GB1027005A - Improvements in the production of cycloalkanols and cycloalkanones and of borate esters of cycloalkanols - Google Patents
Improvements in the production of cycloalkanols and cycloalkanones and of borate esters of cycloalkanolsInfo
- Publication number
- GB1027005A GB1027005A GB44580/62A GB4458062A GB1027005A GB 1027005 A GB1027005 A GB 1027005A GB 44580/62 A GB44580/62 A GB 44580/62A GB 4458062 A GB4458062 A GB 4458062A GB 1027005 A GB1027005 A GB 1027005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzene
- cyclohexane
- line
- cycloalkane
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001642 boronic acid derivatives Chemical class 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 24
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 8
- 238000007254 oxidation reaction Methods 0.000 abstract 7
- 150000001924 cycloalkanes Chemical class 0.000 abstract 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 6
- 230000003647 oxidation Effects 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- -1 borate ester Chemical class 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 abstract 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001639 boron compounds Chemical class 0.000 abstract 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 abstract 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15480261A | 1961-11-24 | 1961-11-24 | |
| US208133A US3239552A (en) | 1962-07-06 | 1962-07-06 | Process of preparing borate esters of cycloalkanols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1027005A true GB1027005A (en) | 1966-04-20 |
Family
ID=26851791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB44580/62A Expired GB1027005A (en) | 1961-11-24 | 1962-11-26 | Improvements in the production of cycloalkanols and cycloalkanones and of borate esters of cycloalkanols |
Country Status (7)
| Country | Link |
|---|---|
| CH (1) | CH462801A (fr) |
| DE (1) | DE1300938C2 (fr) |
| GB (1) | GB1027005A (fr) |
| LU (1) | LU43996A1 (fr) |
| NL (1) | NL285860A (fr) |
| NO (1) | NO118432B (fr) |
| SE (1) | SE331837B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112742367A (zh) * | 2019-10-29 | 2021-05-04 | 中国石油化工股份有限公司 | 一种催化氧化环烷烃的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2931834A (en) * | 1960-04-05 | Ctclohexane oxidation process | ||
| US1947989A (en) * | 1928-06-20 | 1934-02-20 | Firm A Riebeck Sche Montanwerk | Method of oxidizing hydrocarbons |
| US2931501A (en) * | 1953-10-01 | 1960-04-05 | Archer Daniels Midland Co | Hydraulic flotation system |
| DE1046610B (de) * | 1955-06-15 | 1958-12-18 | Basf Ag | Verfahren zur Herstellung von Cyclohexanol und Cyclohexanon durch Oxydation von Cyclohexan |
| DE1158963B (de) * | 1961-01-31 | 1963-12-12 | Halcon International Inc | Verfahren zur Oxydation von gesaettigten Kohlenwasserstoffen |
-
0
- NL NL285860D patent/NL285860A/xx unknown
-
1962
- 1962-11-24 DE DE1962S0082569 patent/DE1300938C2/de not_active Expired
- 1962-11-26 GB GB44580/62A patent/GB1027005A/en not_active Expired
-
1963
- 1963-07-02 LU LU43996D patent/LU43996A1/xx unknown
- 1963-07-05 NO NO149300A patent/NO118432B/no unknown
- 1963-07-05 CH CH843463A patent/CH462801A/fr unknown
- 1963-07-08 SE SE07555/63A patent/SE331837B/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112742367A (zh) * | 2019-10-29 | 2021-05-04 | 中国石油化工股份有限公司 | 一种催化氧化环烷烃的方法 |
| CN112742367B (zh) * | 2019-10-29 | 2023-07-11 | 中国石油化工股份有限公司 | 一种催化氧化环烷烃的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1300938B (de) | 1969-08-14 |
| DE1300938C2 (de) | 1974-02-07 |
| CH462801A (fr) | 1968-09-30 |
| NL285860A (fr) | |
| NO118432B (fr) | 1969-12-29 |
| SE331837B (fr) | 1971-01-18 |
| LU43996A1 (fr) | 1963-09-03 |
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