FR3027605B1 - Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations - Google Patents

Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations

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Publication number
FR3027605B1
FR3027605B1 FR1462297A FR1462297A FR3027605B1 FR 3027605 B1 FR3027605 B1 FR 3027605B1 FR 1462297 A FR1462297 A FR 1462297A FR 1462297 A FR1462297 A FR 1462297A FR 3027605 B1 FR3027605 B1 FR 3027605B1
Authority
FR
France
Prior art keywords
sulfur
preparation
mixture
master
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1462297A
Other languages
English (en)
Other versions
FR3027605A1 (fr
Inventor
Alexander Korzhenko
Christophe Philippe Vincendeau
Thierry Aubert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to CN202210165571.5A priority Critical patent/CN114613977A/zh
Priority to JP2017522526A priority patent/JP6576446B2/ja
Priority to SG11201703269VA priority patent/SG11201703269VA/en
Priority to CN201580055707.5A priority patent/CN107078290A/zh
Priority to EP15808697.5A priority patent/EP3212570A1/fr
Priority to PCT/FR2015/052887 priority patent/WO2016066944A1/fr
Priority to MX2017004280A priority patent/MX2017004280A/es
Priority to KR1020177011072A priority patent/KR101991598B1/ko
Priority to US15/522,125 priority patent/US10633508B2/en
Priority to CA2963214A priority patent/CA2963214C/fr
Publication of FR3027605A1 publication Critical patent/FR3027605A1/fr
Application granted granted Critical
Publication of FR3027605B1 publication Critical patent/FR3027605B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/06—Sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/0221—Melting
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/0237—Converting into particles, e.g. by granulation, milling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/0243—Other after-treatment of sulfur
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/0243—Other after-treatment of sulfur
    • C01B17/0248—Other after-treatment of sulfur of particulate sulfur
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/372—Sulfides, e.g. R-(S)x-R'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00—Personal protection gear
    • F41H1/02—Armoured or projectile- or missile-resistant garments; Composite protection fabrics
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/162—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

La présente invention concerne un procédé de préparation d'un mélange-maître comprenant de 0,01% à 50% en poids de nanocharges carbonées, et au moins un matériau soufré tel que du soufre élémentaire, par voie compoundage en voie fondue, ainsi que le mélange-maître ainsi obtenu et ses différentes utilisations. L'invention a également pour objet une composition solide comprenant des nanocharges carbonées dispersées dans un matériau soufré.
FR1462297A 2014-10-27 2014-12-12 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations Active FR3027605B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
MX2017004280A MX2017004280A (es) 2014-10-27 2015-10-27 Preparacion de lote maestro a base de azufre y nano-rellenadores carbonosos, lote maestro producido, y usos del mismo.
SG11201703269VA SG11201703269VA (en) 2014-10-27 2015-10-27 Production of a master batch based on sulphur and carbonaceous nanofillers, the master batch produced, and uses thereof
CN201580055707.5A CN107078290A (zh) 2014-10-27 2015-10-27 基于硫和含碳纳米填料的母料的生产、生产的母料及其用途
EP15808697.5A EP3212570A1 (fr) 2014-10-27 2015-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations
PCT/FR2015/052887 WO2016066944A1 (fr) 2014-10-27 2015-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations
US15/522,125 US10633508B2 (en) 2014-10-27 2015-10-27 Production of a master batch based on sulphur and carbonaceous nanofillers, the master batch produced, and uses thereof
CN202210165571.5A CN114613977A (zh) 2014-10-27 2015-10-27 基于硫和含碳纳米填料的母料的生产、生产的母料及其用途
JP2017522526A JP6576446B2 (ja) 2014-10-27 2015-10-27 硫黄及び炭素質ナノフィラーに基づくマスターバッチの製造、製造されたマスターバッチ並びにその使用
CA2963214A CA2963214C (fr) 2014-10-27 2015-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations
KR1020177011072A KR101991598B1 (ko) 2014-10-27 2015-10-27 황 및 탄소질 나노충전제 기재의 마스터 배치 제조, 제조된 마스터 배치, 및 이의 용도

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1460299A FR3027604B1 (fr) 2014-10-27 2014-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations

Publications (2)

Publication Number Publication Date
FR3027605A1 FR3027605A1 (fr) 2016-04-29
FR3027605B1 true FR3027605B1 (fr) 2016-11-04

Family

ID=52102902

Family Applications (2)

Application Number Title Priority Date Filing Date
FR1460299A Expired - Fee Related FR3027604B1 (fr) 2014-10-27 2014-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations
FR1462297A Active FR3027605B1 (fr) 2014-10-27 2014-12-12 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations

Family Applications Before (1)

Application Number Title Priority Date Filing Date
FR1460299A Expired - Fee Related FR3027604B1 (fr) 2014-10-27 2014-10-27 Preparation d'un melange-maitre a base de soufre et de nanocharges carbonees, le melange-maitre obtenu et ses utilisations

Country Status (10)

Country Link
US (1) US10633508B2 (fr)
EP (1) EP3212570A1 (fr)
JP (1) JP6576446B2 (fr)
KR (1) KR101991598B1 (fr)
CN (2) CN107078290A (fr)
CA (1) CA2963214C (fr)
FR (2) FR3027604B1 (fr)
MX (1) MX2017004280A (fr)
SG (1) SG11201703269VA (fr)
WO (1) WO2016066944A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3030890B1 (fr) * 2014-12-22 2019-07-26 Arkema France Matiere active d'electrode pour batterie li/s
FR3076827A1 (fr) * 2018-01-12 2019-07-19 Arkema France Matiere solide agglomeree de nanotubes de carbone desagreges.
FR3076952B1 (fr) * 2018-01-16 2023-08-11 Arkema France Formulation sous la forme d'une dispersion solide-liquide pour la fabrication d'une cathode pour batterie li/s et procede de preparation de ladite formulation
FR3078201B1 (fr) * 2018-02-19 2023-01-13 Arkema France Formulation de matiere active pour accumulateur li-s et procede de preparation
FR3080491B1 (fr) * 2018-04-20 2021-06-18 Arkema France Batterie lithium/soufre a capacite augmentee et procedes associes
CN113241440B (zh) * 2021-05-20 2022-08-05 中国科学院过程工程研究所 一种二硫化钼/硫掺杂石墨烯复合材料及其制备方法和应用

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FR1460299A (fr) * 1965-12-14 1966-11-25 Dispositif destiné à la présentation positionnée de porte-clés et s?nilaires
CA2632850C (fr) * 2005-12-09 2015-02-10 Shell Internationale Research Maatschappij B.V. Procede de preparation de ciment au soufre ou d'un composite d'agregat de ciment au soufre
DE102006024590A1 (de) * 2006-05-26 2007-11-29 Degussa Gmbh Hydrophile Kieselsäure für Dichtungsmassen
FR2921391B1 (fr) * 2007-09-24 2010-08-13 Arkema France Procede de preparation de materiaux composites
WO2011000131A1 (fr) * 2009-07-01 2011-01-06 中兴通讯股份有限公司 Procédé et système de téléchargement de fichiers prévus pour le protocole open mobile alliance de gestion de dispositifs
FR2948233B1 (fr) * 2009-07-20 2015-01-16 Commissariat Energie Atomique Materiau composite conducteur soufre/carbone, utilisation comme l'electrode et procede de fabrication d'un tel materiau
JP5696269B2 (ja) * 2009-11-18 2015-04-08 コペリオン ゲーエムベーハー ポリマーとカーボンナノチューブに基づく複合材料の製造方法、この方法によって製造された複合材料及びその使用
FR2957910B1 (fr) * 2010-03-23 2012-05-11 Arkema France Melange maitre de nanotubes de carbone pour les formulations liquides, notamment dans les batteries li-ion
CN102918684B (zh) * 2010-05-28 2016-09-14 巴斯夫欧洲公司 膨胀石墨在锂/硫电池组中的用途
RU2669362C2 (ru) * 2012-04-13 2018-10-11 Аркема Инк. Батарея на основе сераорганических соединений
FR2991313B1 (fr) * 2012-06-01 2015-10-16 Arkema France Soufre liquide de faible viscosite
US20140018489A1 (en) * 2012-07-13 2014-01-16 Baker Hughes Incorporated Mixed metal polymer composite
CN102848545B (zh) * 2012-09-25 2014-05-07 烟台泰鸿橡胶有限公司 橡胶护舷无模挤出法
KR101973778B1 (ko) * 2012-11-16 2019-04-30 삼성디스플레이 주식회사 플렉서블 표시 장치 및 그 커버 윈도우 제조 방법
KR101683963B1 (ko) * 2014-05-26 2016-12-07 현대자동차주식회사 이중 건식 복합화를 통한 황-탄소 복합체 제조 방법

Also Published As

Publication number Publication date
FR3027604B1 (fr) 2016-11-04
US10633508B2 (en) 2020-04-28
US20170313844A1 (en) 2017-11-02
SG11201703269VA (en) 2017-05-30
KR101991598B1 (ko) 2019-06-20
JP6576446B2 (ja) 2019-09-18
CA2963214C (fr) 2022-07-12
MX2017004280A (es) 2017-07-19
CN107078290A (zh) 2017-08-18
KR20170074885A (ko) 2017-06-30
EP3212570A1 (fr) 2017-09-06
JP2018502802A (ja) 2018-02-01
CA2963214A1 (fr) 2016-05-06
FR3027604A1 (fr) 2016-04-29
WO2016066944A1 (fr) 2016-05-06
FR3027605A1 (fr) 2016-04-29
CN114613977A (zh) 2022-06-10

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