FR3068980B1 - Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation - Google Patents

Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation Download PDF

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Publication number
FR3068980B1
FR3068980B1 FR1756648A FR1756648A FR3068980B1 FR 3068980 B1 FR3068980 B1 FR 3068980B1 FR 1756648 A FR1756648 A FR 1756648A FR 1756648 A FR1756648 A FR 1756648A FR 3068980 B1 FR3068980 B1 FR 3068980B1
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FR
France
Prior art keywords
polymer
meth
composition
epoxy adhesive
acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1756648A
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English (en)
French (fr)
Other versions
FR3068980A1 (fr
Inventor
Philippe Hajji
Rosangela Pirri
Raber Inoubli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1756648A priority Critical patent/FR3068980B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to US16/628,289 priority patent/US11312887B2/en
Priority to KR1020247005470A priority patent/KR20240025718A/ko
Priority to CN201880046427.1A priority patent/CN110832047B/zh
Priority to JP2020500607A priority patent/JP2020526619A/ja
Priority to KR1020207003946A priority patent/KR20200028991A/ko
Priority to PCT/EP2018/069027 priority patent/WO2019012077A1/en
Priority to EP18737317.0A priority patent/EP3652263A1/en
Priority to SG11201912339VA priority patent/SG11201912339VA/en
Publication of FR3068980A1 publication Critical patent/FR3068980A1/fr
Application granted granted Critical
Publication of FR3068980B1 publication Critical patent/FR3068980B1/fr
Priority to JP2023097648A priority patent/JP2023134435A/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025Crosslinking or vulcanising agents; including accelerators
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Epoxy Resins (AREA)
FR1756648A 2017-07-12 2017-07-12 Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation Active FR3068980B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1756648A FR3068980B1 (fr) 2017-07-12 2017-07-12 Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation
SG11201912339VA SG11201912339VA (en) 2017-07-12 2018-07-12 Epoxy adhesive composition comprising a multistage polymer and a (meth) acrylic polymer, its method of preparation and its use
CN201880046427.1A CN110832047B (zh) 2017-07-12 2018-07-12 包含多级聚合物和(甲基)丙烯酸类聚合物的环氧粘合剂组合物、其制备方法及其用途
JP2020500607A JP2020526619A (ja) 2017-07-12 2018-07-12 多段階ポリマーと(メタ)アクリルポリマーとを含むエポキシ接着剤組成物、その調製方法及びその使用
KR1020207003946A KR20200028991A (ko) 2017-07-12 2018-07-12 다단 중합체 및 (메트)아크릴 중합체를 포함하는 에폭시 접착제 조성물, 이의 제조 방법 및 이의 용도
PCT/EP2018/069027 WO2019012077A1 (en) 2017-07-12 2018-07-12 EPOXY ADHESIVE COMPOSITION COMPRISING MULTI-STAGE POLYMER AND (METH) ACRYLIC POLYMER, PROCESS FOR PREPARING THE SAME, AND USE THEREOF
US16/628,289 US11312887B2 (en) 2017-07-12 2018-07-12 Epoxy adhesive composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
KR1020247005470A KR20240025718A (ko) 2017-07-12 2018-07-12 다단 중합체 및 (메트)아크릴 중합체를 포함하는 에폭시 접착제 조성물, 이의 제조 방법 및 이의 용도
EP18737317.0A EP3652263A1 (en) 2017-07-12 2018-07-12 Epoxy adhesive composition comprising a multistage polymer and a (meth) acrylic polymer, its method of preparation and its use
JP2023097648A JP2023134435A (ja) 2017-07-12 2023-06-14 多段階ポリマーと(メタ)アクリルポリマーとを含むエポキシ接着剤組成物、その調製方法及びその使用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1756648 2017-07-12
FR1756648A FR3068980B1 (fr) 2017-07-12 2017-07-12 Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation

Publications (2)

Publication Number Publication Date
FR3068980A1 FR3068980A1 (fr) 2019-01-18
FR3068980B1 true FR3068980B1 (fr) 2020-10-02

Family

ID=60765706

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1756648A Active FR3068980B1 (fr) 2017-07-12 2017-07-12 Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation

Country Status (8)

Country Link
US (1) US11312887B2 (https=)
EP (1) EP3652263A1 (https=)
JP (2) JP2020526619A (https=)
KR (2) KR20240025718A (https=)
CN (1) CN110832047B (https=)
FR (1) FR3068980B1 (https=)
SG (1) SG11201912339VA (https=)
WO (1) WO2019012077A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114364765B (zh) * 2019-09-27 2024-04-19 株式会社钟化 粘接剂及粘接剂的制造方法
EP3838936A1 (en) * 2019-12-19 2021-06-23 Arkema France Curable compositions comprising multistage polymers
FR3134393B1 (fr) * 2022-04-12 2026-02-27 Arkema France Composition comprenant un polymère à étages multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE18570T1 (de) 1981-06-02 1986-03-15 Rohm & Haas Freifliessbare teilchen eines schlagfestigkeitsmodifikators, verfahren zu ihrer herstellung und sie enthaltende mischungen.
JPS62104888A (ja) * 1985-10-30 1987-05-15 Mitsubishi Rayon Co Ltd 接着剤組成物
JPS63112654A (ja) 1986-10-29 1988-05-17 Mitsubishi Rayon Co Ltd 熱可塑性樹脂組成物
US8222324B2 (en) 2003-06-09 2012-07-17 Kaneka Corporation Process for producing modified epoxy resin
US7485680B2 (en) 2003-09-18 2009-02-03 Kaneka Corporation Process for producing rubbery polymer particle and process for producing resin composition containing the same
ES2335531T3 (es) * 2005-07-15 2010-03-29 Huntsman Advanced Materials (Switzerland) Gmbh Composicion de tenacidad a la fractura aumentada.
EP2123711B1 (en) 2007-02-28 2016-12-14 Kaneka Corporation Thermosetting resin composition having rubbery polymer particle dispersed therein, and process for production thereof
KR101538193B1 (ko) * 2008-02-15 2015-07-20 가부시키가이샤 구라레 경화성 수지 조성물 및 수지 경화물
WO2009126862A1 (en) * 2008-04-11 2009-10-15 3M Innovative Properties Company One-part epoxy-based structural adhesive
ES2662646T3 (es) 2008-06-12 2018-04-09 Henkel IP & Holding GmbH Composiciones adhesivas epóxicas estructurales de dos partes, altamente reforzadas, de nueva generación
FR2934866B1 (fr) * 2008-08-05 2012-12-28 Arkema France Particules de type "coeur-ecorce" comprenant une ecorce a base de monomeres hydrophiles.
CN103068946B (zh) 2010-08-10 2015-05-06 3M创新有限公司 环氧树脂结构粘合剂
FR2969159B1 (fr) 2010-12-15 2013-01-11 Arkema France Composition thermoplastique modifiee choc ayant une sensibilite hydrolytique pour obtenir une fluidite elevee tout en maintenant une resistance aux chocs elevee
FR2969158B1 (fr) * 2010-12-15 2013-01-18 Arkema France Procede pour modifiants chocs et composition thermoplastique modifiee choc ayant une resistance hydrolytique amelioree
CN102924871A (zh) * 2011-08-10 2013-02-13 上海立汰新模具材料有限公司 环氧树脂组合物
FR3031108B1 (fr) 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
FR3031106B1 (fr) 2014-12-24 2017-02-03 Arkema France Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant

Also Published As

Publication number Publication date
SG11201912339VA (en) 2020-01-30
FR3068980A1 (fr) 2019-01-18
KR20200028991A (ko) 2020-03-17
WO2019012077A1 (en) 2019-01-17
JP2020526619A (ja) 2020-08-31
US11312887B2 (en) 2022-04-26
EP3652263A1 (en) 2020-05-20
KR20240025718A (ko) 2024-02-27
JP2023134435A (ja) 2023-09-27
CN110832047B (zh) 2023-02-10
CN110832047A (zh) 2020-02-21
US20200172773A1 (en) 2020-06-04

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