GB1269378A - Low sudsing detergent compositions - Google Patents
Low sudsing detergent compositionsInfo
- Publication number
- GB1269378A GB1269378A GB36728/69A GB3672869A GB1269378A GB 1269378 A GB1269378 A GB 1269378A GB 36728/69 A GB36728/69 A GB 36728/69A GB 3672869 A GB3672869 A GB 3672869A GB 1269378 A GB1269378 A GB 1269378A
- Authority
- GB
- United Kingdom
- Prior art keywords
- detergent
- agents
- sodium
- soap
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000000344 soap Substances 0.000 abstract 5
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 239000011734 sodium Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 235000021317 phosphate Nutrition 0.000 abstract 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- 102000004190 Enzymes Human genes 0.000 abstract 1
- 108090000790 Enzymes Proteins 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 abstract 1
- 150000008041 alkali metal carbonates Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- -1 alkyl sulphates Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 229940105329 carboxymethylcellulose Drugs 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 125000003709 fluoroalkyl group Chemical group 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000003352 sequestering agent Substances 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- 229940045872 sodium percarbonate Drugs 0.000 abstract 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 239000000271 synthetic detergent Substances 0.000 abstract 1
- 239000003760 tallow Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0418—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing P-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/367—Organic compounds containing phosphorus containing halogen
- C11D3/368—Organic compounds containing phosphorus containing halogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
1,269,378. Low sudsing detergent composition. PROCTER & GAMBLE CO. 22 July, 1969 [22 July, 1968], No. 36728/69. Heading C5D. A low to medium sudsing detergent composition comprises by weight (A) 2 to 30% of a soap or non-soap detergent, (B) 2 to 65% of a detergent builder, and (C) 0À1 to 8% of one or more fluoroalkyl suds-suppressing agents of formula in which each R independently is or and when y = 2 one R may be H; and in which m is an integer of 1 to 12, n is an integer of 1 to 16 and the total of m + n is 2 to 18, y is a number of average value 1.0 to 2.5 (includes mixtures), R<SP>1</SP> is H or F and m is H, alkali metal, ammonium or substituted ammonium. Examples of (C) are phosphates of formula H(CF 2 ) 10 CH 2 O.PO(OH) 2 (Specification 971,585) and phosphonates of formula H(CF 2 ) 10 CH 2 -PO(OM) 2 (A) may be an anionic, non-ionic, zwitterionic or amphoteric synthetic detergent, especially a mixture of detergents containing 0.5 to 6% of a non-ionic ethylene oxide condensate detergent. The soap may be a mixture of tallow and coconut oil soaps in the wt. ratio of 4 : 1. The soaps may be sodium, potassium, ammonium or alkylolammonium salts of C 10 -C 20 fatty acids. Preferred anionics are the C 8 -C 18 alkyl sulphates and C 10 -C 20 random paraffin sulphonates. The builders (B) may be the Na, K, NH 4 and substituted NH 4 salts of sequestering agents e.g. nitrilotriacetates polymaleates, polyitaconates and polyacrylates; alkali metal carbonates, borates, phosphates, polyphosphates, bicarbonates and silicates; and polyphosphonates e.g. ethane - 1 - hydroxy - 1,1 - di - phosphonate. Optional ingredients are (D) per compound bleaching agent e.g. sodium perborate, sodium percarbonate or sodium persulphate; (E) fillers e.g. Na 2 SO 4 or NaCl; (F) carboxy methylcellulose; (G) germicidal agents, enzymes, antitarnishing agents, optical brighteners and dyes. The compositions may be liquid, granules, flakes or tablets.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US74627468A | 1968-07-22 | 1968-07-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1269378A true GB1269378A (en) | 1972-04-06 |
Family
ID=25000147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB36728/69A Expired GB1269378A (en) | 1968-07-22 | 1969-07-22 | Low sudsing detergent compositions |
Country Status (11)
Country | Link |
---|---|
US (1) | US3585145A (en) |
AT (1) | AT310907B (en) |
BE (1) | BE736280A (en) |
CH (1) | CH510734A (en) |
DE (1) | DE1936843C3 (en) |
ES (1) | ES369740A1 (en) |
FR (1) | FR2014675A1 (en) |
GB (1) | GB1269378A (en) |
NL (2) | NL160329C (en) |
NO (1) | NO130594C (en) |
SE (1) | SE353545B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3639144A (en) * | 1969-07-18 | 1972-02-01 | Us Agriculture | Organo-phosphorus compounds containing perfluoroalkyl radicals and their application to cellulosic textiles |
NL7106367A (en) * | 1970-05-20 | 1971-11-23 | ||
DE2233941C3 (en) * | 1972-07-11 | 1978-03-02 | Cassella Farbwerke Mainkur Ag, 6000 Frankfurt | Use of perfluoroalkylphosphorus compounds as foam suppressants |
US4176176A (en) * | 1974-05-31 | 1979-11-27 | Alberto-Culver Company | Hair shampoo and cleanser compositions |
US4183367A (en) * | 1976-06-17 | 1980-01-15 | American Cyanamid Company | Enhancing the drying of hair by the use of fluorinated catonic and amphoteric surfactants |
GB1599414A (en) * | 1977-04-18 | 1981-09-30 | Unilever Ltd | Shampoo with anti-grease properties |
DK435881A (en) * | 1981-10-01 | 1983-04-02 | Niels Ole Vesterager | WASHING ACTIVE DOSAGE UNIT, METHOD OF PREPARING IT AND THE USE OF IT |
DE3723198A1 (en) * | 1987-07-14 | 1989-02-16 | Bayer Ag | FOAM-RESISTANT ADDITIVE IN ACID SOURS AND GALVANIC BATHS |
US6258772B1 (en) * | 1999-10-12 | 2001-07-10 | Bay Technologies, Inc. | Cleaning compositions comprising perfluorinated alkylphosphates |
-
0
- NL NL130594D patent/NL130594C/xx active
-
1968
- 1968-07-22 US US746274A patent/US3585145A/en not_active Expired - Lifetime
-
1969
- 1969-07-17 FR FR6924418A patent/FR2014675A1/fr not_active Withdrawn
- 1969-07-18 NO NO2997/69A patent/NO130594C/no unknown
- 1969-07-18 BE BE736280D patent/BE736280A/xx unknown
- 1969-07-19 DE DE1936843A patent/DE1936843C3/en not_active Expired
- 1969-07-21 SE SE10256/69A patent/SE353545B/xx unknown
- 1969-07-21 CH CH1114669A patent/CH510734A/en not_active IP Right Cessation
- 1969-07-22 GB GB36728/69A patent/GB1269378A/en not_active Expired
- 1969-07-22 AT AT704569A patent/AT310907B/en not_active IP Right Cessation
- 1969-07-22 ES ES369740A patent/ES369740A1/en not_active Expired
- 1969-07-22 NL NL6911186.A patent/NL160329C/en active
Also Published As
Publication number | Publication date |
---|---|
NL6911186A (en) | 1970-01-26 |
NL160329B (en) | 1979-05-15 |
NL160329C (en) | 1979-10-15 |
NO130594C (en) | 1975-01-08 |
DE1936843A1 (en) | 1970-01-22 |
FR2014675A1 (en) | 1970-04-17 |
AT310907B (en) | 1973-10-25 |
ES369740A1 (en) | 1971-06-16 |
BE736280A (en) | 1970-01-19 |
DE1936843B2 (en) | 1978-05-11 |
NO130594B (en) | 1974-09-30 |
NL130594C (en) | |
US3585145A (en) | 1971-06-15 |
SE353545B (en) | 1973-02-05 |
CH510734A (en) | 1971-07-31 |
DE1936843C3 (en) | 1979-01-18 |
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