GB1026366A - Substituted methylenediphosphonic acid compounds and detergent compositions containing them - Google Patents

Substituted methylenediphosphonic acid compounds and detergent compositions containing them

Info

Publication number
GB1026366A
GB1026366A GB11411/64A GB1141164A GB1026366A GB 1026366 A GB1026366 A GB 1026366A GB 11411/64 A GB11411/64 A GB 11411/64A GB 1141164 A GB1141164 A GB 1141164A GB 1026366 A GB1026366 A GB 1026366A
Authority
GB
United Kingdom
Prior art keywords
diphosphonic acid
acid
sodium
radical
methylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11411/64A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1026366A publication Critical patent/GB1026366A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/367—Organic compounds containing phosphorus containing halogen
    • C11D3/368—Organic compounds containing phosphorus containing halogen containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4025—Esters of poly(thio)phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/367—Organic compounds containing phosphorus containing halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
GB11411/64A 1963-03-18 1964-03-18 Substituted methylenediphosphonic acid compounds and detergent compositions containing them Expired GB1026366A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US26605563A 1963-03-18 1963-03-18
DE1793768A DE1793768C3 (de) 1963-03-18 1964-03-17 Substituierte Methylendiphosphonsäuren und deren wasserlösliche Salze
US493925A US3404178A (en) 1963-03-18 1965-10-07 Substituted methylene diphosphonic acids and their salts
NL6514133A NL6514133A (https=) 1963-03-18 1965-11-01
BE672205A BE672205A (https=) 1963-03-18 1965-11-10

Publications (1)

Publication Number Publication Date
GB1026366A true GB1026366A (en) 1966-04-20

Family

ID=27507640

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11411/64A Expired GB1026366A (en) 1963-03-18 1964-03-18 Substituted methylenediphosphonic acid compounds and detergent compositions containing them

Country Status (11)

Country Link
US (2) US3422021A (https=)
AU (1) AU289589B2 (https=)
BE (1) BE672205A (https=)
CA (1) CA777769A (https=)
CH (1) CH465745A (https=)
DE (2) DE1793768C3 (https=)
FI (1) FI42559B (https=)
FR (1) FR1457272A (https=)
GB (1) GB1026366A (https=)
NL (1) NL6514133A (https=)
SE (1) SE300479B (https=)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497313A (en) * 1966-12-29 1970-02-24 Procter & Gamble Carbonyldiphosphonates
US3527795A (en) * 1967-11-20 1970-09-08 Monsanto Co Process for preparing water-soluble salts of organic phosphorus acids
US4416877A (en) 1979-02-13 1983-11-22 Symphar S.A. Anti-atherosclerotic pharmaceutical compositions containing diphosphonate compounds
US4478761A (en) * 1980-04-28 1984-10-23 University Of Iowa Research Foundation Method for preparing fluorine-containing phosphonates
EP0353973A3 (en) * 1988-07-30 1990-10-17 Icn Biomedicals Limited Phosphate-free detergents
WO1991003480A1 (en) * 1989-09-08 1991-03-21 Huhtamäki Oy Process for the preparation of methylenebisphosphonic acids
US5858117A (en) * 1994-08-31 1999-01-12 Ecolab Inc. Proteolytic enzyme cleaner
US5861366A (en) * 1994-08-31 1999-01-19 Ecolab Inc. Proteolytic enzyme cleaner
WO2001021629A1 (en) * 1999-09-17 2001-03-29 Astrazeneca Uk Limited Process for preparing methylene bisphosphonic and salts
WO2016079110A2 (en) 2014-11-19 2016-05-26 Novozymes A/S Use of enzyme for cleaning
WO2019067173A1 (en) 2017-09-29 2019-04-04 Ecolab Usa Inc. USE OF EXTENSIVE SURFACTANTS IN CLEANING A TREATMENT MEMBRANE

Families Citing this family (109)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1103590A (en) * 1965-12-22 1968-02-14 Procter & Gamble Ltd Soap compositions
GB1209486A (en) * 1966-12-16 1970-10-21 Monsanto Co Phosporus-containing organic compounds
US3624188A (en) * 1968-10-25 1971-11-30 Procter & Gamble Hypohalogenation of tetramethyl and tetraethyl methylenediphosphonates and trihydrocarbyl phosphonoacetates
US3962318A (en) * 1970-04-13 1976-06-08 Monsanto Company Substituted ethane diphosphonic acids and salts and esters thereof
US3705191A (en) * 1970-04-13 1972-12-05 Monsanto Co Substituted ethane diphosphonic acids and salts and esters thereof
DE2343195C2 (de) * 1973-08-27 1981-11-19 Henkel KGaA, 4000 Düsseldorf Cyclische Aminophosphonsäuren und Verfahren zu deren Herstellung
GB1445606A (en) * 1973-10-23 1976-08-11 Unilever Ltd Fabric-softening compositions
US3906062A (en) * 1974-08-09 1975-09-16 Monsanto Co Alpha,alpha-diphosphonato acetanilides
US3907937A (en) * 1974-08-09 1975-09-23 Monsanto Co Alpha-cyano-alpha-dialkylphosphonato acetanilides
US3966628A (en) * 1974-08-21 1976-06-29 Westvaco Corporation Solid cleaning compositions containing C21 dicarboxylic acid
US3962100A (en) * 1975-08-18 1976-06-08 The Procter & Gamble Company Fabric softening agents
US4025444A (en) * 1975-08-18 1977-05-24 The Procter & Gamble Company Fabric softening agents
US4120890A (en) * 1976-01-21 1978-10-17 Henkel Kommanditgesellschaft Auf Aktien Diphosphonoalkane carboxylic acids, process of preparation and methods of use
DE2602030C2 (de) * 1976-01-21 1983-12-01 Henkel KGaA, 4000 Düsseldorf Diphosphonoalkancarbonsäuren und Verfahren zu deren Herstellung
NL7711307A (nl) * 1976-10-19 1978-04-21 Hoechst Ag Fosforcarbonzuurverbindingen en hun bereiding.
US4138431A (en) * 1978-06-29 1979-02-06 Nalco Chemical Company Reaction of α-phosphorus containing carboxylic acids with phosphorous acid to prepare scale and corrosion inhibitors
FR2489711A1 (fr) * 1980-04-21 1982-03-12 Minemet Rech Sa Compositions echangeuses de cations metalliques
US4330486A (en) * 1980-04-28 1982-05-18 University Of Iowa Reseach Foundation Bis(phosphonic acid) difluoromethane
GB2152041B (en) 1983-12-22 1987-11-11 Procter & Gamble X-substituted derivatives of carboxylic acids used as peroxygen bleach activators
GB8419489D0 (en) * 1984-07-31 1984-09-05 Leo Pharm Prod Ltd Chemical compounds
IT1187828B (it) * 1985-05-24 1987-12-23 Gentili Ist Spa Composizione farmaceutica a base di difosfonati per il trattamento dell aretrosi
US4818774A (en) * 1986-03-10 1989-04-04 Occidental Chemical Corporation Organophosphorus compounds
CH675422A5 (https=) * 1988-03-31 1990-09-28 Symphar Sa
US5496857A (en) * 1994-03-17 1996-03-05 Targosz; Eugene F. Whitefly insecticide
USH1468H (en) 1994-04-28 1995-08-01 Costa Jill B Detergent compositions containing cellulase enzyme and selected perfumes for improved odor and stability
EP0693549A1 (en) 1994-07-19 1996-01-24 The Procter & Gamble Company Solid bleach activator compositions
GB2297978A (en) 1995-02-15 1996-08-21 Procter & Gamble Detergent compositions containing amylase
JPH11511041A (ja) 1995-06-06 1999-09-28 メルク エンド カンパニー インコーポレーテッド 整形外科的埋め込み装置の無菌性動揺を防止するビスホスホネートセメント組成物
ATE165110T1 (de) 1995-07-13 1998-05-15 Procter & Gamble Verpackte schäumende zusammensetzung
ATE277141T1 (de) 1995-07-13 2004-10-15 Procter & Gamble Verfahren zur reinigung von textilprodukten
EP0763594B1 (en) 1995-09-18 2003-07-02 The Procter & Gamble Company Process for making granular detergents
ATE211728T1 (de) 1995-11-02 2002-01-15 Procter & Gamble Aminoester von parfümalkoholen und ihre verwendung in reinigungs- und waschmittelzusammensetzungen
WO1997042282A1 (en) 1996-05-03 1997-11-13 The Procter & Gamble Company Detergent compositions comprising polyamine polymers with improved soil dispersancy
US7205404B1 (en) * 1999-03-05 2007-04-17 Metabasis Therapeutics, Inc. Phosphorus-containing prodrugs
JP2003521567A (ja) 1999-07-16 2003-07-15 ザ、プロクター、エンド、ギャンブル、カンパニー 双極性ポリアミンおよび中間鎖分岐界面活性剤を含んでなる洗濯洗剤組成物
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
AU2001288407A1 (en) 2000-08-30 2002-03-13 The Procter And Gamble Company Granular bleach activators having improved solubility profiles
GB2366797A (en) * 2000-09-13 2002-03-20 Procter & Gamble Process for making foam component by pressurising/depressurising
US20030206965A1 (en) * 2000-09-29 2003-11-06 The Procter & Gamble Company Allergen neutralization compositions
US20030203035A1 (en) * 2000-09-29 2003-10-30 The Procter & Gamble Company Allergen neutralization compositions
US6387864B1 (en) 2000-12-15 2002-05-14 Ecolab Inc. Composition and method for prevention of discoloration of detergents using nonionic surfactants and an alkaline source
US20020183226A1 (en) * 2001-02-28 2002-12-05 Chandrika Kasturi Liquid detergent composition exhibiting enhanced alpha-amylase enzyme stability
EP1239025A3 (de) 2001-03-03 2003-09-03 Clariant GmbH Waschmittel und Wäschebehandlungsmittel enthaltend farbübertragungsinhibierend Farbfixiermittel
DE10150724A1 (de) 2001-03-03 2003-04-17 Clariant Gmbh Waschmittel und Wäschebehandlungsmittel enthaltend ein oder mehrere farbübertragungsinhibierende Farbfixiermittel
WO2003047417A2 (en) * 2001-12-03 2003-06-12 Merck & Co., Inc. Ep4 receptor agonist, compositions and methods thereof
SK2532004A3 (en) * 2001-12-21 2004-11-03 Procter & Gamble Method for the treatment of bone disorders
US20050070504A1 (en) * 2001-12-21 2005-03-31 The Procter & Gamble Co. Risedronate compositions and their methods of use
JP4502641B2 (ja) * 2002-01-24 2010-07-14 ティルタン ファーマ リミテッド 抗癌組み合わせおよびその使用方法
AU2004266740B2 (en) 2003-08-21 2010-08-26 Merck Frosst Canada Ltd Cathepsin cysteine protease inhibitors
WO2005090370A1 (en) * 2004-02-05 2005-09-29 The Regents Of The University Of California Pharmacologically active agents containing esterified phosphonates and methods for use thereof
DE102004018051A1 (de) * 2004-04-08 2005-11-10 Clariant Gmbh Wasch- und Reinigungsmittel enthaltend Farbfixiermittel und Soil Release Polymere
DK2283825T3 (da) 2004-05-24 2022-06-27 Theramex Hq Uk Ltd Enterisk fast oral doseringsform af en bisfosfonat indeholdende et chelateringsmiddel
UA87854C2 (en) 2004-06-07 2009-08-25 Мерк Энд Ко., Инк. N-(2-benzyl)-2-phenylbutanamides as androgen receptor modulators
DE102004029310A1 (de) * 2004-06-17 2005-12-29 Clariant Gmbh Hochkonzentrierte, wässrige Formulierungen von Oligo-und Polyestern
AU2006302797B2 (en) 2005-03-02 2012-02-02 Merck Canada Inc. Composition for inhibition of cathepsin K
CN101198316A (zh) * 2005-03-17 2008-06-11 伊兰制药国际有限公司 纳米微粒双膦酸盐组合物
JP2008535862A (ja) 2005-04-08 2008-09-04 キメリクス，インコーポレイテッド ポックスウイルス感染の治療のための化合物、組成物および方法
JP2008538354A (ja) * 2005-04-08 2008-10-23 キメリクス，インコーポレイテッド ウイルス感染症およびその他の内科疾患を治療するための化合物、組成物および方法
DE102005061058A1 (de) * 2005-12-21 2007-07-05 Clariant Produkte (Deutschland) Gmbh Anionische Soil Release Polymere
US7674757B2 (en) * 2006-01-23 2010-03-09 Milliken & Company Laundry care compositions with thiazolium dye
SK287193B6 (sk) * 2006-03-03 2010-03-08 Glebus Alloys Europe S.R.O. Odvzdušňovací ventil do odvzdušňovacích otvorov vulkanizačných foriem
US7638475B2 (en) 2006-03-24 2009-12-29 Georgia-Pacific Consumer Products Lp Space saving toilet cleaning system
WO2008100411A1 (en) * 2007-02-09 2008-08-21 The Procter & Gamble Company Perfume systems
US7487720B2 (en) 2007-03-05 2009-02-10 Celanese Acetate Llc Method of making a bale of cellulose acetate tow
DE102007013217A1 (de) 2007-03-15 2008-09-18 Clariant International Ltd. Anionische Soil Release Polymere
DE102007028310A1 (de) 2007-06-20 2008-12-24 Clariant International Ltd. Tensidmischungen mit synergistischen Eigenschaften
EP2254582B1 (en) * 2008-01-25 2016-01-20 Chimerix, Inc. Methods of treating viral infections
DE102008023803A1 (de) 2008-05-15 2009-11-26 Clariant International Ltd. Additive für Wasch- und Reinigungsmittel
US7790664B2 (en) * 2008-10-27 2010-09-07 The Procter & Gamble Company Methods for making a nil-phosphate liquid automatic dishwashing composition
US20100197545A1 (en) * 2009-01-30 2010-08-05 Ecolab USA High alkaline detergent composition with enhanced scale control
US8614200B2 (en) 2009-07-21 2013-12-24 Chimerix, Inc. Compounds, compositions and methods for treating ocular conditions
WO2011017253A1 (en) 2009-08-03 2011-02-10 Chimerix, Inc. Composition and methods of treating viral infections and viral induced tumors
JP5678084B2 (ja) 2009-11-27 2015-02-25 クラリアント・ファイナンス・（ビーブイアイ）・リミテッド 灰色化防止（ｖｅｒｇｒａｕｕｎｇｓｉｎｈｉｂｉｅｒｅｎｄｅｒ）効果および高い溶液安定性を有するソイルリリースポリマー
ES2492500T3 (es) 2009-11-27 2014-09-09 Clariant Finance (Bvi) Limited Utilización de unos concentrados de poliésteres que tienen una alta estabilidad en solución y un efecto inhibidor del agrisamiento en agentes de lavado y limpieza
WO2011100420A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
WO2011100405A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
US20110201534A1 (en) 2010-02-12 2011-08-18 Jennifer Beth Ponder Benefit compositions comprising polyglycerol esters
US9006218B2 (en) 2010-02-12 2015-04-14 Chimerix Inc. Nucleoside phosphonate salts
WO2011100411A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising polyglycerol esters
US9278135B2 (en) 2010-04-26 2016-03-08 Chimerix Inc. Methods of treating retroviral infections and related dosage regimes
RU2012147538A (ru) 2010-05-14 2014-06-20 3Е Сан Продактс Корпорейшн Полимерсодержащие очищающие композиции и способы их получения и применения
CN103228734A (zh) 2010-09-20 2013-07-31 宝洁公司 非含氟聚合物表面保护组合物
EP2619299B1 (en) 2010-09-20 2018-02-28 Wacker Chemie AG Fabric care formulations and methods
EP2619272B1 (en) 2010-09-20 2017-12-06 The Procter and Gamble Company Non-fluoropolymer surface protection composition
WO2012112363A1 (en) 2011-02-14 2012-08-23 Merck Sharp & Dohme Corp. Cathepsin cysteine protease inhibitors
ES2554243T3 (es) 2011-07-12 2015-12-17 Weylchem Switzerland Ag Empleo de una combinación de sulfonato de parafina secundario y amilasa para el aumento del poder de limpieza de agentes de lavado líquidos
US20140193887A1 (en) 2011-07-12 2014-07-10 Clariant International Ltd. Use of Secondary Paraffin Sulfonates for Increasing the Cleaning Capacity of Enzymes
US8623151B2 (en) 2012-03-23 2014-01-07 Ecolab Usa Inc. Terpolymer containing maleic acid, vinyl acetate, and alkyl acrylate monomers for aluminum protection
US8740993B2 (en) 2012-03-23 2014-06-03 Ecolab Usa Inc. Method for reduced encrustation of textiles using a polymer comprising maleic acid, vinyl acetate, and alkyl acrylate
DE102012015826A1 (de) 2012-08-09 2014-02-13 Clariant International Ltd. Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen
US9796952B2 (en) 2012-09-25 2017-10-24 The Procter & Gamble Company Laundry care compositions with thiazolium dye
DE102013004428A1 (de) 2013-03-15 2014-09-18 Clariant International Ltd. Verfahren zum Waschen und Reinigen von Textilien
EP2857486A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857487A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857485A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
WO2015051479A1 (en) 2013-10-08 2015-04-16 Merck Sharp & Dohme Corp. Cathepsin cysteine protease inhibitors
WO2015054089A1 (en) 2013-10-08 2015-04-16 Merck Sharp & Dohme Corp. Cathepsin cysteine protease inhibitors
WO2015120580A1 (en) 2014-02-11 2015-08-20 Merck Sharp & Dohme Corp. Cathepsin cysteine protease inhibitors
JP2017512183A (ja) 2014-02-13 2017-05-18 リガンド・ファーマシューティカルズ・インコーポレイテッド プロドラッグ化合物およびそれらの使用
PL407922A1 (pl) 2014-04-16 2015-10-26 Wrocławskie Centrum Badań Eit + Spółka Z Ograniczoną Odpowiedzialnością Nowe bisfosfoniany i ich zastosowanie
SG11201609050UA (en) 2014-05-30 2016-12-29 Pfizer Carbonitrile derivatives as selective androgen receptor modulators
CN106687118A (zh) 2014-07-02 2017-05-17 配体药物公司 前药化合物及其用途
DE102016223590A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymer enthaltende reinigungsmittelzusammensetzungen
DE102016223584A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymer enthaltende waschmittelzusammensetzungen
DE102016223585A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymere und deren verwendung in waschmittel-zusammensetzungen
DE102016223588A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen
DE102016223586A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen
RU2020126177A (ru) 2018-01-09 2022-02-10 Лиганд Фармасьютикалз, Инк. Ацетальные соединения и их терапевтическое применение
WO2023275715A1 (en) 2021-06-30 2023-01-05 Pfizer Inc. Metabolites of selective androgen receptor modulators

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3125412A (en) * 1964-03-17 Process ok the manufacture of alkali
US2286794A (en) * 1940-10-09 1942-06-16 Eastman Kodak Co Yarn conditioning process and composition therefor
US2594454A (en) * 1946-05-31 1952-04-29 Monsanto Chemicals Organic phosphorus acids and esters
DE973122C (de) * 1949-03-11 1959-12-03 Hoechst Ag Verfahren zur Herstellung geformter Waschmittel
BE551039A (https=) * 1955-09-16
DE1045373B (de) * 1957-04-26 1958-12-04 Hoechst Ag Verwendung von Phosphonsaeuren
US3029205A (en) * 1958-05-05 1962-04-10 Lever Brothers Ltd Light duty liquid detergent
NL121615C (https=) * 1958-09-06 1900-01-01
NL248125A (https=) * 1959-02-06
US3001945A (en) * 1959-04-29 1961-09-26 Procter & Gamble Liquid detergent composition
NL130828C (https=) * 1959-06-03
US3093672A (en) * 1960-10-03 1963-06-11 Monsanto Chemicals Diphosphonate alkyl esters
NL132418C (https=) * 1962-04-13
US3256370A (en) * 1962-12-13 1966-06-14 Monsanto Co Process for preparing alkylene-diphosphonates

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497313A (en) * 1966-12-29 1970-02-24 Procter & Gamble Carbonyldiphosphonates
US3527795A (en) * 1967-11-20 1970-09-08 Monsanto Co Process for preparing water-soluble salts of organic phosphorus acids
US4416877A (en) 1979-02-13 1983-11-22 Symphar S.A. Anti-atherosclerotic pharmaceutical compositions containing diphosphonate compounds
US4478761A (en) * 1980-04-28 1984-10-23 University Of Iowa Research Foundation Method for preparing fluorine-containing phosphonates
EP0353973A3 (en) * 1988-07-30 1990-10-17 Icn Biomedicals Limited Phosphate-free detergents
WO1991003480A1 (en) * 1989-09-08 1991-03-21 Huhtamäki Oy Process for the preparation of methylenebisphosphonic acids
US5237094A (en) * 1989-09-08 1993-08-17 Leiras Oy Process for the preparation of methylenebisphosphonic acids
US5858117A (en) * 1994-08-31 1999-01-12 Ecolab Inc. Proteolytic enzyme cleaner
US5861366A (en) * 1994-08-31 1999-01-19 Ecolab Inc. Proteolytic enzyme cleaner
US6197739B1 (en) 1994-08-31 2001-03-06 Ecolab Inc. Proteolytic enzyme cleaner
WO2001021629A1 (en) * 1999-09-17 2001-03-29 Astrazeneca Uk Limited Process for preparing methylene bisphosphonic and salts
US6657076B1 (en) 1999-09-17 2003-12-02 Astrazeneca Uk Limited Process for preparing methylene bisphosphonic and salts
AU771628B2 (en) * 1999-09-17 2004-04-01 Astrazeneca Uk Limited Process for preparing methylene bisphosphonic and salts
US7288673B2 (en) 1999-09-17 2007-10-30 Astrazeneca Uk Limited Salts of substituted methylene bisphosphonic acids
WO2016079110A2 (en) 2014-11-19 2016-05-26 Novozymes A/S Use of enzyme for cleaning
WO2019067173A1 (en) 2017-09-29 2019-04-04 Ecolab Usa Inc. USE OF EXTENSIVE SURFACTANTS IN CLEANING A TREATMENT MEMBRANE

Also Published As

Publication number Publication date
US3422021A (en) 1969-01-14
US3404178A (en) 1968-10-01
DE1467655C3 (de) 1975-09-25
CH465745A (de) 1968-11-30
CA777769A (en) 1968-02-06
DE1793768C3 (de) 1979-06-07
DE1793768B2 (de) 1978-10-05
SE300479B (https=) 1968-04-29
AU289589B2 (en) 1969-03-17
DE1467655A1 (de) 1969-09-25
FR1457272A (fr) 1966-01-24
NL6514133A (https=) 1967-05-02
BE672205A (https=) 1966-05-10
DE1467655B2 (de) 1973-11-08
FI42559B (https=) 1970-06-01
AU4194564A (en) 1966-09-08
DE1793768A1 (de) 1974-02-28

Similar Documents

Publication Publication Date Title
GB1026366A (en) Substituted methylenediphosphonic acid compounds and detergent compositions containing them
AU596244B2 (en) Aqueous detergent compositions containing diethyleneglycol monohexyl ether solvent
US3865755A (en) Detergent composition
EP0213729B1 (en) Detergent compositions
US3502585A (en) Detergent compositions containing propanepolyphosphonate compounds
IE63070B1 (en) Liquid detergent containing solid peroxygen bleach
GB1503344A (en) Liquid detergent compositions
GB1399966A (en) Detergent compositions
US5250212A (en) Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol
US3697453A (en) Iminodisuccinic acid salts as detergent builders
US3590001A (en) Phosphate free heavy duty detergent formulations
GB1408970A (en) Detergent compositions
US3304263A (en) Phosphine oxide detergent composition
US4440646A (en) Chelation
US3855248A (en) Dioxolane polycarboxylates
US3346629A (en) Process for preparing beta-ethylenically unsaturated organic sulfonates
US3864286A (en) Detergent composition with disulfonated catechol as detergent builder
CA1052220A (en) Detergent composition
GB1483780A (en) Hot-gelling alkali cleaning compositions and process for cleaning surfaces
US3170915A (en) Sucrose ethers
US3704320A (en) Detergent formulations
US3471406A (en) Detergent compositions containing methane tri and tetra phosphonic acid compounds
US3332875A (en) Detergent composition
US3562169A (en) Detergent compositions containing oligomeric ester chain condensates of ethane-1-hydroxy-1,1-diphosphonic acid as builders
US3355494A (en) Preparation of ketosulfoxides