used to form laminates comprise sheeted cellulosic fibrous materials impregnated with a composition comprising a hardenable synthetic resin and a blowing agent which is stable at normal storage temperatures. The fibrous sheet materials may be impregnated with a solution or dispersion containing the resin and blowing agent in a volatile carrier and dried at a temperature sufficient to remove the carrier, e.g. an alcohol or water but insufficient to cause hardening of the resin and decomposition of the blowing agent. Alternatively the fibrous sheet material may be impregnated with a liquid resin comprising the blowing agent, the resin being reacted to a solid, still fusible state while in situ in the material at a temperature below that at which the blowing agent decomposes. If the fibrous sheet material is a felt the powdered synthetic resin and powdered blowing agent may be incorporated therein during its manufacture. Suitable synthetic resins are phenolic, epoxy, polyester and urea- or melamineformaldehyde resins. The blowing agent may be dinitrosopentamethylenetetramine, P P1- oxybis (benzene sulphonyl hydrazide), benzene sulphonyl hydrazide, urea oxalate or an inorganic blowing agent. The composition may also contain salicylic acid, stearic acid, dyes, pigments, fillers, waxes and surfactants. Fibre-reinforced expanded synthetic resin articles may subsequently be produced by heating in or on a mould one or more of the impregnated fibrous sheet materials at a temperature above the decomposition temperature of the blowing agent and the hardening temperature of the resin. The fibrous sheet material may be in the form of knitted fabrics, cross-creped paper, loosely woven or netted fabric, felts, paper creped only in one direction or tightly woven fabrics depending upon the amount of extension required during the subsequent moulding process. Fabrics comprising cotton fibres alone or in admixture with wool and viscose rayon fibres may be treated.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB45854/62A GB1069625A (en) | 1962-12-04 | 1962-12-04 | Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB45854/62A GB1069625A (en) | 1962-12-04 | 1962-12-04 | Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous material |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1069625A true GB1069625A (en) | 1967-05-24 |
Family
ID=10438849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB45854/62A Expired GB1069625A (en) | 1962-12-04 | 1962-12-04 | Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous material |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1069625A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3513185A1 (en) * | 1984-04-13 | 1985-10-17 | Casco AB, Stockholm | IMPREGNATED PAPER AND METHOD FOR THE PRODUCTION THEREOF |
GB2177387A (en) * | 1985-07-02 | 1987-01-21 | Int Fuel Cells Corp | Carbon graphite component for electrochemical cell |
US4738872A (en) * | 1985-07-02 | 1988-04-19 | International Fuel Cells | Carbon-graphite component for an electrochemical cell and method for making the component |
WO1990014383A1 (en) * | 1989-05-18 | 1990-11-29 | ISOVOLTA Österreichische Isolierstoffwerke Aktiengesellschaft | Process for manufacturing a prepreg for use as a reinforcing inlay and use of said prepreg |
ES2235558A1 (en) * | 2002-02-22 | 2005-07-01 | Gamesa Desarrollos Aeronauticos, S.A. | Method of manufacturing a composite structure |
WO2011101343A1 (en) * | 2010-02-19 | 2011-08-25 | Roxel France | Novel composite materials and methods for manufacturing same |
WO2014009381A1 (en) * | 2012-07-13 | 2014-01-16 | Roxel France | Novel light composite materials, methods for manufacturing same, and uses thereof |
CN115368707A (en) * | 2022-09-20 | 2022-11-22 | 国际竹藤中心 | Plant fiber reinforced foaming composite material and preparation method and application thereof |
-
1962
- 1962-12-04 GB GB45854/62A patent/GB1069625A/en not_active Expired
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3513185A1 (en) * | 1984-04-13 | 1985-10-17 | Casco AB, Stockholm | IMPREGNATED PAPER AND METHOD FOR THE PRODUCTION THEREOF |
GB2157331A (en) * | 1984-04-13 | 1985-10-23 | Casco Ab | Impregnated paper and a method for its production |
GB2177387A (en) * | 1985-07-02 | 1987-01-21 | Int Fuel Cells Corp | Carbon graphite component for electrochemical cell |
US4738872A (en) * | 1985-07-02 | 1988-04-19 | International Fuel Cells | Carbon-graphite component for an electrochemical cell and method for making the component |
GB2177387B (en) * | 1985-07-02 | 1989-07-19 | Int Fuel Cells Corp | Carbon-graphite component for an electrochemical cell and method for making the component |
WO1990014383A1 (en) * | 1989-05-18 | 1990-11-29 | ISOVOLTA Österreichische Isolierstoffwerke Aktiengesellschaft | Process for manufacturing a prepreg for use as a reinforcing inlay and use of said prepreg |
ES2235558A1 (en) * | 2002-02-22 | 2005-07-01 | Gamesa Desarrollos Aeronauticos, S.A. | Method of manufacturing a composite structure |
WO2011101343A1 (en) * | 2010-02-19 | 2011-08-25 | Roxel France | Novel composite materials and methods for manufacturing same |
FR2956664A1 (en) * | 2010-02-19 | 2011-08-26 | L Aveyron Composite Atel | NEW COMPOSITE MATERIALS, PROCESSES FOR THEIR MANUFACTURE AND USES THEREOF |
CN103797052A (en) * | 2010-02-19 | 2014-05-14 | 法国罗克塞尔公司 | Novel composite materials and methods for manufacturing same |
US9624609B2 (en) | 2010-02-19 | 2017-04-18 | Roxel France | Composite materials |
WO2014009381A1 (en) * | 2012-07-13 | 2014-01-16 | Roxel France | Novel light composite materials, methods for manufacturing same, and uses thereof |
FR2993202A1 (en) * | 2012-07-13 | 2014-01-17 | Roxel France | NOVEL ALLEGED COMPOSITE MATERIALS, METHODS OF MAKING THE SAME, AND USES THEREOF. |
CN115368707A (en) * | 2022-09-20 | 2022-11-22 | 国际竹藤中心 | Plant fiber reinforced foaming composite material and preparation method and application thereof |
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