GB1042392A - Electrolytic cell, and process for producing phosphine therewith - Google Patents

Electrolytic cell, and process for producing phosphine therewith

Info

Publication number
GB1042392A
GB1042392A GB9213/64A GB921364A GB1042392A GB 1042392 A GB1042392 A GB 1042392A GB 9213/64 A GB9213/64 A GB 9213/64A GB 921364 A GB921364 A GB 921364A GB 1042392 A GB1042392 A GB 1042392A
Authority
GB
United Kingdom
Prior art keywords
plate
cathode
cell
vertical
therewith
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9213/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albright and Wilson Mfg Ltd
Original Assignee
Albright and Wilson Mfg Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US45669A external-priority patent/US3109795A/en
Priority claimed from US262497A external-priority patent/US3251756A/en
Application filed by Albright and Wilson Mfg Ltd filed Critical Albright and Wilson Mfg Ltd
Publication of GB1042392A publication Critical patent/GB1042392A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Glass Compositions (AREA)

Abstract

In the electrolytic preparation of phosphine in a cell employing an aqueous electrolyte and a diaphragm separate the cell into anode and cathode compartments, the cathode which may be of generally flat plate form with sharp bounding edges has a plurality of additional sharp edges disposed on one or more faces, preferably so that phosphorus wicks up over the whole cathode surface. The cell may be as described in the Specification. The cathode which may be of Pb, Pb-Hg amalgam, Cd, Sn,Al,Ni,Cu,Ag or Bi or alloys of these such as Pb-Sn,Pb-Bi and Sn-Bi may comprise a plate with deep vertical grooves, a plate with deep vertical and horizontal grooves or its complementary form, a vertically corrugated plate, an array of spaced vertical rectangular rods or adjoining vertical hexagonal rods, a plate with circular perforations or a plate with cylindrical projections with axes at perpendicular to the plate surfaces as depicted in Figs. 3 to 12 (not shown).
GB9213/64A 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith Expired GB1042392A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB26293/59A GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
US45669A US3109795A (en) 1960-07-27 1960-07-27 Method of preparing phosphine
US29249663A 1963-03-04 1963-03-04
US262498A US3337433A (en) 1959-07-31 1963-03-04 Electrolytic process
US262497A US3251756A (en) 1963-03-04 1963-03-04 Electrolytic process for making phosphine
US262496A US3312610A (en) 1959-07-31 1963-03-04 Electrolytic process for producing phosphine

Publications (1)

Publication Number Publication Date
GB1042392A true GB1042392A (en) 1966-09-14

Family

ID=27546704

Family Applications (4)

Application Number Title Priority Date Filing Date
GB26293/59A Expired GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
GB9214/64A Expired GB1042393A (en) 1959-07-31 1964-03-04 Process and apparatus for producing phosphine
GB9213/64A Expired GB1042392A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith
GB9212/64A Expired GB1042391A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB26293/59A Expired GB889639A (en) 1959-07-31 1959-07-31 Improvements in or relating to the production of phosphine
GB9214/64A Expired GB1042393A (en) 1959-07-31 1964-03-04 Process and apparatus for producing phosphine

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB9212/64A Expired GB1042391A (en) 1959-07-31 1964-03-04 Electrolytic cell, and process for producing phosphine therewith

Country Status (4)

Country Link
US (2) US3337433A (en)
BE (3) BE694669A (en)
DE (4) DE1112722B (en)
GB (4) GB889639A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404076A (en) * 1965-04-15 1968-10-01 Shell Oil Co Electrolytic preparation of hydrides
DE102007033445A1 (en) 2007-07-18 2009-01-22 Monopharm Handelsgesellschaft Mbh Diaphragmalyse method and use of the products obtained by the method
DE102011055186A1 (en) * 2011-11-09 2013-05-16 Monopharm Beratungs- Und Handelsgesellschaft Mbh Process for the preparation of a catholyte and its use
CN112703274A (en) * 2018-11-28 2021-04-23 阿耶尔斯集团有限责任公司 Method and apparatus for energy efficient electrochemical production of hydride gases

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1094315A (en) * 1912-11-16 1914-04-21 Hood Rubber Co Inc PROCESS FOR PRODUCING 1.3-GLYCOLS, (β-GLYCOLS.)
US1926837A (en) * 1931-07-10 1933-09-12 Martin E Cupery Electrolytic reduction of organic nitro compounds
BE491944A (en) * 1948-12-27
US2780593A (en) * 1951-09-01 1957-02-05 New Jersey Zinc Co Production of metallic titanium
US2719822A (en) * 1952-01-10 1955-10-04 Universal Oil Prod Co Production of chlorine from hydrogen chloride
US2944956A (en) * 1956-11-16 1960-07-12 Dow Chemical Co Chlorine cell having protected diaphragm
US3017338A (en) * 1958-03-03 1962-01-16 Diamond Alkali Co Electrolytic process and apparatus
US3109795A (en) * 1960-07-27 1963-11-05 Hooker Chemical Corp Method of preparing phosphine
US3109788A (en) * 1960-07-27 1963-11-05 Hooker Chemical Corp Electrolytic production of phosphine

Also Published As

Publication number Publication date
DE1112722B (en) 1961-08-17
US3337433A (en) 1967-08-22
BE694669A (en) 1967-07-31
GB889639A (en) 1962-02-21
DE1210426B (en) 1966-02-10
BE694671A (en) 1967-07-31
BE694670A (en) 1967-07-31
DE1210425B (en) 1966-02-10
GB1042393A (en) 1966-09-14
DE1210424B (en) 1966-02-10
DE1210426C2 (en) 1966-09-22
GB1042391A (en) 1966-09-14
US3312610A (en) 1967-04-04

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