GB1042391A - Electrolytic cell, and process for producing phosphine therewith - Google Patents

Electrolytic cell, and process for producing phosphine therewith

Info

Publication number
GB1042391A
GB1042391A GB9212/64A GB921264A GB1042391A GB 1042391 A GB1042391 A GB 1042391A GB 9212/64 A GB9212/64 A GB 9212/64A GB 921264 A GB921264 A GB 921264A GB 1042391 A GB1042391 A GB 1042391A
Authority
GB
United Kingdom
Prior art keywords
diaphragm
fabric
aqueous electrolyte
therewith
electrolytic cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9212/64A
Inventor
George Theodore Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albright and Wilson Mfg Ltd
Original Assignee
Albright and Wilson Mfg Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US45669A external-priority patent/US3109795A/en
Priority claimed from US262497A external-priority patent/US3251756A/en
Application filed by Albright and Wilson Mfg Ltd filed Critical Albright and Wilson Mfg Ltd
Publication of GB1042391A publication Critical patent/GB1042391A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Glass Compositions (AREA)

Abstract

Phosphine is produced electrolytically in a cell having an aqueous electrolyte in the anode compartment, an aqueous electrolyte and molten phosphorus in the cathode compartment, and an ion-permeable diaphragm separating the two compartments, that part of the diaphragm which is exposed to the molten phosphorus being of a material (other than sintered glass) not wetted thereby, and recovering the cathodically evolved gas. The diaphragm may be of porous porcelain, aluminium oxide or resin-impregnated wool felt covered at least on the catholyte side with a phosphorusrepelling material such as glass fabric or a synthetic plastic or natural or chlorinated rubber fabric or graphite. The fabric may be adhered to the diaphragm body as by mechanical or heat action or may be formed on it, or may be a sheath into which the diaphragm body is inserted.
GB9212/64A 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith Expired GB1042391A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB26293/59A GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
US45669A US3109795A (en) 1960-07-27 1960-07-27 Method of preparing phosphine
US29249663A 1963-03-04 1963-03-04
US262498A US3337433A (en) 1959-07-31 1963-03-04 Electrolytic process
US262497A US3251756A (en) 1963-03-04 1963-03-04 Electrolytic process for making phosphine
US262496A US3312610A (en) 1959-07-31 1963-03-04 Electrolytic process for producing phosphine

Publications (1)

Publication Number Publication Date
GB1042391A true GB1042391A (en) 1966-09-14

Family

ID=27546704

Family Applications (4)

Application Number Title Priority Date Filing Date
GB26293/59A Expired GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
GB9214/64A Expired GB1042393A (en) 1959-07-31 1964-03-04 Process and apparatus for producing phosphine
GB9213/64A Expired GB1042392A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith
GB9212/64A Expired GB1042391A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith

Family Applications Before (3)

Application Number Title Priority Date Filing Date
GB26293/59A Expired GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
GB9214/64A Expired GB1042393A (en) 1959-07-31 1964-03-04 Process and apparatus for producing phosphine
GB9213/64A Expired GB1042392A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith

Country Status (4)

Country Link
US (2) US3337433A (en)
BE (3) BE694669A (en)
DE (4) DE1112722B (en)
GB (4) GB889639A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404076A (en) * 1965-04-15 1968-10-01 Shell Oil Co Electrolytic preparation of hydrides
DE102007033445A1 (en) 2007-07-18 2009-01-22 Monopharm Handelsgesellschaft Mbh Diaphragmalyse method and use of the products obtained by the method
DE102011055186A1 (en) * 2011-11-09 2013-05-16 Monopharm Beratungs- Und Handelsgesellschaft Mbh Process for the preparation of a catholyte and its use
CN112703274A (en) * 2018-11-28 2021-04-23 阿耶尔斯集团有限责任公司 Method and apparatus for energy efficient electrochemical production of hydride gases

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1094315A (en) * 1912-11-16 1914-04-21 Hood Rubber Co Inc PROCESS FOR PRODUCING 1.3-GLYCOLS, (β-GLYCOLS.)
US1926837A (en) * 1931-07-10 1933-09-12 Martin E Cupery Electrolytic reduction of organic nitro compounds
BE491944A (en) * 1948-12-27
US2780593A (en) * 1951-09-01 1957-02-05 New Jersey Zinc Co Production of metallic titanium
US2719822A (en) * 1952-01-10 1955-10-04 Universal Oil Prod Co Production of chlorine from hydrogen chloride
US2944956A (en) * 1956-11-16 1960-07-12 Dow Chemical Co Chlorine cell having protected diaphragm
US3017338A (en) * 1958-03-03 1962-01-16 Diamond Alkali Co Electrolytic process and apparatus
US3109795A (en) * 1960-07-27 1963-11-05 Hooker Chemical Corp Method of preparing phosphine
US3109788A (en) * 1960-07-27 1963-11-05 Hooker Chemical Corp Electrolytic production of phosphine

Also Published As

Publication number Publication date
DE1112722B (en) 1961-08-17
US3337433A (en) 1967-08-22
BE694669A (en) 1967-07-31
GB889639A (en) 1962-02-21
DE1210426B (en) 1966-02-10
BE694671A (en) 1967-07-31
BE694670A (en) 1967-07-31
DE1210425B (en) 1966-02-10
GB1042393A (en) 1966-09-14
DE1210424B (en) 1966-02-10
DE1210426C2 (en) 1966-09-22
GB1042392A (en) 1966-09-14
US3312610A (en) 1967-04-04

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