GB889639A - Improvements in or relating to the production of phosphine - Google Patents
Improvements in or relating to the production of phosphineInfo
- Publication number
- GB889639A GB889639A GB26293/59A GB2629359A GB889639A GB 889639 A GB889639 A GB 889639A GB 26293/59 A GB26293/59 A GB 26293/59A GB 2629359 A GB2629359 A GB 2629359A GB 889639 A GB889639 A GB 889639A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cathode
- metal
- anode
- electrolyte
- phosphine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Glass Compositions (AREA)
Abstract
889,639. Preparing phosphine electrolytically. ALBRIGHT & WILSON (MFG.) Ltd. July 26, 1960 [July 31, 1959], No. 26293/59. Class 41. Phosphine is made by passing an electric current through an aqueous electrolyte e.g. H3PO4 or H2SO4, using as cathode a metal having a hydrogen over-voltage, preferably mercury, in contact with white phosphorus preferably in molten state. The electrolyte is agitated to make contact with the cathode which may be Hg, Zn, Fe, Ni, Co, Ag, Cu, Cd, Al, Bi or Sn. Alternatively if an inert metal cathode is used, a metal salt e.g. PbSo4 is added to the electrolyte and the metal plated out on the cathode. A suitable apparatus consists of a glass vessel 10, Fig. 1, mercury cathode 11 with a supernatant layer of molten white phosphorus 13 which is agitated by a stirrer 15 to bring the mercury in contact with the aqueous electrolyte 14. Anode 17 is mounted in a glass tube 18 having a sintered glass separator 20, thus preventing phosphine from entering the anode compartment, where oxygen may be generated when a metal anode is used. A carbon anode generates Co2 when a separator is not essential. A solid metal cathode may be used, which projects through the aqueous electrolyte into the molten phosphorus which creeps up the outer surface of the electrode. As electrolyte, mineral acids, strong organic acids, or a salt e.g. alkali metal salt is specified for example phosphoric acid, containing a small amount of lead acetate or barium chloride. In examples, lead, an alloy of Ni, Cu, Cr and Fe, used as cathodes and lead peroxide, platinum, or an alloy of Sn and Bi as anode. U.S.A. Specification 1,375,819 is referred to.
Priority Applications (18)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB26293/59A GB889639A (en) | 1959-07-31 | 1959-07-31 | Improvements in or relating to the production of phosphine |
US45567A US3109787A (en) | 1959-07-31 | 1960-07-27 | Production of phosphine |
FR834368A FR1270717A (en) | 1959-07-31 | 1960-07-29 | Electrolytic production process for phosphine |
DEA35249A DE1112722B (en) | 1959-07-31 | 1960-08-01 | Process for the electrolytic production of phosphine |
US262496A US3312610A (en) | 1959-07-31 | 1963-03-04 | Electrolytic process for producing phosphine |
US262498A US3337433A (en) | 1959-07-31 | 1963-03-04 | Electrolytic process |
FR965832A FR85418E (en) | 1959-07-31 | 1964-03-03 | Electrolytic production process for phosphine |
FR965831A FR85417E (en) | 1959-07-31 | 1964-03-03 | Electrolytic production process for phosphine |
FR965830A FR85416E (en) | 1959-07-31 | 1964-03-03 | Electrolytic production process for phosphine |
GB9213/64A GB1042392A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
DEH51938A DE1210425B (en) | 1959-07-31 | 1964-03-04 | Process for the electrolytic production of phosphine |
DEH51937A DE1210424B (en) | 1959-07-31 | 1964-03-04 | Process for the electrolytic production of phosphine |
DE1964H0051939 DE1210426C2 (en) | 1959-07-31 | 1964-03-04 | Process for the electrolytic production of phosphine |
GB9214/64A GB1042393A (en) | 1959-07-31 | 1964-03-04 | Process and apparatus for producing phosphine |
GB9212/64A GB1042391A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
BE694670D BE694670A (en) | 1959-07-31 | 1967-02-27 | |
BE694671D BE694671A (en) | 1959-07-31 | 1967-02-27 | |
BE694669D BE694669A (en) | 1959-07-31 | 1967-02-27 |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB26293/59A GB889639A (en) | 1959-07-31 | 1959-07-31 | Improvements in or relating to the production of phosphine |
US45669A US3109795A (en) | 1960-07-27 | 1960-07-27 | Method of preparing phosphine |
US29249663A | 1963-03-04 | 1963-03-04 | |
US262496A US3312610A (en) | 1959-07-31 | 1963-03-04 | Electrolytic process for producing phosphine |
US262497A US3251756A (en) | 1963-03-04 | 1963-03-04 | Electrolytic process for making phosphine |
US262498A US3337433A (en) | 1959-07-31 | 1963-03-04 | Electrolytic process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB889639A true GB889639A (en) | 1962-02-21 |
Family
ID=27546704
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB26293/59A Expired GB889639A (en) | 1959-07-31 | 1959-07-31 | Improvements in or relating to the production of phosphine |
GB9212/64A Expired GB1042391A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
GB9213/64A Expired GB1042392A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
GB9214/64A Expired GB1042393A (en) | 1959-07-31 | 1964-03-04 | Process and apparatus for producing phosphine |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9212/64A Expired GB1042391A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
GB9213/64A Expired GB1042392A (en) | 1959-07-31 | 1964-03-04 | Electrolytic cell, and process for producing phosphine therewith |
GB9214/64A Expired GB1042393A (en) | 1959-07-31 | 1964-03-04 | Process and apparatus for producing phosphine |
Country Status (4)
Country | Link |
---|---|
US (2) | US3312610A (en) |
BE (3) | BE694671A (en) |
DE (4) | DE1112722B (en) |
GB (4) | GB889639A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3404076A (en) * | 1965-04-15 | 1968-10-01 | Shell Oil Co | Electrolytic preparation of hydrides |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007033445A1 (en) * | 2007-07-18 | 2009-01-22 | Monopharm Handelsgesellschaft Mbh | Diaphragmalyse method and use of the products obtained by the method |
DE102011055186A1 (en) * | 2011-11-09 | 2013-05-16 | Monopharm Beratungs- Und Handelsgesellschaft Mbh | Process for the preparation of a catholyte and its use |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1094315A (en) * | 1912-11-16 | 1914-04-21 | Hood Rubber Co Inc | PROCESS FOR PRODUCING 1.3-GLYCOLS, (β-GLYCOLS.) |
US1926837A (en) * | 1931-07-10 | 1933-09-12 | Martin E Cupery | Electrolytic reduction of organic nitro compounds |
BE491944A (en) * | 1948-12-27 | |||
US2780593A (en) * | 1951-09-01 | 1957-02-05 | New Jersey Zinc Co | Production of metallic titanium |
US2719822A (en) * | 1952-01-10 | 1955-10-04 | Universal Oil Prod Co | Production of chlorine from hydrogen chloride |
US2944956A (en) * | 1956-11-16 | 1960-07-12 | Dow Chemical Co | Chlorine cell having protected diaphragm |
US3017338A (en) * | 1958-03-03 | 1962-01-16 | Diamond Alkali Co | Electrolytic process and apparatus |
US3109795A (en) * | 1960-07-27 | 1963-11-05 | Hooker Chemical Corp | Method of preparing phosphine |
US3109788A (en) * | 1960-07-27 | 1963-11-05 | Hooker Chemical Corp | Electrolytic production of phosphine |
-
1959
- 1959-07-31 GB GB26293/59A patent/GB889639A/en not_active Expired
-
1960
- 1960-08-01 DE DEA35249A patent/DE1112722B/en active Pending
-
1963
- 1963-03-04 US US262496A patent/US3312610A/en not_active Expired - Lifetime
- 1963-03-04 US US262498A patent/US3337433A/en not_active Expired - Lifetime
-
1964
- 1964-03-04 DE DEH51937A patent/DE1210424B/en active Pending
- 1964-03-04 GB GB9212/64A patent/GB1042391A/en not_active Expired
- 1964-03-04 GB GB9213/64A patent/GB1042392A/en not_active Expired
- 1964-03-04 DE DEH51938A patent/DE1210425B/en active Pending
- 1964-03-04 DE DE1964H0051939 patent/DE1210426C2/en not_active Expired
- 1964-03-04 GB GB9214/64A patent/GB1042393A/en not_active Expired
-
1967
- 1967-02-27 BE BE694671D patent/BE694671A/xx unknown
- 1967-02-27 BE BE694670D patent/BE694670A/xx unknown
- 1967-02-27 BE BE694669D patent/BE694669A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3404076A (en) * | 1965-04-15 | 1968-10-01 | Shell Oil Co | Electrolytic preparation of hydrides |
Also Published As
Publication number | Publication date |
---|---|
DE1210426B (en) | 1966-02-10 |
DE1210426C2 (en) | 1966-09-22 |
DE1210424B (en) | 1966-02-10 |
GB1042393A (en) | 1966-09-14 |
BE694670A (en) | 1967-07-31 |
US3312610A (en) | 1967-04-04 |
BE694671A (en) | 1967-07-31 |
DE1112722B (en) | 1961-08-17 |
BE694669A (en) | 1967-07-31 |
GB1042392A (en) | 1966-09-14 |
US3337433A (en) | 1967-08-22 |
GB1042391A (en) | 1966-09-14 |
DE1210425B (en) | 1966-02-10 |
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