FR3098520B1 - HMPSA réticulable sous irradiation UV - Google Patents

HMPSA réticulable sous irradiation UV Download PDF

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Publication number
FR3098520B1
FR3098520B1 FR1907762A FR1907762A FR3098520B1 FR 3098520 B1 FR3098520 B1 FR 3098520B1 FR 1907762 A FR1907762 A FR 1907762A FR 1907762 A FR1907762 A FR 1907762A FR 3098520 B1 FR3098520 B1 FR 3098520B1
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France
Prior art keywords
weight
layer
hmpsa
irradiation
composition
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1907762A
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English (en)
Other versions
FR3098520A1 (fr
Inventor
Amandine Rafaitin
Christophe Robert
Alexandre Gourlain
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bostik SA
Original Assignee
Bostik SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1907762A priority Critical patent/FR3098520B1/fr
Application filed by Bostik SA filed Critical Bostik SA
Priority to EP20750317.8A priority patent/EP3997185A1/fr
Priority to MX2021015444A priority patent/MX2021015444A/es
Priority to US17/618,048 priority patent/US20220315811A1/en
Priority to JP2022501225A priority patent/JP2022540852A/ja
Priority to AU2020312223A priority patent/AU2020312223A1/en
Priority to CN202080049481.9A priority patent/CN114096630A/zh
Priority to CA3140840A priority patent/CA3140840A1/fr
Priority to PCT/FR2020/051197 priority patent/WO2021005299A1/fr
Priority to KR1020227000215A priority patent/KR20220032549A/ko
Publication of FR3098520A1 publication Critical patent/FR3098520A1/fr
Application granted granted Critical
Publication of FR3098520B1 publication Critical patent/FR3098520B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09J157/02—Copolymers of mineral oil hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C08L57/02—Copolymers of mineral oil hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/387—Block-copolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)

Abstract

1) Composition HMPSA réticulable UV comprenant : - 10-24 % en poids d’un copolymère à blocs qui comprend un bloc styrénique et un bloc polybutadiène comprenant au moins 25 % en poids du motif vinyle-1,2 ; - 43-65 % en poids d’une résine tackifiante obtenue par polymérisation, puis hydrogénation totale ou partielle d’une coupe C9, ayant un point de ramollissement de 80-150°C ; - 10-25 % en poids d’une huile hydrocarbonée  pétrolière ; et - d’une teneur appropriée d’un photoinitiateur (D). 2) Article auto-adhésif comprenant une couche support (b) revêtue d’une couche auto-adhésive (a) constituée de la composition HMPSA à l’état réticulé. 3) Procédé de fabrication de l'article 2) comprenant : - le préchauffage de la composition HMPSA à une température de 70-80°C ; - son application par enduction sur une surface porteuse ; - sa réticulation par irradiation UV pour former la couche de composition adhésive réticulée (a) ; puis - le contre collage ou transfert de la couche (a) sur une couche support ou un film protecteur anti-adhérent.
FR1907762A 2019-07-10 2019-07-10 HMPSA réticulable sous irradiation UV Active FR3098520B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1907762A FR3098520B1 (fr) 2019-07-10 2019-07-10 HMPSA réticulable sous irradiation UV
PCT/FR2020/051197 WO2021005299A1 (fr) 2019-07-10 2020-07-06 Hmpsa reticulable sous irradiation uv
US17/618,048 US20220315811A1 (en) 2019-07-10 2020-07-06 Hmpsa crosslinkable under uv irradiation
JP2022501225A JP2022540852A (ja) 2019-07-10 2020-07-06 Ｕｖ照射下で架橋可能なｈｍｐｓａ
AU2020312223A AU2020312223A1 (en) 2019-07-10 2020-07-06 HMPSA crosslinkable under UV irradiation
CN202080049481.9A CN114096630A (zh) 2019-07-10 2020-07-06 在uv辐照下可交联的hmpsa
EP20750317.8A EP3997185A1 (fr) 2019-07-10 2020-07-06 Hmpsa reticulable sous irradiation uv
MX2021015444A MX2021015444A (es) 2019-07-10 2020-07-06 Adhesivo sensible a la presion de fusion en caliente (hmpsa) reticulable bajo irradiacion ultravioleta (uv).
KR1020227000215A KR20220032549A (ko) 2019-07-10 2020-07-06 Uv 조사하에서 가교 결합 가능한 hmpsa
CA3140840A CA3140840A1 (fr) 2019-07-10 2020-07-06 Hmpsa reticulable sous irradiation uv

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1907762A FR3098520B1 (fr) 2019-07-10 2019-07-10 HMPSA réticulable sous irradiation UV
FR1907762 2019-07-10

Publications (2)

Publication Number Publication Date
FR3098520A1 FR3098520A1 (fr) 2021-01-15
FR3098520B1 true FR3098520B1 (fr) 2022-07-22

Family

ID=68501747

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1907762A Active FR3098520B1 (fr) 2019-07-10 2019-07-10 HMPSA réticulable sous irradiation UV

Country Status (10)

Country Link
US (1) US20220315811A1 (fr)
EP (1) EP3997185A1 (fr)
JP (1) JP2022540852A (fr)
KR (1) KR20220032549A (fr)
CN (1) CN114096630A (fr)
AU (1) AU2020312223A1 (fr)
CA (1) CA3140840A1 (fr)
FR (1) FR3098520B1 (fr)
MX (1) MX2021015444A (fr)
WO (1) WO2021005299A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117417726B (zh) * 2023-12-15 2024-03-15 广州鹿山新材料股份有限公司 Uv固化橡胶系压敏胶及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3817452A1 (de) * 1988-05-21 1989-11-30 Basf Ag An der luft mit ultravioletten strahlen vernetzbare schmelzhaftkleber
US5804663A (en) 1995-03-16 1998-09-08 Shell Oil Company Radiation sensitive vinyl aromatic block copolymers and compositions containing them
JP2002527568A (ja) 1998-10-09 2002-08-27 クレイトン・ポリマーズ・リサーチ・ベー・ベー 照射硬化性接着剤
DE60127306T2 (de) * 2000-01-31 2007-12-20 H.B. Fuller Licensing & Financing, Inc., Saint Paul Strahlungshärtbare klebstoffzusammensetzungen enthaltend blockcopolymere mit vinylfunktionalisierten polybutadienblöcken
FR2812652B1 (fr) * 2000-08-04 2005-05-20 Plasto Sa Bandes adhesives empilables sans protecteur
DE10212049A1 (de) 2002-03-19 2003-10-02 Tesa Ag Haftklebemasse und Verfahren zur Herstellung hierzu
US20080153981A1 (en) * 2006-12-22 2008-06-26 Bostik S.A. Hot melt pressure sensitive adhesive for paper labels
DE102017218519A1 (de) * 2017-10-17 2019-04-18 Tesa Se Härtbarer Haftklebestreifen auf Basis von Vinylaromatenblockcopolymer

Also Published As

Publication number Publication date
EP3997185A1 (fr) 2022-05-18
CN114096630A (zh) 2022-02-25
CA3140840A1 (fr) 2021-01-14
FR3098520A1 (fr) 2021-01-15
MX2021015444A (es) 2022-01-24
WO2021005299A1 (fr) 2021-01-14
US20220315811A1 (en) 2022-10-06
JP2022540852A (ja) 2022-09-20
KR20220032549A (ko) 2022-03-15
AU2020312223A1 (en) 2022-01-20

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