GB1039741A - A method for electroplating objects with successive deposits of bright nickel and chromium - Google Patents
A method for electroplating objects with successive deposits of bright nickel and chromiumInfo
- Publication number
- GB1039741A GB1039741A GB5038/63A GB503863A GB1039741A GB 1039741 A GB1039741 A GB 1039741A GB 5038/63 A GB5038/63 A GB 5038/63A GB 503863 A GB503863 A GB 503863A GB 1039741 A GB1039741 A GB 1039741A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bright nickel
- bath
- sulphate
- intermediate layer
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/623—Porosity of the layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9265—Special properties
- Y10S428/927—Decorative informative
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/936—Chemical deposition, e.g. electroless plating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/1266—O, S, or organic compound in metal component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
- Y10T428/12854—Next to Co-, Fe-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12896—Ag-base component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
In electroplating an object with successive deposits of bright nickel and chromium, an intermediate metal layer of an average thickness of not substantially more than 2 m consisting of nickel, silver, or a metal or alloy which occupies a position between these metals in the electrochemical series, is electrodeposited from a bath containing also a solid non- or less-conducting material in suspension in the bath. The solid non- or less-conducting material preferably comprises particles of diameter not greater than 5m . The intermediate layer may be produced from a bright nickel sulphate-chloride bath to which is added colloidal silica, SiC, or BaSO4, AgCl or NiS formed by addition of Ba Cl2, Ag2CO3, or H2S respectively, or from a cyanide silver bath to which is added alumina or Ag2S formed by addition of K2S. The solid particles may be kept in suspension by stirring or if organic wetting agents are not present by air agitation. Reference is also made to the use of hydroxides of Fe, In, Al and Th but PbCrO4, PbS and HgS are mentioned as less suitable. Examples of bright nickel baths referred to are sulphate or sulphate-chloride baths buffered with boric acid and containing saccharin and butin-diol together with sodium lauryl sulphate, or formic acid and formaldehyde with cobalt as a metal brightener. If a bright nickel bath is used for the intermediate layer, adhesion to the original bright nickel layer may be improved either by first immersing the bright nickel plated object in an aqueous sulphuric acid solution of KI or by adding fluoride or fluoborate to the intermediate layer bath.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL275167 | 1962-02-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1039741A true GB1039741A (en) | 1966-08-24 |
Family
ID=19753635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5038/63A Expired GB1039741A (en) | 1962-02-23 | 1963-02-07 | A method for electroplating objects with successive deposits of bright nickel and chromium |
Country Status (5)
Country | Link |
---|---|
US (1) | US3298802A (en) |
DE (1) | DE1496927C3 (en) |
GB (1) | GB1039741A (en) |
NL (2) | NL122246C (en) |
SE (1) | SE302555B (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1447970A (en) * | 1964-10-12 | 1966-08-05 | Renault | Corrosion resistant decorative chrome deposits |
US3428441A (en) * | 1965-07-28 | 1969-02-18 | Kewanee Oil Co | Article coated with a composite particulate,microporous chromium coating and method of producing said article |
US3471271A (en) * | 1965-08-16 | 1969-10-07 | Udylite Corp | Electrodeposition of a micro-cracked corrosion resistant nickel-chromium plate |
US3523877A (en) * | 1966-03-23 | 1970-08-11 | Ethyl Corp | Method for treating a scrubbing solution for chlorinated hydrocarbons |
US3413711A (en) * | 1966-09-07 | 1968-12-03 | Western Electric Co | Method of making palladium copper contact for soldering |
FR1579266A (en) * | 1967-09-09 | 1969-08-22 | ||
GB1282373A (en) * | 1969-10-15 | 1972-07-19 | A I C Approvvigionamenti Ind C | Nickel-chromium electroplating |
USRE33767E (en) * | 1971-12-15 | 1991-12-10 | Surface Technology, Inc. | Method for concomitant particulate diamond deposition in electroless plating, and the product thereof |
US3812566A (en) * | 1972-07-03 | 1974-05-28 | Oxy Metal Finishing Corp | Composite nickel iron electroplate and method of making said electroplate |
JPS534498B2 (en) * | 1973-06-23 | 1978-02-17 | ||
DE3327346C2 (en) * | 1983-07-29 | 1986-03-27 | MTU Motoren- und Turbinen-Union München GmbH, 8000 München | Process for the production of a wear protection layer and its use |
GB0029954D0 (en) * | 2000-12-08 | 2001-01-24 | Caradon Mira Ltd | Improvements in or relating to metal finishes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL233860A (en) * | 1957-12-03 | 1900-01-01 | ||
US2871550A (en) * | 1958-01-10 | 1959-02-03 | Udylite Res Corp | Composite chromium electroplate and method of making same |
NL125956C (en) * | 1960-07-26 | |||
US3090733A (en) * | 1961-04-17 | 1963-05-21 | Udylite Res Corp | Composite nickel electroplate |
-
0
- NL NL275167D patent/NL275167A/xx unknown
- NL NL122246D patent/NL122246C/xx active
-
1963
- 1963-02-07 GB GB5038/63A patent/GB1039741A/en not_active Expired
- 1963-02-15 DE DE1496927A patent/DE1496927C3/en not_active Expired
- 1963-02-21 SE SE1893/63A patent/SE302555B/xx unknown
- 1963-02-25 US US260854A patent/US3298802A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US3298802A (en) | 1967-01-17 |
SE302555B (en) | 1968-07-22 |
DE1496927B2 (en) | 1975-04-24 |
DE1496927A1 (en) | 1969-12-18 |
NL122246C (en) | |
DE1496927C3 (en) | 1975-12-04 |
NL275167A (en) |
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